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AN EXPERT SYSTEM FOR COMPUTER AIDED ALLOY STEEL DESIGN—ASPRES

CHEN Yu , CHEN Nianyi Shanghai institute of Metallurgy , Academia Sinica , Shanghai , China PENG Ping , KONG Bingyu Iron and Steel Research Institute , Shanghai Baoshan Iron and Steel Complex , Shanghai , China professor , Shanghai Institute of Metallurgy , Academia Sinica , Shanghai 200050 , China

金属学报(英文版)

An alloy steel pattern recognition expert system,ASPRES,has been established for the purpose of computer aided optimal design of alloy steel in compositions and process pa- rameters,Pattern recognition techniques are used to abstract inner relationship between mechanical properties and process variables.The ASPRES uses 2-dimensional graph as visual knowledge to represent domain expertise of specific object.Forward and back- ward chaining can be utilized by researcher in predicting sample performances or giving helpful suggestions about the chemical compositions and process parameters according to desired properties.

关键词: pattern recognition , null , null

ELECTRONIC STRUCTURE OF Pd-Y-Si GLASSES

LUO Meiqing CHEN Nianyi Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , ChinaYU Zhizhong Shanghai Institute of Testing Technics , Shanghai , ChianNING Yuantao ZHOU Xinming Kunming Institute of Precious Metals , Kunming , China CHEN Nianyi , Professor , Shanghai Institute of Metallurgy , Academia Sinica , Shanghai 200050 , China

金属学报(英文版)

The electronic structure of Pd-Y-Si glass has been investigated by ESCA and quantum chem- ical calculation.It was found that the valence electrons of Y transferred to Si atoms in this metallic glass,forming polar covalent bonds.Perhaps these strong covalent bonds link Si and Y atoms to form clusters that hinder the process of crystallization.

关键词: Pd-Y-Si glass , null , null , null

ELECTRON MICROANALYSIS FOR LASER MELTED ZONE IN 45 STEEL WITH Fe-Ni-Cr COATING

CHENG Yongxing LI Genfu YU Shaoluo Shanghai University of Engineering Science , Shanghai , China WANG Huimin No.11 Institute of China State Shipbuilding Corp. , Shanghai , China Associate Professor , Dept.No.5 , Shanghai University of Engineering Science , 350 Xianxia Road , Shanghai , China

金属学报(英文版)

The Fe-Ni-Cr coating laver has been alloyed with 45 steel base metal by transverse.flow type CO_2 gas laser of maximum output 5kW.The characteristics of the melted zone and the es- sence of the“bright band”has been investigated using the electron microscopy.The results show that the“bright band”belongs to the melted zone and is a vertical section of the plane crystal,The width of the“bright band”equals the height of the plane crystal,which decreases with the increase of laser beam scanning rate and the decrease of laser power.This has been explained in terms of constitutional supercooling G/R.

关键词: laser alloying , null , null

EFFECT OF MAGNETIC FIELD ON MARTENSITIC TRANSFORMATION IN Fe-21Ni-4Mn ALLOY

SUN Enxi Dalian Railway College , Dalian , ChinaYANG Dazhi Dalian University of Technology , Dalian , ChinaXU Zuyao (T.Y.Hsu) Shanghai Jiaotong University , Shanghai , ChinaYANG Fuming ZHAO Ruwen Institute of Physics , Academia Sinica , Beijing , China YANG Dazhi , Professor , Dalian University of Technology , Dalian 116024 , China

金属学报(英文版)

The pulsed magnetic field induced martensitic transformation with isothermal and athermal kinetics in Fe-2Ni-4Mn(wt-%)alloy has been studied by means of magnetization measurements,optical microscopy and thermodymical analyses.It is shown that there exits a critical magnetic intensity for induing martensitic transformation at a given temperature above Ms.The critical magnetic field increases linearly with increasing ΔT= T-M_S.The magnetic field strongly promotes the athermal martensitic transforamtion and restrains the isothermal one.The entropy change ΔS for athermal transformation at Ms is 4.13 J/mol· K.The effect of magnetic field on martensitic transformation in Fe-21Ni-4Mn alloy is main- ly due to Zeeman effect.Lath,plate and butterfly martensities were observed under magnetic field.

关键词: magnetic field-induced martensitic transformation , null , null

MICROSTRUCTURE OF A RAPIDLY SOLIDIFIED Fe-C-Sn ALLOY

ZHANG Jingguo ZHANG Xiaomin LIN Yijian Shanghai Iron and Steel Research Institute , Shanghai , ChinaKE Jun (T.Ko) University of Iron and Steel Technology Beijing , Beijing , ChinaCHEN Lanying Shanghai Institute of Optic and Fine Mechanics , Academic Sinica , Shanghai , China Senior Engineer , Shanghai Iron and Steel Research Institute , Shanghai 200940 , China

金属学报(英文版)

The microstructure of a laser-melted Fe-4% C-10% Sn alloy has been studied.A non-crystalline phase was found in the upper part of the laser-melted zone:At the bottom of the melted zone,however,the microcrystalline zone which consists of α-Fe and a bet phase was observed.Fine twinning martensite exists in the other area of the melted zone.

关键词: Fe-C-Sn alloy , null , null , null

PRECIPITATION OF TiC IN METASTABLE β-Ti ALLOY

YU Xuejie WANG Jianlin Shanghai Iron and Steel Research Institute , Shanghai , ChinaZHOU Tianjian Anhui Institute of Technology , Hefei , China YU Xuejie , Senior Engineer , Shanghai Iron Steel Research Institute , 1001 Taihe Road , Wusong , Shanghai , China.

金属学报(英文版)

In order to clarify that the IFP and the “Type 2”α phase are also arising from TiC,a metastable β-Ti alloy was selected for investigation in this work.The results showed that af- ter heating the alloy just below the α+β→β transus temperature and quenching,the TiC lay- er existed at the α/β interface.The morphology of TiC is similar to that of the IFP arising from TiH_2 in the α-β two-phase alloys.The IFP TiC also provided an easy crack path or the crack initiation sites.The fracture is also identical to that caused by IFP TiH_2.The arced diffractions(characteristic of “Type 2”α)were found in the selected area diffraction pat- terns of some specimens which had been isothermally aged after solid solution treatment.The particles which bring on the arced diffractions may be TiC on the basis of structure and lat- tice parameter analysis,not the so called “Type 2”α phase.

关键词: interface phase(IFP) , null , null , null

EFFECT OF LASER SCANNING SPEED ON PHASE CONSTITUTION AND WEAR RESISTANCE OF LASER CLADDING HARD FACING ALLOY STELLITE 12

XU Yourong ZHANG Henghua CHEN Darning XIE Fuchun XU Mingyu Shanghai University of Science and Technology , Shanghai , ChinaCHEN Lanying SU Baorong QIAN Hongbin Shanghai Optics and Fine Mechinery Research Institute , Academia Sinica , Shanghai , China XU Yourong , professor , Department of Materials Science and Engineering , Shanghai University of Science and Technology , Shanghai 201800 , China

金属学报(英文版)

Effect of laser scanning speed on phase constitution,microstructure,microhardness and wear resistance of laser-cladding hard facing alloy Stellite 12 has been investigated by means of a cross-flow-type CO_2 laser of 1.5 kW.The laser-cladding layer on the alloy consists of ma- trix phase of suppersaturated solid solution γ(Co,Cr)and complex hexagonal carbide M_7C_3.Under certain condition,at higher laser scanning speed,the suppersaturated solubility of elements increases in γ(Co,Cr),and the precipitation of the complex carbtde M_7C_3 de- creases,so the microhardness increases and the wear resistance decreases.But at slower laser scanning speed,more complex carbide M_7C_3 may precipitate,and the wear resistance may be improved.Therefore,it is believed that the principal factor in improving wear resistance is the precipitation of carbide M_7C_3,while increment of microhardness is the suppersaturated solu- bility of elements in matrix phase γ(Co,Cr).

关键词: laser-cladding , null , null , null

FACTORS AFFECTING SILICA CONTENT OF ALUMINIUM HYDROXIDE PRODUCT IN CARBONIZATION PROCESS

LIU Miaoxiu CHENG Zhaonian CHEN Nianyi Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , ChinaKE Jiajun Institute of Chemical Metallurgy , Academia Sinica , Beijing , China CHEN Nianyi , Professor , Shanghai Institute of Metallurgy , Academia Sinica , Shanghai 200050 , China

金属学报(英文版)

The regularity of the carbonization process in alumina production has been summarized by the pattern recognition and regression.A mathematical model has been proposed to describe the factors affecting the silica content of aluminium hydroxide product.The high concentration of aluminate ions in solution will produce aluminium hydroxide with low content of SiO_2 under the condition of Al_2O_3/SiO_2 ratio kept unchanged.This was confirmed by certain scale experiments.

关键词: carbonization , null , null , null

INFLUENCE OF GRAIN BOUNDARY MORPHOLOGY ON CREEP AND FRACTURE BEHAVIOURS OF SUPERALLOYS IN SULFUR-CONTAINING ENVIRONMENT

ZHANG Yuanhu SUN Jian XIANG Yi HU Gengxiang Shanghai Jiaotong University , Shanghai , ChinaLI Tiefan Institute of Corrosion and Protection of Metals , Academia Sinica , Shenyang , China Yuanhu , Department of Materials Science and Engineering , Shanghai Jiaotong University , Shanghai , 200030

金属学报(英文版)

Studies on the high temperature creep and fracture behaviours in air or in SO_2 contaminated environment for the Fe-base superalloy GH302 with flat or zigzag grain boundaries(GB) and the Ni-base superalloy Rene 80 were carried out.Although the creep rupture properties of the GH302 with zigzag GB was remarkably superior to that of flat GB in air,the properties of both droped dramatically in 10% SO_2-air environment,the creep rupture properties of the directional solidified Rene 80 were much better than that of the conventionally cast alloy in air,and also kept the same property in SO_2 contaminated environment as in air.Owing to the interaction between creep and sulphidation,the failure mechanism relates to the formation of molten Ni-Ni-3S_2 eutectic along GB,led to the premature failure of the alloy.

关键词: superalloy , null , null , null , null

RAMAN SPECTRA OF SODIUM ALUMINATE SOLUTIONS WITH HIGH-CAUSTIC RATIO AND HIGH CONCENTRATION

LIU Miaoxiu CAO Yilin CHEN Nianyi Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , ChinaZHUANG Zhicheng Shanghai Jiaotong University , Shanghai , China Professor , Shanghai Institute of Metallurgy , Academia Sinica , Shanghai 200050 , China

金属学报(英文版)

The constitution of high-caustic ratio and highly concentrated sodium aluminate solutions has been investigated by Raman spectra method.By comparison with the Raman spectra of crystalline solids of Ca_3[Al(OH)_6]_2 and Ba_2[Al_2(OH)_(10)],it can be concluded that AI(OH)_6~(3-)ion and perhaps its polymers may be formed in these solutions.

关键词: high caustic ratio , null , null

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