WANG Nan
,
LIANG Zhi-gang
,
CHEN Min
,
ZOU Zong-shu
钢铁研究学报(英文版)
The enrichment behavior of phosphorus in CaO-SiO2-FeOx-P2O5 slag was studied by making an investigation on the distribution of phosphorous content in the CaO-SiO2-FeOx-P2O5 molten slag. The research results showed that the 2CaO·SiO2 solid particles existing in molten slag were the condensation sites for the phosphorus enrichment. The enrichment process of phosphorus in the molten slag can be recognized as three substeps: mass transfer of phosphorus from bulk slag to the surface of 2CaO·SiO2 particle, superficial solid solution reaction of phosphorus around the 2CaO·SiO2 particle, and diffusion of phosphorus through the product layer of 2CaO·SiO2-3CaO·P2O5 solid solution to the inner of 2CaO·SiO2 particle. Moreover, higher temperature is favorable to the phosphorous enrichment from molten bulk slag to the 2CaO·SiO2 particles.
关键词:
enrichment behavior
,
phosphorus
,
2CaO·SiO2 particle
,
mass transfer
WANG Nan
,
LIANG Zhi-gang
,
CHEN Min
,
ZOU Zong-shu
钢铁研究学报(英文版)
The effects of adjusting technological conditions on the phosphorous enrichment of adjusted converter slag were investigated. The results showed that the phosphorus could be effectively enriched to 2CaO·SiO2 and 2CaO·SiO2-3CaO·P2O5 solid solution (SS, namely phosphorus-rich phase) to be formed with the decreasing of basicity and cooling rate. Moreover, the morphology of the phosphorus-rich phase changed from granular for the original converter slag with higher basicity to the coexistence of granular shape and rod-like for the adjusted slag with lower basicity. P2O5 content in phosphorus-rich phase exceeded 30% while the basicity was 13 at the cooling rate of 10 ℃/min.
关键词:
phosphorous enrichment
,
adjusting technological condition
,
adjusted converter slag
,
phosphorus-rich phase
