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KINETICS OF DESULPHURIZATION IN PERMANENT CONTACT OF SLAG AND STEEL

JIANG Guochang XU Kuangdi DENG Jianxiong Shanghai University of Technology , Shanghai , ChinaGUO Zhancheng GUAN Yulong Beiiing University of Science and Technology , Beijing , China Jiang Guochang Associate Professor , The Institute of Metallurgy and Materials , Shanghai University of Technology , Shanghai 200072 , China

金属学报(英文版)

The curve of % S vs reaction time is described quantitatively based on the electrochemical model directly deduced from the principle of electrochemistry as well as the given method for calculating the initial oxygen potential along slag/steel interface.The calculated data is in good agreement with the experimental results. During desulphurization,both L_s~* and L_s,the sulphur partition along the interface and that in the bulk,go up in association with the descending of oxygen potential along interface. The plot of L_s~* against reaction time follows a parabolic curve,while that of L_s is of hyperbola type.Correspondingly,on curves of driving force parameter vs reaction tone,either calculated or experimental,a hump occurs.

关键词: slag/steel interface , null , null

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