{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"从力学和耐蚀性能方面,综述了Ni-P二元化学镀层三元化学镀层化学复合镀层的研究现状。对于不同基材上的二镀层,表面钝化剂、络合剂和热处理影响碳钢二镀层的力学与耐蚀性能;表面阳极化、激光表面合金化和热处理影响铝合金二镀层的附着力、耐蚀性与硬度;表面阳极活化和热处理影响不锈钢二镀层的结合力与硬度。对于三元镀层,热处理和激光晶化影响Ni-W-P三元镀层的耐磨性与耐蚀性;含Mo元素的Ni-Mo-P三元镀层在不同温度下热处理后,均表现出良好的耐蚀性;稀土金属氧化物可改变三元化学镀层的镀速、表面质量、晶体结构与耐蚀性能。对于复合镀层,由于添加了 SiC, SiO2,WC 和PTFE等不溶性粒子,因此硬度、耐磨性、耐蚀性和自润滑性得到提高。三元化学镀层化学复合镀层的力学和耐蚀性能明显优于二元化学镀层,是Ni-P化学镀研究和发展的方向。","authors":[{"authorName":"张冠军","id":"1a5a5776-4f6b-4060-ae5b-5bd0e4b4d2b1","originalAuthorName":"张冠军"},{"authorName":"来维亚","id":"626aead9-6f6e-4fb2-b872-2cb5827b7421","originalAuthorName":"来维亚"},{"authorName":"尹成先","id":"232fe5e7-7832-4ac5-a58f-52dd50faa944","originalAuthorName":"尹成先"},{"authorName":"徐秀清","id":"a8751c0e-afd5-4d0d-be78-727ddc0469ce","originalAuthorName":"徐秀清"}],"doi":"10.16490/j.cnki.issn.1001-3660.2016.02.002","fpage":"8","id":"ea0dc8d9-22a2-40e5-a665-d21a692ea4b4","issue":"2","journal":{"abbrevTitle":"BMJS","coverImgSrc":"journal/img/cover/BMJS.jpg","id":"3","issnPpub":"1001-3660","publisherId":"BMJS","title":"表面技术 "},"keywords":[{"id":"bb86be44-8134-4fb6-8681-796cc59beca6","keyword":"Ni-P化学镀层","originalKeyword":"Ni-P化学镀层"},{"id":"17577ca2-e9ba-45b3-93bc-4f87e82652f1","keyword":"三元化学镀层","originalKeyword":"三元化学镀层"},{"id":"093fff08-165e-4836-94e0-97a8ece2be75","keyword":"化学复合镀层","originalKeyword":"化学复合镀层"},{"id":"1bd2f5d4-64b6-4e48-a798-e76be7dc117c","keyword":"耐蚀性","originalKeyword":"耐蚀性"},{"id":"1ec8ac46-fdb6-4559-bbe7-5ece94bbf079","keyword":"耐磨性","originalKeyword":"耐磨性"}],"language":"zh","publisherId":"bmjs201602004","title":"金属表面Ni-P化学镀层研究现状","volume":"","year":"2016"},{"abstractinfo":"用SEM,TEM,DTA,XRD等方法研究了化学镀Ni-Cr-P三元合金镀层的形貌和结构变化.结果表明,镀层组成均匀,呈非晶态结构,初始晶化温度为270.7 ℃,热处理可使镀层析出晶态Ni相和Ni3P相,高温热处理条件下还有晶态Cr相和Cr3P相析出.","authors":[{"authorName":"杨玉国","id":"f8468976-4a8e-4fce-8eed-2c131c42c0dd","originalAuthorName":"杨玉国"},{"authorName":"孙冬柏","id":"7056582c-18cc-4a6d-9036-d22a551124fe","originalAuthorName":"孙冬柏"},{"authorName":"杨德钧","id":"4d8411b2-3942-441a-be09-1fb87b84a212","originalAuthorName":"杨德钧"}],"doi":"10.3969/j.issn.1001-1560.1999.10.005","fpage":"10","id":"6e865f4b-33f6-4faa-a5b2-570589340bd1","issue":"10","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"98228a6e-9bd7-4f38-862d-53194480a317","keyword":"化学镀","originalKeyword":"化学镀"},{"id":"04cbbee3-0faf-4b4e-9e17-e3bf42d6c3a3","keyword":"Ni-Cr-P合金","originalKeyword":"Ni-Cr-P合金"},{"id":"47ba2f94-9257-46de-9b80-909488116295","keyword":"组织","originalKeyword":"组织"}],"language":"zh","publisherId":"clbh199910005","title":"Ni-Cr-P三元合金化学镀层的组织结构","volume":"32","year":"1999"},{"abstractinfo":"为得到电磁性能优良的碳纳米管,采用化学镀的方法在碳纳米管表面镀镍-钴-磷三元合金.利用透射电镜(TEM)、能谱分析(EDS)、振动样品磁强计(VSM)对施镀后的碳纳米管进行表征,发现所得镀层完整、均匀,为软磁材料.碳纳米管化学镀Ni-Co-P三元合金的电磁参数研究表明,其吸波机理主要为磁损耗.","authors":[{"authorName":"王广征","id":"b0244b8f-cce9-4ecf-9e00-1b0abadd1fa3","originalAuthorName":"王广征"},{"authorName":"黄英","id":"c6de0a81-ed66-41b6-97c4-18964063efa6","originalAuthorName":"黄英"},{"authorName":"孙晓峰","id":"4b184014-e532-4585-b29a-701e1b34bd3e","originalAuthorName":"孙晓峰"}],"doi":"10.3969/j.issn.1003-1545.2011.03.010","fpage":"34","id":"8650d6ac-733e-4480-abcc-d93155512ebc","issue":"3","journal":{"abbrevTitle":"CLKFYYY","coverImgSrc":"journal/img/cover/CLKFYYY.jpg","id":"10","issnPpub":"1003-1545","publisherId":"CLKFYYY","title":"材料开发与应用"},"keywords":[{"id":"cae8b56e-bf12-4c3c-b93b-794d7b16f4ce","keyword":"碳纳米管","originalKeyword":"碳纳米管"},{"id":"144c111b-ad34-44e1-9a8b-fe7843b97cb7","keyword":"化学镀","originalKeyword":"化学镀"},{"id":"62149a55-053e-4a8b-82a7-fcd3530e6839","keyword":"镍-钴-磷三元合金","originalKeyword":"镍-钴-磷三元合金"},{"id":"a3c8458d-62de-4f0b-9456-0cbaefa7c628","keyword":"吸波","originalKeyword":"吸波"}],"language":"zh","publisherId":"clkfyyy201103010","title":"碳纳米管化学镀Ni-Co-P三元合金","volume":"26","year":"2011"},{"abstractinfo":"为提高化学镀镍-磷合金镀层的性能及获得多种性能的合金镀层以拓宽其应用范围.在化学镀镍-磷合金液中加入硫酸铜制得镍-铜-磷三元合金.研究了镀液中硫酸镍、次磷酸钠、柠檬酸钠、硫酸铜、稳定剂、光亮剂的含量以及pH值和温度等因素对合金镀层的外观、沉积速度及铜含量的影响.通过5% 氯化钠溶液和10%硫酸溶液浸泡试验比较了所得镍-铜-磷合金镀层与镍-磷合金镀层以及前人制得的镍-磷合金镀层的耐蚀性,同时比较了上述镀层的其它性能.结果表明,所得镍-铜-磷合金镀层的耐蚀性、外观、结合力、孔隙率、沉积速度、硬度和耐磨性等性能优于镍-磷合金及前人制得的镍-铜-磷合金镀层.","authors":[{"authorName":"肖鑫","id":"1be6f1df-e686-4cfa-b9b9-cf04a8126d23","originalAuthorName":"肖鑫"},{"authorName":"秦灏","id":"21ee642e-6e58-444d-b485-70235fac07ba","originalAuthorName":"秦灏"},{"authorName":"郭贤烙","id":"3a1ebb88-3488-4044-a9fc-abe0a9cb4117","originalAuthorName":"郭贤烙"},{"authorName":"易翔","id":"1edbdb4c-75c5-4716-ac3d-2c685cb901db","originalAuthorName":"易翔"}],"doi":"10.3969/j.issn.1004-227X.2003.01.005","fpage":"15","id":"93a39adc-7810-4d37-a990-dc2c7215baf8","issue":"1","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"46f67940-9466-4da7-a945-a3bf48331817","keyword":"镍-铜-磷","originalKeyword":"镍-铜-磷"},{"id":"3ccff181-c162-4fbe-905f-c3bcd9eed7dd","keyword":"化学镀","originalKeyword":"化学镀"},{"id":"3d21f815-b6ce-4795-9e41-366e7979c8f3","keyword":"三元合金","originalKeyword":"三元合金"}],"language":"zh","publisherId":"ddyts200301005","title":"化学镀镍-铜-磷三元合金工艺的研究","volume":"22","year":"2003"},{"abstractinfo":"为提高化学镀镍的硬度、耐磨及耐蚀性,以拓宽其在电子工业中的应用,采用在化学镀镍磷合金液中添加适量的铜离子制得镍铜磷三元合金.研究了镍离子与铜离子浓度比、次磷酸钠含量、柠檬酸钠添加量、沉积温度对合金镀层沉积速率的影响,利用S-570扫描电镜和H-800透射电镀观察了镀层表面形貌和显微组织,通过硝酸腐蚀试验比较了镍磷合金与镍铜磷合金镀层的耐蚀性.结果表明:铜的共沉积能明显提高镍磷合金的耐蚀性.","authors":[{"authorName":"吴玉程","id":"54d7f42f-34ac-4228-a396-0d996d1d4c59","originalAuthorName":"吴玉程"}],"doi":"10.3969/j.issn.1004-227X.2000.02.001","fpage":"1","id":"44774d5f-baa1-4a70-a3e3-612a41396839","issue":"2","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"e76e4110-2cd4-4dca-97e9-ffa896f35a3e","keyword":"化学镀镍","originalKeyword":"化学镀镍"},{"id":"2aa5f685-9726-4901-8aee-5976c43989f3","keyword":"镍铜磷","originalKeyword":"镍铜磷"},{"id":"cf7c8be2-222f-4cdd-a7f2-84db5e894cf8","keyword":"三元合金","originalKeyword":"三元合金"}],"language":"zh","publisherId":"ddyts200002001","title":"化学镀镍铜磷三元合金沉积工艺的研究","volume":"19","year":"2000"},{"abstractinfo":"研究了镀液配方对化学镀Ni-Zn-P三元合金施镀效果的影响,探明了镀速、镀层硬度及其腐蚀防护性,以及镀层Ni,Zn和P含量的变化规律,确定了含Zn 9.50~16.57和P 7.55~13.59(质量分数,%)的Ni-Zn-P镀层制备工艺.对典型试样进行了SEM和XRD分析以及耐酸、耐碱及耐盐溶液腐蚀性能测试,结果表明:镀层表面平整、均匀,结构致密,具有典型的胞状/球状及条带状微观形貌;镀层主要由非晶、微晶或其混合相组成,其中Zn和P固溶于fcc的Ni晶格中;镀层耐盐、耐碱腐蚀能力较强.","authors":[{"authorName":"张永君","id":"277246c0-7cf1-46e5-bbf0-2ee02cda44ba","originalAuthorName":"张永君"},{"authorName":"赵翠玲","id":"2756f7f1-8eeb-4c6b-afec-792e9af9cb4f","originalAuthorName":"赵翠玲"},{"authorName":"李茂东","id":"79d9848d-6553-483b-a2eb-98613ea07754","originalAuthorName":"李茂东"},{"authorName":"马括","id":"ba878e5a-b1a0-4afd-8a93-8aff48952b09","originalAuthorName":"马括"},{"authorName":"王磊","id":"7551f109-ddad-4ad8-ae5d-1790fb0b7078","originalAuthorName":"王磊"},{"authorName":"倪进飞","id":"fb445e05-6c69-4f06-bf62-e20efb7f0a93","originalAuthorName":"倪进飞"},{"authorName":"夏兰梅","id":"01a504a3-7c0f-4d7b-849a-b42874e33c41","originalAuthorName":"夏兰梅"}],"doi":"10.11903/1002.6495.2015.196","fpage":"206","id":"1f2a8312-a6cc-4721-8750-7f0f27e18995","issue":"3","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报(英文)"},"keywords":[{"id":"5c437d5a-1e06-4479-b803-76a9715792d7","keyword":"化学镀","originalKeyword":"化学镀"},{"id":"1d6ac127-f496-465c-8f65-da2cc5828ed6","keyword":"Ni-Zn-P合金","originalKeyword":"Ni-Zn-P合金"},{"id":"cf7008dd-3b86-489a-a164-37aab41cc272","keyword":"镀液配方","originalKeyword":"镀液配方"},{"id":"e899f8b8-ebdf-4c2b-80be-6776cf2cf2ce","keyword":"镀速","originalKeyword":"镀速"}],"language":"zh","publisherId":"fskxyfhjs201603003","title":"Ni-Zn-P三元合金化学镀镀液配方优化研究","volume":"28","year":"2016"},{"abstractinfo":"研究了镁及镁合金的化学镀Ni-Cu-P三元合金工艺, 通过正交试验获得了最佳的镀覆条件.并对镀层的组织结构及其性能进行了测试,所得的Ni-Cu-P三元非晶态镀层结合力好,具有良好的导电性和耐蚀性能.","authors":[{"authorName":"贾志华","id":"43857280-60df-4173-bb6a-dad2861d1ac0","originalAuthorName":"贾志华"},{"authorName":"王玉平","id":"6e1f200d-a34c-491a-9446-920f29dd29ed","originalAuthorName":"王玉平"}],"doi":"10.3969/j.issn.1004-227X.2004.03.003","fpage":"6","id":"4d25b501-a21d-4aef-8579-990f7c288e7a","issue":"3","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"129b700f-5af4-4795-ad73-d592348cad26","keyword":"镁","originalKeyword":"镁"},{"id":"7990f6b1-feb0-46ab-9af5-a69bfd3e03d9","keyword":"镁合金","originalKeyword":"镁合金"},{"id":"95c3f806-6a08-4474-bf83-1732901bed02","keyword":"化学镀","originalKeyword":"化学镀"},{"id":"6efbcd4b-2289-427c-b9d4-ff002a92cc20","keyword":"Ni-Cu-P","originalKeyword":"Ni-Cu-P"}],"language":"zh","publisherId":"ddyts200403003","title":"镁及镁合金化学镀Ni-Cu-P三元合金工艺","volume":"23","year":"2004"},{"abstractinfo":"目的:优化中温化学镀三元络合剂体系,得到性能优良的化学镀镍层。方法选取乳酸、冰乙酸及柠檬酸作为络合剂组分,以镀速和含磷量为考察指标,通过设计 L9(34)正交实验,研究次亚磷酸钠、乳酸、冰乙酸及柠檬酸的浓度对化学镀镀速以及镀层磷含量的影响。结果综合考虑镀速和磷含量,得到的最佳三元络合剂体系为20 mL/ L 乳酸+15 mL/ L 冰乙酸+10 g/ L 柠檬酸,该条件下镀速为6.4 mg/ h,镀层磷质量分数为8.8%。结论采用优化的络合剂体系,可以获得致密均匀、结合力良好的化学镀镍层。","authors":[{"authorName":"刘鹏","id":"b4132235-2186-4f68-84d0-daf51f12fb4b","originalAuthorName":"刘鹏"},{"authorName":"杨伏良","id":"c8b2b5d7-3374-46fa-8f9f-4239fbe16ca6","originalAuthorName":"杨伏良"}],"doi":"","fpage":"66","id":"38650e79-245e-4c04-a693-6cdd863cc5f6","issue":"5","journal":{"abbrevTitle":"BMJS","coverImgSrc":"journal/img/cover/BMJS.jpg","id":"3","issnPpub":"1001-3660","publisherId":"BMJS","title":"表面技术 "},"keywords":[{"id":"b821745f-bb37-4306-b1d3-348bccbcd61b","keyword":"化学镀","originalKeyword":"化学镀"},{"id":"fc470667-25d1-4438-ac09-e62aa7c21993","keyword":"镀镍","originalKeyword":"镀镍"},{"id":"aaf3d27d-c997-4fc5-bf9c-60f974483f6a","keyword":"三元络合剂","originalKeyword":"三元络合剂"},{"id":"179e725b-139f-49fa-8238-2a3c616a519b","keyword":"镀速","originalKeyword":"镀速"},{"id":"0a5fb012-2c1b-46fb-923d-8be008c40c9c","keyword":"磷含量","originalKeyword":"磷含量"}],"language":"zh","publisherId":"bmjs201405015","title":"氧化锆陶瓷中温化学镀三元络合剂的研究","volume":"","year":"2014"},{"abstractinfo":"采用化学镀方法,在A3钢表面制备Ni-Fe-P三元合金,通过SEM,EDS,XRD,OM等表征手段对合金镀层成分、结构和形貌进行分析,并使用增重法、氯化钯加速法分别对镀层的沉积速率、镀液的稳定性进行分析.探讨了主盐、还原剂、络合剂、稳定剂、pH值、温度等工艺参数对沉积速率、镀层形貌、成分、镀液稳定性的影响,获得了镀速快、镀层均匀、镀液稳定性好的工艺配方.在采用复合络合剂的体系中,当主络合剂柠檬酸钠的浓度为60g/L,辅助络合剂氨基乙酸的浓度为5g/L时,化学镀沉积速率可以达到20.2mg·cm-2·h-1,并且镀液保持了较好的稳定性.","authors":[{"authorName":"李松梅","id":"547ebaa5-dab2-4e98-ab52-724eefc1adc5","originalAuthorName":"李松梅"},{"authorName":"韩宇","id":"e052d150-318d-450d-afc2-0a89ae16f5fa","originalAuthorName":"韩宇"},{"authorName":"刘建华","id":"843286de-1250-420a-80d4-3b0770e7680c","originalAuthorName":"刘建华"},{"authorName":"于美","id":"e129eb87-b9a9-45c1-988c-d9434325340c","originalAuthorName":"于美"}],"doi":"10.3969/j.issn.1001-4381.2010.08.011","fpage":"44","id":"4a41eaa6-07b1-4750-a507-14b321bdbeb7","issue":"8","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"6585e844-2fb5-4e94-a279-78b61bcd6e18","keyword":"化学镀Ni-Fe-P","originalKeyword":"化学镀Ni-Fe-P"},{"id":"8130e6f2-f6cd-48b9-977c-75e5e1253f9d","keyword":"镀速","originalKeyword":"镀速"},{"id":"ea0e4ac2-7d92-48b4-b013-6c6c38f39c2a","keyword":"稳定性","originalKeyword":"稳定性"},{"id":"824b69fd-2ead-4139-a94b-af4161d3ebdc","keyword":"参数","originalKeyword":"参数"},{"id":"dfb2e8c2-03ee-4233-858d-8bf8adc2421c","keyword":"工艺","originalKeyword":"工艺"}],"language":"zh","publisherId":"clgc201008011","title":"Ni-Fe-P三元合金的快速化学镀制备工艺研究","volume":"","year":"2010"},{"abstractinfo":"在铝合金表面化学镀Ni-W-P三元合金,通过X射线衍射(XRD)、扫描电镜(SEM)、差热分析(DTA)等测试手段对镀层的形貌、成分、组织结构及性能进行了研究.结果表明:镀层完全覆盖基体,表面由胞状物组成,光亮均匀,颗粒平均直径约为7 μm.镀态时,镀层硬度达到HV610左右,属于均一单相体系,有较高的耐腐蚀性;若在380℃进行热处理,镀层中有Ni和Ni3P晶体析出,硬度达到HV920左右.环境温度较高时,W的沉积可阻碍Ni3P的析出,延滞Ni合金的晶化过程,使得Ni-W-P镀层比Ni-P镀层具有更好的热稳定性.","authors":[{"authorName":"姚怀","id":"66cc06c9-fd6b-449f-99f3-01859613f700","originalAuthorName":"姚怀"},{"authorName":"苌清华","id":"69cbb06b-fcac-444b-87df-45d886f5701e","originalAuthorName":"苌清华"},{"authorName":"王喜然","id":"879d1de2-66e2-476d-936f-aee6b20ab13e","originalAuthorName":"王喜然"}],"doi":"10.3969/j.issn.1001-3660.2010.03.008","fpage":"26","id":"2088482c-cd97-4fc5-9387-6e1e69564344","issue":"3","journal":{"abbrevTitle":"BMJS","coverImgSrc":"journal/img/cover/BMJS.jpg","id":"3","issnPpub":"1001-3660","publisherId":"BMJS","title":"表面技术 "},"keywords":[{"id":"7d314607-e379-45f7-95ab-5f35873e871f","keyword":"化学镀","originalKeyword":"化学镀"},{"id":"cf1e7d12-28a5-4aaf-8cad-0743eb54c7ac","keyword":"Ni-W-P合金","originalKeyword":"Ni-W-P合金"},{"id":"d07ea743-4be6-4cde-a89f-c6a80cd99a18","keyword":"组织结构","originalKeyword":"组织结构"},{"id":"d0cfd2cb-f412-4faa-9417-b2ba42f9c576","keyword":"性能","originalKeyword":"性能"}],"language":"zh","publisherId":"bmjs201003008","title":"铝合金化学镀Ni-W-P三元合金组织及性能的研究","volume":"39","year":"2010"}],"totalpage":5839,"totalrecord":58386}