ZHENG Minhui Univeristy of Science and Technology Beijing
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Beijing
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ChinaKOZUKA Zensaku Faculty of Engineering
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Osaka University
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Japan
金属学报(英文版)
The activities of In in two pseudo-binary systems of fixed molar fraction ratio N_(Bi)/N_(Ti) have been measured by means of EMF method using zirconia solid electrolyte gal- vanic cells over the temperature range of 973—1223 K.The excess free energies were deter- mined based on the experimental data.The experimentally determined thermodynamic prop- erties of the ternary alloys agree well with the values caleulated from the author's equations using related binary data.The excess free energies are negative in almost all compositions ex- cept those near the In-Tl side and become negatively larger as the compositions approach the Bi-Tl side.
关键词:
In-Bi-Tl alloy
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