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In Situ Scanning-Tunneling-Microscope Observation on Dissolution of a Cu-20Zr Film

Haibo LU

材料科学技术(英文)

A nanocrystalline coating of Cu-20Zr (in wt~pct) was obtained on glass by magnetron sputtering. The corrosion behavior of the Cu-20Zr film in 0.001 mol/L HCl solution was investigated using potentiodynamic polarization and in situ electrochemical scanning-tunneling-microscopy (ECSTM). Results demonstrated that the film exhibits active behavior. Microscopic pitting corrosion and tunneling are caused by localized electrodissolution of Zr atoms and the diffusion of Cu atoms at surface defects.

关键词: Magnetron sputtering , null , null , null

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