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Glass Formation and Thermal Stability in Rapidly Solidified Al-Fe-V-Si Alloy with Misch Metal Additions

Jianqiang WANG , Meiguang ZENG (M.K.Tseng) and Xiufang CHEN(Dept. of Material Science , College of Science , Northeastern University , Shenyang 110006 , China)Lin DONG and Shixu GU(Liaoning Province Center of Analysis and Testing Research , Shenyang 110015 , Chi

材料科学技术(英文)

A new amorphous Al87.3Fe4.3V0.7Si1.7Mm6.0(Mm: misch metal) was prepared by using melt-spinning technique. Differential scanning calorimetry (DSC), X-ray diffraction (XRD). transmis-sion electron microscopy (TEM) and energy dispersive X-ray (EDX) have been used to investigatethe crystallization behaviour of thi5 amorphous alloy It is found that the crystallization processcan be concluded as follows: amorphous→ amorphous plus fcc-Al→ fcc-Al plus AI11(La,Ce)3plus i-phase (icosahedral)→ fcc-Al plus Al11(La,Ce)3 plus i-phase plus ic-phase (icosahedralcompounds). The results of microhardness measurement show that HV values are higher thanthose in Al-Fe-V-Si based alloy and the maximum HV value corresponds to the coexisting ofnanoscale Al particles and i-phase.

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