{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"研究了以多孔聚丙烯支撑体,-(2-乙基)(BEHPA)为流动载体的Co(Ⅱ)离子支撑传输行为;萃取法测定了BEHPA/CHCl3体系中Co(Ⅱ)萃合物组成(CoR2 4HR)及相应的萃取常数(Kex=3.89×10-8);考察了料相pH值、载体浓度、实验温度和起始浓度对Co(Ⅱ)传输的影响,并对该体系富集、传输Co(Ⅱ)的最佳条件进行了讨论;从界面化学和扩散传质角度提出了金属离子的传输动力学方程,采用直线斜率法对Co(Ⅱ)在BEHPA/CHCl3支撑体系中的扩散层厚度(δa=7.73×10-6 m)和内扩散系数(d0=5.69×10-10 m2/s)进行了测定,取得满意结果.","authors":[{"authorName":"王骋","id":"e46bb756-6c3e-4502-a934-9db09be71683","originalAuthorName":"王骋"},{"authorName":"石振海","id":"38103472-13a6-42f9-9677-e24bae4ecbfa","originalAuthorName":"石振海"},{"authorName":"姚秉华","id":"ea7135db-c9a3-4f28-b6bb-138141675ce7","originalAuthorName":"姚秉华"},{"authorName":"王力","id":"b61d9423-3c93-4a59-a426-540fa115ea5c","originalAuthorName":"王力"}],"doi":"10.3969/j.issn.1000-0518.2004.11.011","fpage":"1127","id":"b4cf6ae1-b7c3-4bbd-ac3f-97d4a5f67c6e","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"6ae7cfa4-0841-4a3b-8c1f-742459dd7289","keyword":"支撑,膜分离,-(乙基),(Ⅱ)","originalKeyword":"支撑液膜,液膜分离,二-(乙基己基)膦酸,钴(Ⅱ)"}],"language":"zh","publisherId":"yyhx200411011","title":"(Ⅱ)在-(2-乙基)/CHCl3支撑体系中的传输","volume":"21","year":"2004"},{"abstractinfo":"介绍了支撑膜分离技术的最新研究进展,特别是欧洲的研究现状.叙述了近年来使用支撑进行金属离子的选择分离,光学异构体的分离,生物活性物质的分离及气体分离的基本原理和研究进展.列举了不同金属离子和有机选择分离的载体.同时报道了支撑作为分析检测的辅助手段用于微量成份,环境中污染药物,人体体液中的药物的分离富集分析检测的研究.并对支撑稳定性的研究进展,包括支撑不稳定性的机理,改进支撑稳定性的方法作了介绍.","authors":[{"authorName":"张保成","id":"cdeae123-6535-402b-88a2-d39ca5818e6b","originalAuthorName":"张保成"},{"authorName":"","id":"741a9b47-46c8-44be-8d99-f5ec34f683c1","originalAuthorName":""},{"authorName":"","id":"57b1f190-0b67-473f-922a-769991c4d042","originalAuthorName":""}],"doi":"10.3969/j.issn.1007-8924.2000.06.013","fpage":"46","id":"9b4e2430-36bd-4fbb-b9dd-894d1a106e3f","issue":"6","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术 "},"keywords":[{"id":"660f284a-269b-4fd5-8f22-fdfc791d8f11","keyword":"分离","originalKeyword":"分离"},{"id":"1e667302-0f63-4382-b828-4f6cba317ce4","keyword":"支撑","originalKeyword":"支撑液膜"},{"id":"22e2d62c-7fe4-4483-bcfe-921b367e3d97","keyword":"稳定性","originalKeyword":"稳定性"}],"language":"zh","publisherId":"mkxyjs200006013","title":"支撑膜分离技术的研究进展","volume":"20","year":"2000"},{"abstractinfo":"研究了(2-乙基)(PIA-8)的庚烷溶液在高氯酸钠介质中对Ln3+的萃取.探讨了萃取平衡时间、不同介质、PIA-8浓度对萃取La3+的影响及反萃剂浓度对反萃率的影响;用斜率法确定了萃合物的组成为La(HA2)3;测定了La3+、Ce3+、Pr3+、Nd3+、Sm3+、Eu3+的半萃取pH1/2值分别为3.69、3.30、3.16、3.10、2.68、2.54.","authors":[{"authorName":"余晓皎","id":"fed3ad64-62a4-4fa7-a860-eb57b085e091","originalAuthorName":"余晓皎"},{"authorName":"姚秉华","id":"0d4cf1c5-28ba-43b2-a627-2bbca376aa8a","originalAuthorName":"姚秉华"},{"authorName":"永长幸雄","id":"2e7508b6-90e5-4e23-895f-88648f24e097","originalAuthorName":"永长幸雄"}],"doi":"10.3969/j.issn.1004-0277.2006.06.015","fpage":"59","id":"6ac517db-f09c-4193-8a8e-670d0e2361ce","issue":"6","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"d098ffb5-4f00-4056-9c8d-11a22a8c4830","keyword":"(2-乙基)","originalKeyword":"二(2-乙基己基)膦酸"},{"id":"41303fa8-1e9c-4331-8289-740c18a012d1","keyword":"萃取","originalKeyword":"萃取"},{"id":"59362a4f-9a3a-41ec-a523-2883472b7c4c","keyword":"镧","originalKeyword":"镧"},{"id":"c15a03a3-24ab-4726-a065-b6937c933804","keyword":"高氯酸钠","originalKeyword":"高氯酸钠"}],"language":"zh","publisherId":"xitu200606015","title":"(2-乙基)萃取镧系元素研究","volume":"27","year":"2006"},{"abstractinfo":"研究了用2-乙基单-2-乙基酯(HEH/EHP,P507)和(2-乙基)磷酸(HDEHP,P204)从硫酸介质中协同萃取Ce(Ⅳ)的机制.结果表明:在HEH/EHP的摩尔分散在0.6时,体系的协萃系数最大.Ce(Ⅳ)以Ce(SO4)0.5HL2A2的形式被萃人有机相,协萃反应为阳离子交换机制.同时还得到了HEH/EHP和HDEHP从硫酸介质中协同萃取Ce(Ⅳ)时,体系的平衡常数及热力学函数如△G,△H和△S等.","authors":[{"authorName":"罗兴华","id":"2680261b-70ed-4007-a1c3-0d5f543621c6","originalAuthorName":"罗兴华"},{"authorName":"黄小卫","id":"5779b939-1acd-458a-9e78-92e75ce92d55","originalAuthorName":"黄小卫"},{"authorName":"朱兆武","id":"10b858c6-46d3-4752-85fb-9c01774b6a4e","originalAuthorName":"朱兆武"},{"authorName":"龙志奇","id":"bb26ed02-6526-4a2c-ac47-773bbd900f51","originalAuthorName":"龙志奇"},{"authorName":"刘营","id":"e3ee0fda-1e88-4d64-8a2a-1fc5363de6b0","originalAuthorName":"刘营"}],"doi":"","fpage":"566","id":"08dd8fee-9f78-4c17-a18b-bbdb9ac242b9","issue":"5","journal":{"abbrevTitle":"ZGXTXB","coverImgSrc":"journal/img/cover/ZGXTXB.jpg","id":"86","issnPpub":"1000-4343","publisherId":"ZGXTXB","title":"中国稀土学报"},"keywords":[{"id":"19dd8f1c-c6fd-48c1-a8ea-935b6b80713e","keyword":"协同萃取","originalKeyword":"协同萃取"},{"id":"c05ed5db-4ce7-4cc5-88bb-306aadfe2466","keyword":"Ce(Ⅳ)","originalKeyword":"Ce(Ⅳ)"},{"id":"6bf85cde-2ff4-44a9-8191-d844e1392fca","keyword":"HEH/EHP萃取剂","originalKeyword":"HEH/EHP萃取剂"},{"id":"7f12dfae-52fa-4722-ad26-09eea3bb8c87","keyword":"HDEHP萃取剂","originalKeyword":"HDEHP萃取剂"},{"id":"a3310a03-02be-4921-ab31-90772de4a15b","keyword":"硫酸介质","originalKeyword":"硫酸介质"},{"id":"94459be3-c191-4a08-81a6-3c26b933e886","keyword":"稀土","originalKeyword":"稀土"}],"language":"zh","publisherId":"zgxtxb200805010","title":"2-乙基单2-乙基酯和(2-乙基)磷酸从硫酸介质中协同萃取Ce(Ⅳ)的研究","volume":"26","year":"2008"},{"abstractinfo":"通过固态萃合物2-乙基单(2-乙基)酯(HEH(EH)P,HA)-Mn的制备,对单烷基膦酸酯萃取价Mn离子的萃合物组成及萃取机理进行了研究。结果表明:萃合物为不含水分子,组成为MnA_2,属高旋弱场配合物;认为萃合物为四面体结构。","authors":[{"authorName":"黄可龙","id":"2294925c-ead4-4f40-a8f4-85aef0850d35","originalAuthorName":"黄可龙"},{"authorName":"舒万银","id":"b5362839-4067-4361-a880-e25dcb9db6b8","originalAuthorName":"舒万银"},{"authorName":"丁敦煌","id":"8b3d9b18-40e1-4243-8308-f1638395e0e3","originalAuthorName":"丁敦煌"},{"authorName":"刘国根","id":"39969305-14c4-4b53-a376-721b220f3b58","originalAuthorName":"刘国根"},{"authorName":"董萍","id":"d529a03d-945d-4ecc-943f-5e5ab8ecac6a","originalAuthorName":"董萍"}],"categoryName":"|","doi":"","fpage":"88","id":"889ac2b4-8f7c-4659-b2d4-4f78a5d78194","issue":"4","journal":{"abbrevTitle":"JSXB","coverImgSrc":"journal/img/cover/JSXB.jpg","id":"48","issnPpub":"0412-1961","publisherId":"JSXB","title":"金属学报"},"keywords":[{"id":"304f484a-4ef2-4d67-9bee-602a3907e325","keyword":"萃取","originalKeyword":"萃取"},{"id":"59289988-b401-459d-a8a7-3a84cdf18502","keyword":"mono(2-ethylhexyl)-2-ethylhexyl phosphate","originalKeyword":"mono(2-ethylhexyl)-2-ethylhexyl phosphate"},{"id":"c727daea-ed93-4acf-8cf6-e23e5bee6433","keyword":"Mn","originalKeyword":"Mn"},{"id":"4363fdbe-6d6c-45a1-b181-94e5e7a33554","keyword":"extracted complex","originalKeyword":"extracted complex"}],"language":"zh","publisherId":"0412-1961_1991_4_16","title":"2-乙基单(2-乙基)酯-Mn萃合物的研究","volume":"27","year":"1991"},{"abstractinfo":"简要回顾膜分离过程的发展史;介绍支撑法的基本原理.在分析支撑所存在问题的基础上重点论述近10年来支撑的应用和发展.","authors":[{"authorName":"裴亮","id":"69929f42-ece2-4ef7-bec6-2883c5b6e02a","originalAuthorName":"裴亮"},{"authorName":"姚秉华","id":"5b51b960-fb6e-4061-8ef6-4890805dc962","originalAuthorName":"姚秉华"},{"authorName":"付兴隆","id":"a6efbb18-04ad-46dc-a290-0757f2c60d0e","originalAuthorName":"付兴隆"}],"doi":"10.3969/j.issn.1007-8924.2009.03.018","fpage":"80","id":"69a2e7c2-e6cf-4653-abf4-6c6359779eba","issue":"3","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术 "},"keywords":[{"id":"1d9321f2-8d1d-4efd-9860-0c89be62e51f","keyword":"支撑","originalKeyword":"支撑液膜"},{"id":"f839b100-d0a6-4358-81eb-539e5fa772ab","keyword":"分离","originalKeyword":"分离"},{"id":"073032f8-2669-4e3c-a124-3b9f4f98fe99","keyword":"液体薄膜渗透","originalKeyword":"液体薄膜渗透"},{"id":"e6754fd3-197e-45f8-a853-067e9f4b49ee","keyword":"稳定性","originalKeyword":"稳定性"}],"language":"zh","publisherId":"mkxyjs200903018","title":"支撑膜分离过程应用研究新进展","volume":"29","year":"2009"},{"abstractinfo":"研究了(2-乙基)(PIA-8)的庚烷溶液分别在高氯酸钠、氯乙酸、柠檬介质中对Pr3+的萃取.探讨了萃取平衡时间、不同介质、PIA-8浓度对萃取Pr3+的影响及反萃剂浓度对反萃率的影响;斜率法确定了萃合物的组成为Pr(HA2)3;测定了La3+、Ce3+、Pr3+、Nd3+、Sm3+、Eu3+在不同介质中的半萃取pH值,在高氯酸钠介质中分别为3.55、3.19、3.02、2.98、2.61、2.43:在氯乙酸介质中分别为3.65、3.27,3.12、3.08、2.66、2.50;在柠檬介质中分别为4.34、4.26、4.11、3.91、3.57、3.38.","authors":[{"authorName":"余晓皎","id":"12a087a7-38ce-4d97-abbb-884169726813","originalAuthorName":"余晓皎"},{"authorName":"姚秉华","id":"bbfdf553-01ba-4867-a998-97b83dc440c5","originalAuthorName":"姚秉华"},{"authorName":"永长幸雄","id":"10e6a992-1fdb-4ce4-911a-f7bb872e8dd6","originalAuthorName":"永长幸雄"}],"doi":"","fpage":"1099","id":"f79dbe28-d703-4aef-82ad-d400031093ec","issue":"6","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"61e71794-d4c4-4910-b9d8-7d68f7631486","keyword":"(2-乙基)","originalKeyword":"二(2-乙基己基)膦酸"},{"id":"d4bb9b90-bb99-43e4-bdb1-2c69ff5d98fa","keyword":"萃取","originalKeyword":"萃取"},{"id":"dddb63b2-b5f8-4a03-8da8-1c9829a0654d","keyword":"镨","originalKeyword":"镨"},{"id":"936107d5-0a74-441a-83fe-411acd6d2a1a","keyword":"介质","originalKeyword":"介质"}],"language":"zh","publisherId":"xyjsclygc200706039","title":"(2-乙基)萃取不同介质中Pr3+的研究","volume":"36","year":"2007"},{"abstractinfo":"使用离子液体\"充填型\"支撑,进行乙醇/水混合物的蒸汽渗透膜分离实验,比较了原料浓度、操作温度对分离性能的影响.结果表明,离子液体支撑的蒸汽渗透过程能够实现乙醇脱水,用于制备无水乙醇.经过140 h的实验测定,支撑膜分离性能稳定.在50℃温度下,原料中含水摩尔分数0.024~0.24时,蒸汽渗透分离因子5.5~3.2,渗透通量55 g/(m2·h).离子液体支撑的蒸汽渗透膜分离过程,有望用于醇类水溶液组成的恒沸体系脱水.","authors":[{"authorName":"吴锋","id":"a700de64-8e6c-4c38-9892-39a55e8bcb39","originalAuthorName":"吴锋"},{"authorName":"王保国","id":"34199ae3-ea67-475a-b65d-0a6650e34dee","originalAuthorName":"王保国"}],"doi":"10.3969/j.issn.1007-8924.2008.05.013","fpage":"68","id":"1b9385ef-4119-4d4f-ae01-1b9e3029e81e","issue":"5","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术 "},"keywords":[{"id":"33c0a86a-ae04-4971-aa43-36d9d3250a85","keyword":"离子液体","originalKeyword":"离子液体"},{"id":"46f0695a-fe02-405f-a6b7-9f0bcf2aaac9","keyword":"支撑","originalKeyword":"支撑液膜"},{"id":"cf710dbb-b0b3-4dc5-85c0-ef98983e9a72","keyword":"蒸汽渗透","originalKeyword":"蒸汽渗透"},{"id":"ad090ab5-30a4-4b32-8d38-b143429c3e91","keyword":"乙醇/水混合物","originalKeyword":"乙醇/水混合物"}],"language":"zh","publisherId":"mkxyjs200805013","title":"离子液体充填型支撑膜分离乙醇/水混合物","volume":"28","year":"2008"},{"abstractinfo":"简要回顾了膜分离过程的发展史,分析了乳化支撑的特点及其存在的问题,介绍了近年来各国学者在改进稳定性方面所作的努力,并展望了工业化的前景.","authors":[{"authorName":"顾忠茂","id":"d4950601-ec71-48cc-a70e-d089259aace9","originalAuthorName":"顾忠茂"}],"doi":"10.3969/j.issn.1007-8924.2003.04.039","fpage":"214","id":"e5227ce5-ae59-4742-80de-dcada5244d55","issue":"4","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术 "},"keywords":[{"id":"40802122-e8d1-424c-bd37-46683862d8e2","keyword":"乳化","originalKeyword":"乳化液膜"},{"id":"8bbae652-9a52-4409-acde-befccb8f51a7","keyword":"支撑","originalKeyword":"支撑液膜"},{"id":"741743d7-53d1-4858-86b1-f9be7671014e","keyword":"流动(包容)","originalKeyword":"流动液膜(包容液膜)"},{"id":"a6b711e7-9cac-4f29-a7a7-851c4d1cdcbf","keyword":"静电式准","originalKeyword":"静电式准液膜"},{"id":"5d679b75-3473-4663-80d2-15df8f9f719d","keyword":"内耦合萃反交替","originalKeyword":"内耦合萃反交替"},{"id":"6892f6b0-1187-4d98-af8b-99583a8a3b5b","keyword":"支撑乳化","originalKeyword":"支撑乳化液膜"}],"language":"zh","publisherId":"mkxyjs200304039","title":"膜分离技术进展","volume":"23","year":"2003"},{"abstractinfo":"建立了分离提取蛋氨酸、亮氨酸、苯丙氨酸和色氨酸的磷酸(2-乙基)酯(D2EHPA)-煤油-HCI反萃分散组合体系,考察了料相pH值、载体D2EHPA浓度、相与反萃相体积比、反萃相组成、料相与反萃分散相流速、传输时间以及支撑重复使用次数对氨基渗透系数和传输效率的影响.在优化的条件下,建立的反萃分散组合体系对4种氨基均可以获得大于35%的传输效率,其中色氨酸和亮氨酸的传输效率超过了79%,且传输效率呈Et.Trp>Et.Leu>Et.Phe>Et.Met的趋势.支撑重复使用25次,对氨基的传输效率没有明显改变.建立的体系对考察的氨基展示了较高传输效率和优越的传输选择性,是一种简单和环境友好的分离技术.","authors":[{"authorName":"陈园园","id":"e5112485-07b1-46a8-9a3d-dc0ecc5f928f","originalAuthorName":"陈园园"},{"authorName":"商静芬","id":"b2329bee-ed19-4d5c-ace7-361db6fd3e49","originalAuthorName":"商静芬"},{"authorName":"欧阳丽","id":"4f5f7ed2-d4c5-4104-9559-e4cf2aa0bae8","originalAuthorName":"欧阳丽"},{"authorName":"苏孝礼","id":"1085f0c5-5e50-4c8e-8db6-482810171669","originalAuthorName":"苏孝礼"},{"authorName":"方正法","id":"1e77d2ab-fdec-4b70-a692-f752e44f5fd0","originalAuthorName":"方正法"},{"authorName":"马铭","id":"146f0d22-fd6f-4e61-950e-b7771becc0dc","originalAuthorName":"马铭"}],"doi":"10.3724/SP.J.1095.2012.00314","fpage":"697","id":"23a87824-dad4-4f0c-b899-843ce34408eb","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"f340955d-280f-4cf9-bbf8-eb8fe32d8962","keyword":"反萃分散组合","originalKeyword":"反萃分散组合液膜"},{"id":"ab2d2633-6c9f-4006-9618-755db081a456","keyword":"氨基","originalKeyword":"氨基酸"},{"id":"e5999dc1-8ff1-453e-9c7a-3143f11cb2ec","keyword":"蛋氨酸","originalKeyword":"蛋氨酸"},{"id":"87d2bbfe-65b3-4488-a2b1-fddb24c4974f","keyword":"亮氨酸","originalKeyword":"亮氨酸"},{"id":"30b52ab7-901f-4111-a953-b4f1f64413ec","keyword":"苯丙氨酸","originalKeyword":"苯丙氨酸"},{"id":"8a54489f-86bd-448c-a046-283d708c7581","keyword":"色氨酸","originalKeyword":"色氨酸"},{"id":"e2aa199c-6a1b-4870-8d9d-c644e21fa937","keyword":"传输","originalKeyword":"传输"}],"language":"zh","publisherId":"yyhx201206015","title":"反萃分散组合膜分离提取氨基","volume":"29","year":"2012"}],"totalpage":8223,"totalrecord":82221}