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水泥浆体体系ζ-电位探究

张翠 , 王智 , 王林龙 , 张磊

硅酸盐通报

本文通过电泳法系统测定了水泥浆体体系的ζ-电位,研究了实际工程应用中,对水泥浆体性质影响较大、实际可控的五个因素对水泥浆体ζ-电位的影响规律.研究证明:水化时间,掺合料对水泥浆体的ζ-电位影响不大;低水灰比时,水泥浆体中电解质离子浓度较高;聚羧酸减水剂能有效提高水泥颗粒表面ζ-电位,但聚羧酸减水剂对ζ-电位的影响不如萘系减水剂的大;适量硫酸盐可提高掺聚羧酸减水剂的水泥浆体ζ-电位,增加水泥颗粒间静电斥力,对水泥浆体的分散性和流动性有利.实验结论对研究水泥浆体的介电性质、流变性能及水泥与减水剂的分散性具有较高的理论参考价值.

关键词: 水泥浆体 , ζ-电位 , 静电斥力 , 流变性能

On the ζ-Potential of Nanodiamond in Aqueous Systems

Yongwei ZHU , Xiangqian SHEN , Zhijing FENG , Xiangyang XU , Baichun WANG

材料科学技术(英文)

Several factors affecting the ζ-potential of nanodiamonds were studied. The Chemical Mechanical Modification (CMM) of surface, different surfactants and its dosage, and inorganic ions on the ζ-potential of nanodiamond sample L were studied using ZETASIZER3000HS and Nexus470. Results show that the ζ-potential changes with its parameters of detonation synthesis and purification. Results also suggest that CMM and subsequent treatments employed can alter apparently the ζ-potential and that some anionic surfactants increase the absolute value of the ζ-potential in the alkaline surrounding.

关键词: Nanodiamond , null , null , null

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