HUANG Kelong
,
SHU Wanyin
,
DING Dunhuang
,
LIU Guogen
,
DONG Ping
,
Central South University of Technology
,
Changsha
,
China HUANG Kelong
,
Lecturer
,
Department of Chemistry
,
Central South University of Technology
,
Changsha 410083
,
China
金属学报(英文版)
In order to clarify the mechanism and the complex formed in the extraction of divalent Mn by alkylphosphonic acid monoester, the solid complex has been prepared by mono (2-ethylhexyl)-2-ethylhexyl phosphate, HEH(EH)P, HA with divalent Mn. The elemental analysis, magnetic susceptibility and thermogravimetry have been determined for the solid complex of HEH(EH)P-Mn(II) and the infrared spectrum has been carried out in comparison to the extractant HEH(EH)P. The extracted compound has also been studied by electronic and electron spin resonance spectroscopy in octane solvent and solid state at room temperature. On the basis of the measurements, it is concluded that the structure of the solid polymeric species MnA_2 is in a tetrahedral arrangement.
关键词:
solvent extraction mono (2-ethylhexyl)-2-ethylhexyl phosphate
,
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,
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