{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"在装饰性和PCB电镀中,酸性光亮镀铜的阳极最佳含磷量为0.035%~0.070%,磷化铜(Cu3P)黑膜的生成对于阳极性能具有决定性的意义.","authors":[{"authorName":"程良","id":"f6bdd735-7e31-4195-b4a4-c0f40f77833f","originalAuthorName":"程良"},{"authorName":"邝少林","id":"ed1fc513-24d1-451d-bc63-5b9ff0c609de","originalAuthorName":"邝少林"},{"authorName":"周腾芳","id":"d62c3a59-68e7-4222-a991-b2d629114f03","originalAuthorName":"周腾芳"}],"doi":"10.3969/j.issn.1004-227X.1999.02.006","fpage":"20","id":"d60abde1-b2ee-4ba2-8ce7-2f6a0a674a05","issue":"2","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"0c1d157c-2c49-42a4-bd6f-e32eb46eb160","keyword":"阳极磷铜","originalKeyword":"阳极磷铜"},{"id":"eb40ad6d-2f44-46aa-bad7-d8986e914fb7","keyword":"0.035%~0.070%","originalKeyword":"0.035%~0.070%"},{"id":"27a49c6e-e06f-4103-9f55-1468c00e46db","keyword":"磷含量","originalKeyword":"磷含量"}],"language":"zh","publisherId":"ddyts199902006","title":"再谈硫酸盐光亮镀铜的磷铜阳极","volume":"18","year":"1999"},{"abstractinfo":"论述了硫酸盐光亮镀铜磷铜阳极中磷的作用.对比了国内外酸性镀铜工艺磷铜阳极中磷含量的差异.指出在装饰性和印制线路板电镀中,酸性光亮镀铜的阳极最佳含磷量为0.035%~0.075%,磷化铜(Cu3P)黑膜的生成对阳极性能、工艺稳定及镀层质量有显著作用.最后说明了电镀中的注意要点.","authors":[{"authorName":"周腾芳","id":"fe3e8706-e7ff-45ba-a513-4be1af9c38df","originalAuthorName":"周腾芳"},{"authorName":"程良","id":"eda0283e-da4f-438c-9eb9-d6ef86ae74d6","originalAuthorName":"程良"},{"authorName":"邝少林","id":"20cf6c20-556c-4e33-8d85-68d8f480b5b2","originalAuthorName":"邝少林"}],"doi":"10.3969/j.issn.1001-1560.2001.10.013","fpage":"31","id":"bce6ff1c-3972-4b45-bab0-908abd73c856","issue":"10","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"61060f8c-985a-4caf-945f-c8ac9af2ee50","keyword":"磷铜阳极","originalKeyword":"磷铜阳极"},{"id":"cba936b4-99f1-4bc5-a044-deccf83796b3","keyword":"磷含量","originalKeyword":"磷含量"},{"id":"2b44f627-8ec3-4cdb-bd2d-364945ef7b01","keyword":"光亮镀铜","originalKeyword":"光亮镀铜"},{"id":"9b5294f0-5b18-4aef-8246-4553d17d1596","keyword":"硫酸盐","originalKeyword":"硫酸盐"}],"language":"zh","publisherId":"clbh200110013","title":"谈谈硫酸盐光亮镀铜的磷铜阳极","volume":"34","year":"2001"},{"abstractinfo":"主要探讨了影响电镀铜用磷铜阳极质量的因素,包括原材料、铜晶粒结构、磷含量及阳极表面的清洁.分别比较了某公司磷铜阳极标准与国内一般磷铜阳极标准、粗大铜晶粒结构与精细铜晶粒结构图,并将该公司揉制磷铜球黑膜形成及表面溶解状况与低质量轧制磷铜球进行了比较.介绍了优质铜阳极的特点:低金属杂质;铜晶粒精细、规整;磷铜阳极的磷含量为0.04%~0.065%且均匀分布等.","authors":[{"authorName":"张立伦","id":"0d356b12-49ef-4c3b-a830-acd6707e55f0","originalAuthorName":"张立伦"}],"doi":"10.3969/j.issn.1004-227X.2006.09.011","fpage":"35","id":"50ee232f-a15d-49c7-acb2-6bc3c2eaee64","issue":"9","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"1e550f5e-61ac-4100-baa3-665685f687b6","keyword":"酸性电镀铜","originalKeyword":"酸性电镀铜"},{"id":"64507912-5a75-4977-adb8-34e4d788ceb1","keyword":"磷铜阳极","originalKeyword":"磷铜阳极"},{"id":"428a0f80-fab6-4b4e-85b9-7fdedef30e81","keyword":"影响因素","originalKeyword":"影响因素"},{"id":"2b898085-23b1-4088-a350-7947c5aad418","keyword":"晶粒结构","originalKeyword":"晶粒结构"},{"id":"390e7978-b1e4-483c-b5a9-5a0ce096f138","keyword":"磷含量","originalKeyword":"磷含量"}],"language":"zh","publisherId":"ddyts200609011","title":"影响酸性电镀铜用磷铜阳极质量因素的探讨","volume":"25","year":"2006"},{"abstractinfo":"通过观察磷铜阳极表面的成膜情况来判断酸性光亮镀铜液中的氯离子含量.当镀液中的氯离子含量接近通常要求的上限或下限时,阳极表面的膜有明显变化,电镀产品则无明显变化.即阳极通常比阴极先反映出问题.本方法可及时指出因镀液中氯离子含量偏高或偏低引起的产品问题.","authors":[{"authorName":"蒋金鸿","id":"2e344f0b-8d0a-41a5-8526-30a0665f64d1","originalAuthorName":"蒋金鸿"}],"doi":"","fpage":"13","id":"78b5b969-9226-4996-a1c9-e8fee7132c17","issue":"5","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"da1d9779-24ca-4c1f-9bae-d524dcf6b877","keyword":"光亮酸性镀铜","originalKeyword":"光亮酸性镀铜"},{"id":"e7f2e64f-ef71-437b-8f56-3c7ab776b2d1","keyword":"磷铜阳极","originalKeyword":"磷铜阳极"},{"id":"5bdfbcc5-d12a-43a0-a526-d99f6b1481c0","keyword":"氯离子","originalKeyword":"氯离子"},{"id":"91be6db0-fa8b-4494-8618-b4d59a70cad1","keyword":"维护","originalKeyword":"维护"}],"language":"zh","publisherId":"ddyts201305003","title":"根据磷铜阳极维护酸性光亮镀铜液中的氯离子","volume":"32","year":"2013"},{"abstractinfo":"采用电化学联机测试系统对酸性硫酸盐镀铜工艺中含磷质量分数不同的铜阳极的电化学行为进行了阳极极化曲线和循环伏安曲线的对比研究,结果表明在酸性硫酸盐镀铜溶液中低质量分数磷铜阳极要比高质量分数磷铜阳极和纯铜阳极允许使用的阳极电流密度高,产生的Cu+离子更少,效果更好。","authors":[{"authorName":"刘学雷","id":"af2c7f23-5ffb-4248-8081-28faf69a914b","originalAuthorName":"刘学雷"},{"authorName":"钟强","id":"4ff2bd9f-8049-4b25-b5d9-7bf1a9899757","originalAuthorName":"钟强"},{"authorName":"王为","id":"06a57772-1c04-48bc-99b6-eac04f051e45","originalAuthorName":"王为"}],"doi":"10.3969/j.issn.1001-3849.2001.04.012","fpage":"36","id":"4b6e1a9f-a35e-4e00-9018-685736c3f5ee","issue":"4","journal":{"abbrevTitle":"DDYJS","coverImgSrc":"journal/img/cover/DDYJS.jpg","id":"20","issnPpub":"1001-3849","publisherId":"DDYJS","title":"电镀与精饰 "},"keywords":[{"id":"f60369bb-a1d3-4077-a134-4e05b321ef3e","keyword":"铜阳极","originalKeyword":"铜阳极"},{"id":"8dba5617-8fc6-455a-a4b4-fd469378c735","keyword":"磷的质量分数","originalKeyword":"磷的质量分数"},{"id":"d42c6857-0955-4bf1-875d-532ea4c5081b","keyword":"硫酸盐镀铜","originalKeyword":"硫酸盐镀铜"},{"id":"18fc9d90-3ea3-4fbc-82a5-4123f3afd485","keyword":"极化曲线","originalKeyword":"极化曲线"}],"language":"zh","publisherId":"ddjs200104012","title":"硫酸盐镀铜溶液中铜阳极性能研究","volume":"23","year":"2001"},{"abstractinfo":"硫酸盐镀铜铜阳极的含磷量究竟是采用低磷(0.02%~0.06%),还是采用高磷(0.1%~0.3%),一直以来,国内外观点各有不同,为了弄清含磷量高低铜阳极的性能差异,本文对用于硫酸盐镀铜的无氧钝铜阳极、高磷铜阳极和低磷铜阳极进行了电化学行为的对比研究,并结合对于不同含磷量铜阳极的组织结构分析,探讨了造成其性能差异的原因.","authors":[{"authorName":"王为","id":"579b6cd7-23b8-4ae5-a073-4d6d6db67aa0","originalAuthorName":"王为"},{"authorName":"刘学雷","id":"531a8cee-2260-4984-b986-5c41854034ea","originalAuthorName":"刘学雷"},{"authorName":"巩运兰","id":"139bc659-3427-4c82-9b58-86718871f12e","originalAuthorName":"巩运兰"},{"authorName":"钟强","id":"04d7c90b-f680-4b5d-8364-d5245e58e40a","originalAuthorName":"钟强"}],"doi":"10.3969/j.issn.1001-1560.2001.09.005","fpage":"10","id":"e80086ee-e211-45fd-8c3c-8e112d227caa","issue":"9","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"2052b1ad-2e22-4311-82f4-bd2aeba8e6c9","keyword":"磷铜阳极","originalKeyword":"磷铜阳极"},{"id":"e524b74b-eb4e-4570-9f67-9e2a312ae90c","keyword":"含磷量","originalKeyword":"含磷量"},{"id":"6cc69cb0-2f30-4cf7-871b-81850ba4e684","keyword":"硫酸盐镀铜","originalKeyword":"硫酸盐镀铜"}],"language":"zh","publisherId":"clbh200109005","title":"硫酸盐镀铜溶液中铜阳极性能的研究","volume":"34","year":"2001"},{"abstractinfo":"研究了磷锑钼三元杂多酸的形成条件及其还原产物的光度性质.实验结果表明,在0.45~0.65 mol/L的硫酸介质中,磷浓度介于0~7 μg/25ml范围内遵守比尔定律,相关系数r=0.999 96.大量铜(Ⅱ)的干扰可用空白试样来消除,应用于磷铜角中微量磷的测定,方法简便快速.","authors":[{"authorName":"丘山","id":"fab28cf8-bc26-4d07-a49a-6bdd7069dbcc","originalAuthorName":"丘山"},{"authorName":"丘星初","id":"e2940c9a-c42e-4c93-8916-699e5bee9a0f","originalAuthorName":"丘星初"},{"authorName":"黄曙明","id":"91650ce8-7f57-4299-89ce-e43756786ca6","originalAuthorName":"黄曙明"},{"authorName":"沙志勇","id":"8309ac2e-847e-4e6b-a644-a0a778821169","originalAuthorName":"沙志勇"}],"doi":"10.3969/j.issn.1001-1560.2002.12.024","fpage":"59","id":"559aa052-9e29-4574-857b-4af6eabe740a","issue":"12","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"9fda174e-8957-4de4-a9dc-4cbfcd4fb589","keyword":"磷","originalKeyword":"磷"},{"id":"bd975b81-6bb2-456b-b6fd-d673ab1556ef","keyword":"测定","originalKeyword":"测定"},{"id":"62973a93-d803-48c2-a462-f280e02c3047","keyword":"光度法","originalKeyword":"光度法"},{"id":"b95b29de-336a-4a80-990e-05a6cc73492d","keyword":"磷锑钼杂多酸","originalKeyword":"磷锑钼杂多酸"},{"id":"457c1402-eaa9-41a3-90e1-3262d25158c1","keyword":"磷铜角","originalKeyword":"磷铜角"}],"language":"zh","publisherId":"clbh200212024","title":"磷铜角中微量磷的快速测定","volume":"35","year":"2002"},{"abstractinfo":"通过测量阳极极化曲线、循环伏安曲线等电化学方法研究了酸性硫酸盐镀铜溶液中铜阳极的电化学行为,分析了镀液组成和工艺条件对铜阳极溶解和钝化过程的影响.结果表明,纯铜阳极在酸性硫酸盐溶液中发生电化学溶解的电势范围较窄,容易发生钝化,在阳极电势达3.0V(相对于饱和甘汞电极)后仍无过钝化或析氧现象.完全钝化的铜阳极重新通电后依然能发生正常的电化学溶解.磷铜阳极的电化学溶解性能稍好于纯铜阳极.增大硫酸铜质量浓度和加入添加剂HN-Super-A使铜阳极更易钝化,而增大硫酸质量浓度、加入添加剂HN-Super-Mμ和升温有利于铜阳极的电化学溶解.电镀过程中的电流密度不应超过铜阳极的临界钝化电流密度,否则铜阳极容易钝化.","authors":[{"authorName":"韩姣","id":"2a645a3f-568e-4a6d-a09b-da4684d3d238","originalAuthorName":"韩姣"},{"authorName":"曾振欧","id":"28a24a51-b197-4ca6-8270-8b583c2aa401","originalAuthorName":"曾振欧"},{"authorName":"谢金平","id":"230d5535-9eda-42f9-92b1-bed1cfa64cfa","originalAuthorName":"谢金平"},{"authorName":"范小玲","id":"66ec9a2f-925f-477e-8c67-ade36aff663d","originalAuthorName":"范小玲"}],"doi":"","fpage":"955","id":"700ab8da-ca0a-4674-9ae2-4abd603da027","issue":"17","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"47d32345-ea27-461c-8c21-4d1c5e7e88d7","keyword":"酸性镀铜","originalKeyword":"酸性镀铜"},{"id":"0bd6ab93-6bd0-43e7-acc0-518813a75771","keyword":"硫酸盐溶液","originalKeyword":"硫酸盐溶液"},{"id":"04a8dc5d-66bf-4bbb-9a16-d0b8767ae8be","keyword":"阳极","originalKeyword":"阳极"},{"id":"5528b51a-fc15-42c7-8acc-0166d84d6bbb","keyword":"纯铜","originalKeyword":"纯铜"},{"id":"f5043dad-b139-4663-943e-716e2bdd8682","keyword":"磷铜","originalKeyword":"磷铜"},{"id":"5fa8ec83-b99a-4c2b-bd1d-49b80641ae4a","keyword":"溶解","originalKeyword":"溶解"},{"id":"26d010ff-6be8-47d1-b6a2-d87a138c399f","keyword":"钝化","originalKeyword":"钝化"},{"id":"9d675883-d086-47c2-91a1-7ced32efef2f","keyword":"电化学","originalKeyword":"电化学"}],"language":"zh","publisherId":"ddyts201517001","title":"酸性硫酸盐体系镀铜中铜阳极的电化学行为","volume":"34","year":"2015"},{"abstractinfo":"将\"活性硫化镍法\"所用的除铜试剂\"硫化镍\"视为先导化合物,按电子等排原理,通过分子修饰进行类型衍化,修饰阴离子,以一种新设计的含硫化学结构取代S2-,得到的新型除铜剂为NAS和硫化镍混合物.结果表明:当NAS纯度α≥73%(NAS在混合物中所占比例)、除铜剂用量为理论量的1.2倍、溶液pH值为4.0、反应温度为60℃时反应80 min后,采用新型除铜剂从镍电解阳极液中除铜,除铜后溶液中的铜浓度c(Cu2+)可降至1.57×10-5mol/L,除铜渣中铜镍质量比不小于25,远优于工业生产的要求(c(Cu2+)≤1.57×10-5mol/L,渣中铜镍质量比不小于15);NAS在自然条件下放置62 d后,其除铜效果仍然能够满足生产要求,且NAS在除铜过程中没有引入有害离子进入溶液.","authors":[{"authorName":"赵中伟","id":"2ae89fa8-6915-4a6a-b455-3198e5519308","originalAuthorName":"赵中伟"},{"authorName":"陈爱良","id":"46a9d5f4-be21-4ddd-826f-a771426958b0","originalAuthorName":"陈爱良"},{"authorName":"孙培梅","id":"c30ef9e0-eedb-48b6-8c8f-55bcc0e24817","originalAuthorName":"孙培梅"},{"authorName":"陈星宇","id":"6441ed85-5f90-4036-b48b-3ed8011d3b39","originalAuthorName":"陈星宇"},{"authorName":"霍广生","id":"060cf074-7b48-48f6-9c60-63975a4f2963","originalAuthorName":"霍广生"},{"authorName":"李洪桂","id":"5614e5a8-bc93-4ad3-ac06-785c5f50a6fb","originalAuthorName":"李洪桂"}],"doi":"","fpage":"749","id":"3a9f939f-f580-400f-94af-769df83a8894","issue":"4","journal":{"abbrevTitle":"ZGYSJSXB","coverImgSrc":"journal/img/cover/ZGYSJSXB.jpg","id":"88","issnPpub":"1004-0609","publisherId":"ZGYSJSXB","title":"中国有色金属学报"},"keywords":[{"id":"a9959176-cd86-47c1-a102-ed5365af306b","keyword":"镍电解阳极液","originalKeyword":"镍电解阳极液"},{"id":"6807b4a6-3a0d-4247-9879-5c4797c32bb7","keyword":"除铜:电子等排原理","originalKeyword":"除铜:电子等排原理"}],"language":"zh","publisherId":"zgysjsxb200904025","title":"镍电解阳极液深度除铜","volume":"19","year":"2009"},{"abstractinfo":"分析了铜阳极泥预处理过程中有价元素Cu、Te、As的分布状况及工艺存在的问题,提出了铜阳极泥预处理过程工艺优化方案.结果表明:优化后,中间物料如吸收后液、银过量还原后液等得到充分利用,工艺过程试剂消耗为零.同时,脱铜渣含铜可稳定控制在6%左右,并回收了部分Au、Ag物料,提高了Au、Ag的回收率. ","authors":[{"authorName":"胡建辉","id":"d36af0e8-f397-42bb-8eb6-c5a47f6cc74b","originalAuthorName":"胡建辉"},{"authorName":"张传福","id":"7eabff72-0a7e-48f8-9ac2-6fa71a6494b8","originalAuthorName":"张传福"}],"doi":"10.3969/j.issn.1004-0676.2002.04.001","fpage":"1","id":"98e42f4b-e989-4f30-a919-da6241947c0a","issue":"4","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"43c9f17e-90cb-430f-9fd1-17118a39b340","keyword":"阳极泥","originalKeyword":"阳极泥"},{"id":"b4c2e178-10b1-4e00-a81b-25186c574b92","keyword":"预处理","originalKeyword":"预处理"},{"id":"bc4b3063-a8fb-4b1d-9b59-1596540eb9c9","keyword":"铜","originalKeyword":"铜"},{"id":"aa1476f8-dadc-499d-951d-c51a113525a0","keyword":"砷","originalKeyword":"砷"},{"id":"964dd79c-85ef-43fc-a921-a7d1aa4de958","keyword":"碲","originalKeyword":"碲"},{"id":"41023ef2-5525-42ac-ab3d-7fa260b5d18c","keyword":"优化","originalKeyword":"优化"}],"language":"zh","publisherId":"gjs200204001","title":"铜阳极泥预处理脱铜工艺优化","volume":"23","year":"2002"}],"totalpage":1316,"totalrecord":13158}