{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"合成了苯甲酸-<span style=\"color:red\">铕</span>-<span style=\"color:red\">铽</span>和苯甲酸-<span style=\"color:red\">铕</span>-<span style=\"color:red\">铽</span>-镧系列固体<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,研究了它们的荧光发射光谱.结果表明,Tb3+对Eu3+的荧光发射有很强的敏化作用,而Eu3+对Tb3+的荧光发射有很强的猝灭作用;但Eu3+和Tb 3+的荧光发射峰的位置基本上保持不变.","authors":[{"authorName":"连锡山","id":"3e97ff35-23e2-46d5-856f-f40577d35cbb","originalAuthorName":"连锡山"},{"authorName":"马素清","id":"b0fdf9fe-ccd1-49a2-9ee8-1794f2d0995f","originalAuthorName":"马素清"}],"doi":"10.3969/j.issn.1004-0277.1999.05.003","fpage":"7","id":"af0c5a17-9079-4c25-b03a-0ce3daed0e09","issue":"5","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"8f48b273-71c0-4a47-b3e2-2c9a284bcb58","keyword":"<span style=\"color:red\">铕</span>-<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铕-铽配合物"},{"id":"40fecd71-0eeb-4959-bcf3-bd31875d7b24","keyword":"苯甲酸","originalKeyword":"苯甲酸"},{"id":"7e66f8b7-ba2c-4d28-8383-fde7d80fdce6","keyword":"荧光光谱","originalKeyword":"荧光光谱"}],"language":"zh","publisherId":"xitu199905003","title":"苯甲酸-<span style=\"color:red\">铕</span>-<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的荧光光谱研究","volume":"20","year":"1999"},{"abstractinfo":"分别合成了以对苯基苯甲酸为配体,<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span>及掺杂<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span>为中心的固态<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>.经元素分析、摩尔电导及差热-热重分析,推测其组成分别为:<span style=\"color:red\">铕</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>:EuL3·3H2O、 Eu0.5La0.5 L 3·3H2O 、 Eu0.5Y0.5 L 3·3H2O;<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>:TbL3·2H2O、 Tb0.5La0.5 L 3·2H2O、Tb0.5Y0.5 L3·3H2O(L=(◇)-(◇)-COO-). 红外光谱、紫外光谱及核磁共振氢谱分析表明,对苯基苯甲酸的羧基氧原子与稀土离子配位.<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的荧光光谱测定表明,<span style=\"color:red\">铕</span>系列和<span style=\"color:red\">铽</span>系列<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>都可发出其特征荧光,<span style=\"color:red\">铕</span>异核稀土<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的荧光强度与相同配体的<span style=\"color:red\">铕</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>相比,均有不同程度提高.","authors":[{"authorName":"李强","id":"73cd97e2-ceb6-4476-bb21-a840765bbb50","originalAuthorName":"李强"},{"authorName":"赵永亮","id":"217c25d2-0812-4ed6-b244-625f586251b0","originalAuthorName":"赵永亮"},{"authorName":"赵凤英","id":"ae2ff004-e6ae-40c7-97d3-7304406a3557","originalAuthorName":"赵凤英"}],"doi":"10.3969/j.issn.1004-0277.2007.04.002","fpage":"5","id":"215b4d0a-e973-4083-b14d-007cf1dff501","issue":"4","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"02e48075-ff5c-497d-8d89-04d59930e575","keyword":"对苯基苯甲酸","originalKeyword":"对苯基苯甲酸"},{"id":"af97f26a-7f7f-4b84-af28-adddba238d68","keyword":"<span style=\"color:red\">铕</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铕配合物"},{"id":"ccba2f6c-3497-4e0e-ab87-b3655726217e","keyword":"<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铽配合物"},{"id":"da2d4778-6800-4c4b-8a24-3f79742034d8","keyword":"荧光光谱","originalKeyword":"荧光光谱"}],"language":"zh","publisherId":"xitu200704002","title":"对苯基苯甲酸<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成、表征及荧光性能研究","volume":"28","year":"2007"},{"abstractinfo":"用壳寡糖分别与硝酸<span style=\"color:red\">铕</span>和硝酸<span style=\"color:red\">铽</span>反应, 制备了壳寡糖-<span style=\"color:red\">铕</span>、壳寡糖-<span style=\"color:red\">铽</span>两种<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>. 用红外光谱、紫外光谱、 荧光和X射线光电子能谱(XPS)等分析测试手段对<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>进行了表征. 以吩嗪硫酸甲酯(PMS)-还原型辅酶Ⅰ烟酰胺腺嘌呤二核苷酸(NADH)-硝基四氮唑蓝(NBT)产生超氧阴离子自由基(·O-2)来研究壳寡糖和壳寡糖稀土金属<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>对·O-2自由基的清除作用. 结果表明: 壳寡糖与Eu3+或Tb3+形成了<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>, 壳寡糖-<span style=\"color:red\">铕</span>、壳寡糖-<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中不仅壳寡糖氨基上的N原子参与了配位, 同时仲羟基的O原子也参与了配位. 壳寡糖和壳寡糖稀土金属<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>对·O-2均具有明显的清除作用, <span style=\"color:red\">配合</span><span style=\"color:red\">物</span>与壳寡糖相比对·O-2具有更高的清除活性.","authors":[{"authorName":"任群翔","id":"a430faff-9ec0-4725-b238-f52f1fe190ab","originalAuthorName":"任群翔"},{"authorName":"翟玉春","id":"24264e40-1fa7-4fda-828d-2a6fa125a547","originalAuthorName":"翟玉春"},{"authorName":"秦岩","id":"4c5706ed-8b17-4733-bfa8-ce191fef5699","originalAuthorName":"秦岩"}],"doi":"","fpage":"385","id":"38105a51-7061-4c66-9674-114a9284450e","issue":"4","journal":{"abbrevTitle":"ZGXTXB","coverImgSrc":"journal/img/cover/ZGXTXB.jpg","id":"86","issnPpub":"1000-4343","publisherId":"ZGXTXB","title":"中国稀土学报"},"keywords":[{"id":"589ead06-9860-4acb-82f9-f314b7975fda","keyword":"壳寡糖","originalKeyword":"壳寡糖"},{"id":"54a19c8c-1466-4fa4-882e-85ad876080d8","keyword":"稀土<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"稀土配合物"},{"id":"dd36b134-631e-4451-ad59-4d6f2da2dbdb","keyword":"合成","originalKeyword":"合成"},{"id":"44b92a77-7f10-4731-9d4c-73e192a2d3fd","keyword":"自由基","originalKeyword":"自由基"}],"language":"zh","publisherId":"zgxtxb200804001","title":"壳寡糖<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成、表征及抗·O-2活性","volume":"26","year":"2008"},{"abstractinfo":"以辛酰丙氨酸作为配体,以乙醇和水作为混合溶剂,用溶液化学反应法制备氨基酸<span style=\"color:red\">铕</span>和<span style=\"color:red\">铽</span>的<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>.用13C NMR(核磁共振)、偏光显微镜、DSC(差示扫描量热法)、分光荧光光度计等分别对所制备样品进行了元素分析和表征.13C NMR谱测试及元素分析结果表明,实验所得辛酰丙氨酸<span style=\"color:red\">铕</span>和<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>具有(C10H20NCO3)3M(M为Tb、Eu)型化学分子结构;使用偏光显微镜观察表面形貌,发现稀土<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>可以形成非晶态,且表面均匀、透明;DSC测定<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的玻璃化转换温度和结晶态的熔点温度,且结晶态具有明显的结晶吸热峰;荧光光度计测试发现<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>有明显的发光特性.","authors":[{"authorName":"那仁格日乐","id":"0229589c-7759-4b28-a6d2-703e138d917c","originalAuthorName":"那仁格日乐"},{"authorName":"周炳卿","id":"9a91823e-b923-4192-a979-7be9d6967d3b","originalAuthorName":"周炳卿"},{"authorName":"田晓","id":"e32c97ee-8ac8-4142-ae20-733cc41ddc0a","originalAuthorName":"田晓"},{"authorName":"包富泉","id":"92b43cc3-d2cd-480d-b133-6f5de19fc217","originalAuthorName":"包富泉"}],"doi":"10.16533/J.CNKI.15-1099/TF.201601005","fpage":"27","id":"d12b1195-ff1f-4487-b900-c3449679029c","issue":"1","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"ba6f7794-4ffd-4905-868c-6db5bfccb797","keyword":"发光材料","originalKeyword":"发光材料"},{"id":"faeb75f3-2d21-45d2-ba55-405274d23a3a","keyword":"金属<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"金属配合物"},{"id":"7d6a5da9-19fc-4b79-a139-cb60b301e87a","keyword":"稀土","originalKeyword":"稀土"},{"id":"a480c9fd-ddf8-4896-a46e-9a7e5988e6ca","keyword":"发光性质","originalKeyword":"发光性质"}],"language":"zh","publisherId":"xitu201601005","title":"辛酰丙氨酸<span style=\"color:red\">铕</span>和<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的制备及其表征","volume":"37","year":"2016"},{"abstractinfo":"以5-磺基水杨酸、α-噻吩甲酰三氟丙酮为小分子配体、溶液聚合法制备的甲基丙烯酸甲酯和丙烯酸共聚<span style=\"color:red\">物</span>(PMMA-AA)为高分子配体,合成了<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span>双核高分子<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>.通过元素分析、EDTA配位滴定分析、热分析、紫外光谱分析、红外光谱分析对标题<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的组成、结构进行了表征;采用荧光光谱仪研究了其发光性能.结果表明:标题<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中,Eu对Tb有很强的荧光猝灭作用,Tb对Eu有较强的荧光敏化作用,但Eu和Tb的荧光发射峰的位置基本保持不变.","authors":[{"authorName":"陈仲清","id":"b6daa30a-cb20-4d99-b17d-e3d8b2ad2cc1","originalAuthorName":"陈仲清"},{"authorName":"郭栋才","id":"67b7b2e6-5e16-4b16-8699-8e7023145df8","originalAuthorName":"郭栋才"},{"authorName":"李征宇","id":"0a11bced-672c-461b-9d1c-9ff08a58921f","originalAuthorName":"李征宇"},{"authorName":"舒万艮","id":"9f4ca0dd-16b6-4b22-812a-57904010b4ad","originalAuthorName":"舒万艮"}],"doi":"","fpage":"31","id":"ca0a525a-50cc-458e-8a80-3e4a40ac262f","issue":"z3","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"c99b4e34-d394-4320-8068-c4758c99e1dd","keyword":"稀土","originalKeyword":"稀土"},{"id":"a1ebf79e-4684-4414-acf4-26040daaa600","keyword":"合成","originalKeyword":"合成"},{"id":"dfffbed6-87ac-4e03-aff6-6db92d1e6759","keyword":"高分子","originalKeyword":"高分子"},{"id":"475e5526-6d8c-4529-bf7e-4f1439646b8c","keyword":"<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"配合物"},{"id":"f7145498-7217-404a-bd75-6b81cec76afe","keyword":"荧光","originalKeyword":"荧光"}],"language":"zh","publisherId":"xyjsclygc2007z3008","title":"稀土(<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span>)双核高分子荧光<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成及性能研究","volume":"36","year":"2007"},{"abstractinfo":"以5-磺基水杨酸、α-噻吩甲酰三氟丙酮为小分子配体,以溶液聚合制备的甲基丙烯酸甲酯和丙烯酸共聚<span style=\"color:red\">物</span>(PMMA-AA)为高分子配体,合成了一系列<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span>的高分子<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,并通过UV、IR和元素分析对其结构进行了表征.用荧光分光光度计研究了它们的荧光性能及<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span>之间的荧光性能的互相影响规律,讨论了它们的荧光发射峰位、荧光发射强度与组成的关系.实验结果表明,在稀土(<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span>)多核高分子荧光<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中,Eu3+与Tb3+之间的荧光光谱有相互敏化或猝灭的作用. 其中Eu3+对Tb3+的荧光有很强的荧光猝灭作用,且在n(Eu3+):n(Tb3+)=1:1时,Eu3+对Tb3+的荧光猝灭作用最大;Tb3+在低浓度n(Eu3+):n(Tb3+)大于1:1时,Tb3+对Eu3+的荧光有猝灭作用,Tb3+在高浓度n(Eu3+):n(Tb3+)小于1:1时,Tb3+对Eu3+的荧光有很强的敏化作用.","authors":[{"authorName":"陈仲清","id":"9014f324-55b3-45cd-8127-4ce46abfa06d","originalAuthorName":"陈仲清"},{"authorName":"郭栋才","id":"6d87aaba-782b-4821-a463-5bcd1037d2f4","originalAuthorName":"郭栋才"},{"authorName":"夏良树","id":"4a61e409-f144-4330-a9a3-6028b8b325e1","originalAuthorName":"夏良树"}],"doi":"10.3969/j.issn.1000-0518.2007.10.014","fpage":"1157","id":"15a001ce-d6d4-4074-b84d-9c77943fe173","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"64e9e805-fdf1-4c77-9424-8c3bb83102ba","keyword":"稀土","originalKeyword":"稀土"},{"id":"7247da2b-3f17-472f-828d-ed44e2eaf021","keyword":"高分子","originalKeyword":"高分子"},{"id":"fba42c74-8346-4e6f-a95a-db4837a2c229","keyword":"<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"配合物"},{"id":"cd08354d-4eb6-47c5-a398-d308231903a1","keyword":"合成","originalKeyword":"合成"},{"id":"427de9cb-6024-4690-873c-5a9bd4558a3e","keyword":"荧光性能","originalKeyword":"荧光性能"}],"language":"zh","publisherId":"yyhx200710014","title":"稀土(<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span>)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中荧光性能相互影响","volume":"24","year":"2007"},{"abstractinfo":"采用Claisen缩合反应合成了一种新型的β-二酮化合<span style=\"color:red\">物</span>1-(4-溴苯)-3-苯基丙烷-1,3-二酮(L),并以其为第一配体,邻菲罗啉(phen)为第二配体,合成出新型稀土<span style=\"color:red\">铕</span>,<span style=\"color:red\">铽</span>二元及三元<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>.通过元素分析、红外光谱、紫外光谱、荧光光谱对合成的配体及<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>进行了表征.元素分析确定了<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的组成.红外光谱的分析表明第一配体L中的氧原子以及第二配体phen中的氮原子与稀土离子进行了配位.紫外光谱表明第一配体L为能量的给体,第二配体phen起协同作用.通过荧光光谱研究了<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的发光性质,结果显示三元<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的发光强度大于二元<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,三元<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>Eu(L)3phen表现出Eu3+的特征发射,在593,615,653,701 nm处的发射峰分别归属于Eu3+的5 D0→7Fj(j=1,2,3,4)能级间的跃迁,并且以位于615 nm处的5D0→7F2电子跃迁所发出的荧光强度最大；而<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中并没有出现Tb3+的特征发射.进一步的研究表明,这是由于配体L的最低三重态能级较适合Eu3+的发射能级,配体L吸收的能量可以有效的通过Antenna效应传递给稀土中心离子,使得三元<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>Eu(L)3phen的发光强度较大.","authors":[{"authorName":"任晓明","id":"b4049399-5e7f-450d-91b8-756c9e41adba","originalAuthorName":"任晓明"},{"authorName":"魏长平","id":"f1544456-e3c2-4212-9a84-af0afa3de5ee","originalAuthorName":"魏长平"},{"authorName":"程果","id":"743da1e5-ada2-4b6e-96b0-27e59e840031","originalAuthorName":"程果"}],"doi":"10.3969/j.issn.0258-7076.2012.01.022","fpage":"124","id":"babdaaf9-67b4-4950-9536-f8db63d0382b","issue":"1","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"735fc0ff-a480-4429-aa87-d6927f1dace7","keyword":"稀土","originalKeyword":"稀土"},{"id":"3649eeff-b894-421d-bcf3-93ae3bb6ef95","keyword":"β-二酮","originalKeyword":"β-二酮"},{"id":"f4096244-fa29-446b-b726-7d9bbc99afc7","keyword":"合成","originalKeyword":"合成"},{"id":"0ca2e7d4-c295-4de2-919c-af6f1609a8fa","keyword":"三元<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"三元配合物"},{"id":"36439f96-878b-4f2a-8e93-7554933deebc","keyword":"发光性能","originalKeyword":"发光性能"}],"language":"zh","publisherId":"xyjs201201022","title":"稀土<span style=\"color:red\">铕</span>,<span style=\"color:red\">铽</span>β-二酮<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成与发光性能","volume":"","year":"2012"},{"abstractinfo":"采用稀土掺杂的方法合成了<span style=\"color:red\">铕</span>锶、<span style=\"color:red\">铽</span>锶的对苯二甲酸(L)<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,并对系列<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>进行了红外光谱测定和荧光光谱研究.实验结果表明,共掺杂<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的羧基氧与稀土离子配位.<span style=\"color:red\">铽</span>锶<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>Tb-Sr-L和<span style=\"color:red\">铕</span>锶<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>Eu-Sr-L的发光性能较好.在上述<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>中加入荧光惰性离子Y3+形成Tb-Sr-Y-L和Eu-Sr-Y-L<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>可以使对苯二甲酸<span style=\"color:red\">铕</span>锶、<span style=\"color:red\">铽</span>锶<span style=\"color:red\">配合</span>物体系的荧光得到进一步增强,这可能是由于存在有效的分子内传能,使发光稀土离子Eu3+和Tb3+受到敏化作用而使荧光增强;而加入Zn2+和Mn2+使体系的荧光减弱,<span style=\"color:red\">铽</span>锶<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>及其掺杂<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>Tb-Sr-Y-L是较理想的发光<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>.","authors":[{"authorName":"李颖","id":"88f4d940-1bc9-41e6-871d-9fc92aa4d135","originalAuthorName":"李颖"},{"authorName":"赵永亮","id":"225c7996-1c65-4d27-87b7-123c04410e3d","originalAuthorName":"赵永亮"},{"authorName":"丁飞","id":"bd7d0e8b-9e8b-4414-aa27-63bf61a6bfb9","originalAuthorName":"丁飞"},{"authorName":"赵凤英","id":"76c3d1fb-64aa-43ab-8b88-3a8c667fbcd9","originalAuthorName":"赵凤英"}],"doi":"10.3969/j.issn.1004-0277.2005.05.004","fpage":"13","id":"63d8d249-b262-4ed5-8c9a-ef5af3702684","issue":"5","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"8c4ca35b-31d9-4e05-8ab7-888602759381","keyword":"对苯二甲酸","originalKeyword":"对苯二甲酸"},{"id":"8da70f8b-d52b-42e9-b458-bede1bd034b8","keyword":"<span style=\"color:red\">铕</span>锶<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铕锶配合物"},{"id":"c2a55736-6152-4c4f-888c-e48c4f333ba5","keyword":"<span style=\"color:red\">铽</span>锶<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"铽锶配合物"},{"id":"81499485-0de8-4fd8-8e56-340a13c89d07","keyword":"荧光光谱","originalKeyword":"荧光光谱"}],"language":"zh","publisherId":"xitu200505004","title":"对苯二甲酸<span style=\"color:red\">铕</span>锶、<span style=\"color:red\">铽</span>锶掺杂<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的红外光谱及荧光光谱研究","volume":"26","year":"2005"},{"abstractinfo":"合成了以Eu3+,Tb3+及Eu3+,Tb3+掺杂RE3+(La3+,Gd3+,Y3+)为中心,以2-噻吩乙酸和1,10-邻菲啰啉为配体的两个系列8种同核与掺杂稀土固体<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>.对其进行了稀土及C、H和N元素分析、摩尔电导、热谱、红外光谱、核磁共振氢谱的测定及荧光性能研究.确定了<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的组成为REL3L′和RE0.5Ln0.5L3L′(RE=Eu,Tb;Ln=La,Gd,Y;L=2-噻吩乙酸;L′=1,10-邻菲啰啉,在常温下测定了它们的固态粉末荧光光谱,发现掺杂离子(La3+,Gd3+,T3+)使稀土Eu3+离子发光明显增强,讨论了掺杂稀土离子对<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的发光影响.","authors":[{"authorName":"张梅","id":"6272e67e-8030-428a-8caa-fb0fda8fbdc0","originalAuthorName":"张梅"},{"authorName":"赵永亮","id":"827e558e-79fa-4a28-8acb-2855e95384e1","originalAuthorName":"赵永亮"},{"authorName":"王连蒙","id":"d8140704-e343-475c-b03c-75265d494cc3","originalAuthorName":"王连蒙"},{"authorName":"高德青","id":"c3bcd75d-faf6-4a4a-968f-cafeef1dbab7","originalAuthorName":"高德青"}],"doi":"10.3969/j.issn.1004-0277.2008.03.007","fpage":"27","id":"0a38af49-d94f-4fb8-b91c-fa7e68ea24c2","issue":"3","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"8b06bcee-4922-4148-9885-ee07711c168f","keyword":"2-噻吩乙酸","originalKeyword":"2-噻吩乙酸"},{"id":"fbf18f97-8dff-4923-8475-756ac7e35f11","keyword":"1,10-邻菲啰啉","originalKeyword":"1,10-邻菲啰啉"},{"id":"6165f6d9-69b3-473e-b019-4a60eaba6e1a","keyword":"<span style=\"color:red\">铕</span>","originalKeyword":"铕"},{"id":"ac338a0a-b2d6-40fc-a17a-42466d24bb18","keyword":"<span style=\"color:red\">铽</span>","originalKeyword":"铽"}],"language":"zh","publisherId":"xitu200803007","title":"2-噻吩乙酸邻菲啰啉<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span><span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成表征及荧光性能研究","volume":"29","year":"2008"},{"abstractinfo":"合成了Eu(TFA)3(TPPO)2、Tb(TFA)3(TPPO)2三元<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>以及Eu1/2Tb1/2(TFA)3(TPPO)2三元双核<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>,并经元素分析、紫外-可见吸收光谱和红外透射光谱确认.研究了<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的发光性质,发现了该三元体系<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的摩擦发光现象,且三元双核<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>经摩擦发出明亮的白光.","authors":[{"authorName":"刘妍","id":"8e1efa8b-0e7f-454b-9a4a-ed57a40c1412","originalAuthorName":"刘妍"},{"authorName":"王怀善","id":"04ca3264-913b-4e32-b692-1dc565ae2922","originalAuthorName":"王怀善"},{"authorName":"李明","id":"04aa8d9c-0ddc-4d6b-bd10-b8fa056247a5","originalAuthorName":"李明"},{"authorName":"李娟","id":"1fdf5ae4-6027-4e08-90d0-e0af1f3e72b6","originalAuthorName":"李娟"},{"authorName":"钱国栋","id":"a81fa91e-c23c-40af-a4e4-0869c71214d5","originalAuthorName":"钱国栋"},{"authorName":"王民权","id":"a09fe803-f462-4c54-90ab-4ce32c9469e2","originalAuthorName":"王民权"}],"doi":"","fpage":"210","id":"0f26dba0-0354-416a-af38-2b3615a6f505","issue":"2","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"5ea4e850-2439-4540-90fa-633bafa9f2d5","keyword":"双核<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>","originalKeyword":"双核配合物"},{"id":"57559323-6d97-4140-805c-0d769fef5945","keyword":"发光性能","originalKeyword":"发光性能"},{"id":"bf36d891-dfdf-49c1-a08d-74558873a0e6","keyword":"摩擦发光","originalKeyword":"摩擦发光"}],"language":"zh","publisherId":"gncl200302034","title":"稀土(<span style=\"color:red\">铕</span>、<span style=\"color:red\">铽</span>)三元<span style=\"color:red\">配合</span><span style=\"color:red\">物</span>的合成、表征与发光性能","volume":"34","year":"2003"}],"totalpage":3979,"totalrecord":39783}