{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"对采用流态化技术,还原多钒酸铵(APV)制取三氧化二钒工艺及相关参数进行了研究,得到了合格的三氧化二钒产品.试验表明: APV在还原温度700~750 ℃、保温时间10~15 min的条件下可以得到TV≥63%的三氧化二钒产品,比回转窑方法所需时间短、温度低;更容易实现对温度和时间的控制,得到较高品位的三氧化二钒产品(TV>67%);流态化生产的三氧化二钒产品C含量低,更有利于钒铁冶炼对C含量的控制;同时,流态化生产三氧化二钒效率高、还原剂消耗少、设备固定、相对安全性更高.","authors":[{"authorName":"张帆","id":"6577b0c8-80d6-4c2c-bfbe-554caedf98c3","originalAuthorName":"张帆"}],"doi":"","fpage":"27","id":"3a2cc00c-033f-4900-bc20-557155ce9a11","issue":"3","journal":{"abbrevTitle":"GTFT","coverImgSrc":"journal/img/cover/gtft1.jpg","id":"28","issnPpub":"1004-7638","publisherId":"GTFT","title":"钢铁钒钛"},"keywords":[{"id":"49287363-765d-4c5d-87ab-a21af0ffe05e","keyword":"三氧化二钒","originalKeyword":"三氧化二钒"},{"id":"b8cdd8b9-ecae-46cd-9dfc-4e56b797b047","keyword":"流态化床","originalKeyword":"流态化床"},{"id":"2fb76fff-884f-43f3-b281-76ace9c734dc","keyword":"多钒酸铵","originalKeyword":"多钒酸铵"}],"language":"zh","publisherId":"gtft200803006","title":"流态化制取三氧化二钒研究","volume":"29","year":"2008"},{"abstractinfo":"介绍了以三氧化二钒为原料电硅热法生产中钒铁(FeV50)工艺,探讨了配硅系数和炉渣组成对FeV50冶炼的影响.稳定试验结果表明,按照试验提供的工艺参数,可以稳定地获得质量符合GB4139-87标准的钒铁产品,钒的平均回收率为96.84%.","authors":[{"authorName":"杨仰军","id":"64e2c93d-c390-4ad4-9ed5-0376fab78213","originalAuthorName":"杨仰军"},{"authorName":"孙朝晖","id":"bd35defb-4946-4110-bccf-45879576c2ec","originalAuthorName":"孙朝晖"},{"authorName":"唐洪国","id":"8e7eae43-349f-4d57-881b-7012bb842ed2","originalAuthorName":"唐洪国"},{"authorName":"杜勇","id":"977661b8-f22d-4ba8-8e8d-762c1331f50b","originalAuthorName":"杜勇"}],"doi":"10.3969/j.issn.1004-7638.2003.02.005","fpage":"19","id":"7fd3f5d2-9be2-433d-9203-3a2eb76df7e8","issue":"2","journal":{"abbrevTitle":"GTFT","coverImgSrc":"journal/img/cover/gtft1.jpg","id":"28","issnPpub":"1004-7638","publisherId":"GTFT","title":"钢铁钒钛"},"keywords":[{"id":"af8f0826-877f-4ff9-8c18-9aa2dae19569","keyword":"三氧化二钒","originalKeyword":"三氧化二钒"},{"id":"8c1489e8-2ba9-4ff3-bbc1-a81a511714de","keyword":"FeV50","originalKeyword":"FeV50"},{"id":"8f31c4d8-bf8d-4e7d-8821-8eec3f3e3b84","keyword":"电硅热法","originalKeyword":"电硅热法"},{"id":"e2cad0ae-33cb-4d28-a946-796132a00c87","keyword":"冶炼","originalKeyword":"冶炼"}],"language":"zh","publisherId":"gtft200302005","title":"用三氧化二钒电硅热法冶炼FeV50试验研究","volume":"24","year":"2003"},{"abstractinfo":"通过水解硫酸氧钒,在不加入还原剂条件下合成了三氧化二钒粉体,研究不同烧结温度以及气氛对产物的影响;对产物进行X射线衍射分析、扫描电镜形貌观察和激光粒度仪粒度检测,结果表明:在不同的气氛中,以5℃/min的升温速度,由室温升至800℃并保温3h得到的产物不同.在氩气流量为160 mL/min的气氛中得到V4O7粉体;而在真空中煅烧的产物是V2O3粉体,其在玛瑙研钵中研磨20 min平均直径为452 nm.确定了水解硫酸氧钒获得氢氧化钒沉淀的最佳pH值约为4.","authors":[{"authorName":"仝俊峰","id":"69f7183c-d20a-4860-874e-ad553143d643","originalAuthorName":"仝俊峰"},{"authorName":"赵红雨","id":"6157f7b0-a3dc-4eb5-a343-c2494c831d4f","originalAuthorName":"赵红雨"},{"authorName":"栗正新","id":"849053e3-4d4f-4270-8fe5-d0ec69b0f094","originalAuthorName":"栗正新"}],"doi":"10.7513/j.issn.1004-7638.2014.03.003","fpage":"10","id":"2bc72fdd-5cc8-4516-9107-1dfae51540d2","issue":"3","journal":{"abbrevTitle":"GTFT","coverImgSrc":"journal/img/cover/gtft1.jpg","id":"28","issnPpub":"1004-7638","publisherId":"GTFT","title":"钢铁钒钛"},"keywords":[{"id":"df29569c-6c7b-416e-b47b-887b509bd441","keyword":"硫酸氧钒","originalKeyword":"硫酸氧钒"},{"id":"37e90549-d80b-4e1e-8f4e-b06cfbac5069","keyword":"水解法","originalKeyword":"水解法"},{"id":"a8fa25c9-5fd0-4d1b-870d-4ca7c1c8cf57","keyword":"三氧化二钒","originalKeyword":"三氧化二钒"}],"language":"zh","publisherId":"gtft201403003","title":"水解法制备三氧化二钒粉体","volume":"35","year":"2014"},{"abstractinfo":"以V2O3为原料, 采用真空还原方法制备出碳化钒, 生成的碳化钒直接进行渗氮制备出碳氮化钒. 结果表明, 原料中的配碳量是控制反应产物中氮含量的关键因素. 氮化温度影响产物中氮含量, 低温条件下, 随氮化温度提高氮含量增加, 但当反应温度高到一定程度, 氮含量不再随温度提高而增加. 氮化温度在1400 ℃时, 4 h可以氮化完全. ","authors":[{"authorName":"卢志玉","id":"e108402e-f8f1-4020-ab37-9bcb70e9aac6","originalAuthorName":"卢志玉"},{"authorName":"罗冬梅","id":"b5e656a9-b6fc-481b-ba57-81e78d205e8a","originalAuthorName":"罗冬梅"},{"authorName":"都兴红","id":"9d4b1760-9881-4d77-830a-5915a998b12a","originalAuthorName":"都兴红"},{"authorName":"陈厚生","id":"80826143-d754-48bf-afaf-20e2655663c4","originalAuthorName":"陈厚生"},{"authorName":"隋智通","id":"ea693074-4916-4154-96c3-e1f0d8c10186","originalAuthorName":"隋智通"}],"doi":"10.3969/j.issn.0258-7076.2003.01.051","fpage":"193","id":"01c90ca6-d3a9-41dc-9b67-8ac1eb4c6b11","issue":"1","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"a8e712eb-78e1-43d6-adb0-2736396ec11b","keyword":"三氧化二钒","originalKeyword":"三氧化二钒"},{"id":"680a3330-624f-4b5e-83cb-e60f5aeca6ef","keyword":"碳化钒","originalKeyword":"碳化钒"},{"id":"c88f2fea-5033-4b37-9315-7c8740738095","keyword":"氮化钒","originalKeyword":"氮化钒"},{"id":"0fd77b63-fdaf-4777-b441-cbf2daf1862d","keyword":"碳氮化钒","originalKeyword":"碳氮化钒"}],"language":"zh","publisherId":"xyjs200301051","title":"由三氧化二钒制备碳氮化钒的研究","volume":"27","year":"2003"},{"abstractinfo":"研究了化学纯V2O3在氧压碱浸过程中钒的非等温溶解动力学.考察了搅拌转速(200-1000 r·min-1)、氧分压(200-700 kPa),NaOH浓度(0.1-2.0 mol·L-1)和升温速率(1.31-4.01 K·min-1)对钒溶解率的影响.实验结果表明,降低升温速率或增大氧气压力,可以提高钒浸出率;搅拌转速在800 r·min-1以上或NaOH浓度高于0.5 mol ·L-1时对反应速率的影响可以忽略.采用一种非等温动力学模型来描述该反应过程.得到了4种不同升温速率下碱液浸取提钒的动力学方程式.动力学分析结果显示,在室温与423 K之间,该浸出过程的平均表观活化能E为36.62-37.52 kJ·mol-1.从而证实了在实验条件下.溶解过程的控制步骤为化学反应与扩散混合控制.反应中氧分压和NaOH浓度的反应级数分别为0.74和0.","authors":[{"authorName":"邱爽","id":"5a0c8bb8-9617-4dfb-a07f-3071b16085fa","originalAuthorName":"邱爽"},{"authorName":"魏昶","id":"664a2c10-fee8-46a3-8799-4d7a1660e390","originalAuthorName":"魏昶"},{"authorName":"李旻廷","id":"dcfecfd5-40f6-4a2a-8439-55624b403035","originalAuthorName":"李旻廷"},{"authorName":"周雪娇","id":"374aaa39-296f-41a3-9f9a-ae98a229e04a","originalAuthorName":"周雪娇"}],"doi":"10.3969/j.issn.0258-7076.2011.02.021","fpage":"269","id":"77da1857-e3c2-458f-b75c-fdba271260c4","issue":"2","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"07cc6ef9-cb6b-41b8-9fcd-a56e0207af4b","keyword":"三氧化二钒","originalKeyword":"三氧化二钒"},{"id":"48deb87b-5c12-4b28-9e52-23e53e28947e","keyword":"溶解","originalKeyword":"溶解"},{"id":"a2abab1a-8b5f-45b5-83b8-7f4b7607ba54","keyword":"压力氧化","originalKeyword":"压力氧化"},{"id":"f730e2cc-5508-45b9-a020-fd22549e6a21","keyword":"氢氧化钠","originalKeyword":"氢氧化钠"},{"id":"76a1a1d8-4740-4dd2-8437-d6a7829fec41","keyword":"动力学","originalKeyword":"动力学"}],"language":"zh","publisherId":"xyjs201102021","title":"三氧化二钒的非等温氧压碱溶动力学研究","volume":"35","year":"2011"},{"abstractinfo":"经溶解、过滤、洗涤等条件及共存离子干扰影响等试验,提出测定 五氧化二钒产品中三价钒量的容量法,结果满意。","authors":[{"authorName":"唐华应","id":"fbe63468-c907-4220-9c13-6cd55d6a7a4a","originalAuthorName":"唐华应"}],"doi":"10.3969/j.issn.1000-7571.2001.02.025","fpage":"63","id":"e77548c2-2d39-49ff-baa5-223aabdba82a","issue":"2","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析 "},"keywords":[{"id":"1be55fc2-f906-4d61-a19c-19f50c3e5e95","keyword":"五氧化二钒","originalKeyword":"五氧化二钒"},{"id":"bac15417-6946-4e24-8f51-f75d6b2c56d0","keyword":"硫酸亚铁铵","originalKeyword":"硫酸亚铁铵"},{"id":"2f8d273d-5d4c-47ae-9e3f-d57969fcb7e4","keyword":"三氧化二钒","originalKeyword":"三氧化二钒"},{"id":"93d7b8c4-607c-44ae-aa2d-d0e4ed1dc556","keyword":"容量法","originalKeyword":"容量法"}],"language":"zh","publisherId":"yjfx200102025","title":"滴定法测定冶金产品五氧化二钒中V2O3","volume":"21","year":"2001"},{"abstractinfo":"通过三氧化二钒和碳的热重实验,发现三氧化二钒的碳热还原氮化过程可分为两个不同的反应阶段.反应过程存在多个吸热反应,并且不同的反应存在相当程度的重合.根据TG/DTG曲线,通过动力学分析方法得出三氧化二钒的碳热还原氮化反应的不同阶段的反应表观活化能Ea(1170~1340 K:Ea=205.46 kJ·mol-1;1340~1410 K:Ea=465.27 KJ·mkl-1)、频率因子A及动力学速率方程,反应符合反应控制机制(Rn模型).","authors":[{"authorName":"于三三","id":"2ca0d588-1339-4521-8621-05e30f07762c","originalAuthorName":"于三三"},{"authorName":"付念新","id":"e0db8290-fab2-4ec7-ad61-3b42f779ce71","originalAuthorName":"付念新"},{"authorName":"高峰","id":"a7306600-7364-4a74-a1c7-5d2268af6801","originalAuthorName":"高峰"},{"authorName":"隋智通","id":"a1795bc0-a2b3-4840-994d-c7b9a853afa9","originalAuthorName":"隋智通"}],"doi":"10.3969/j.issn.0258-7076.2008.01.018","fpage":"84","id":"fb010a5d-da01-4c49-ae9b-4de4c1e56f32","issue":"1","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"7f014fa8-c632-41a0-8cfb-5e11ee752a97","keyword":"碳氮化钒","originalKeyword":"碳氮化钒"},{"id":"b7659371-8873-4c71-8c85-3c43535a07c2","keyword":"表面活化能","originalKeyword":"表面活化能"},{"id":"4b0c8751-2367-4ca9-80f0-0588e3f5f968","keyword":"三氧化二钒","originalKeyword":"三氧化二钒"},{"id":"8f8bbc8f-5a86-41a9-b02e-1866abf43957","keyword":"氮化","originalKeyword":"氮化"},{"id":"cc89c780-3c2e-4240-bd23-b9deaeb4b201","keyword":"碳热还原","originalKeyword":"碳热还原"}],"language":"zh","publisherId":"xyjs200801018","title":"一步法合成碳氮化钒的动力学研究","volume":"32","year":"2008"},{"abstractinfo":"研究了采用真空碳热还原法由三氧化二钒制备碳化钒, 并研究了碳化钒产物密度随实验条件的变化规律, 找到了用于强化碳化钒产物密度的添加剂, 研究结果表明, 反应温度、添加剂是影响碳化钒产物密度的主要因素, 反应时间对产物密度也有一定影响. 研究结果同时表明, 含铁化合物能有效地提高产物密度. ","authors":[{"authorName":"卢志玉","id":"9b1069bb-8776-485b-ba40-2541c7230a63","originalAuthorName":"卢志玉"},{"authorName":"罗冬梅","id":"e5d0828b-e7ca-4ab6-ae65-bf2e4b773f40","originalAuthorName":"罗冬梅"},{"authorName":"陈厚生","id":"841ef500-a7bf-42ee-b0fc-adfdfae28a64","originalAuthorName":"陈厚生"},{"authorName":"隋智通","id":"f85f53b6-1615-4ae2-bdf8-1f20bd07f0e1","originalAuthorName":"隋智通"}],"doi":"10.3969/j.issn.0258-7076.2003.01.032","fpage":"132","id":"6dca648e-1dc2-4ad5-859e-f4b37cccef94","issue":"1","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"cca56a19-db21-4fdd-bea8-46d8effe7d2b","keyword":"三氧化二钒","originalKeyword":"三氧化二钒"},{"id":"150c5e33-9e95-4a4c-ad34-8be58ec0bafe","keyword":"碳化钒","originalKeyword":"碳化钒"},{"id":"67ffe2a7-5825-4a27-bea6-9996551341ce","keyword":"密度","originalKeyword":"密度"},{"id":"5ef584d9-45f3-46bd-a775-3908a502bae2","keyword":"真空碳热还原法","originalKeyword":"真空碳热还原法"}],"language":"zh","publisherId":"xyjs200301032","title":"真空碳热还原法制备高密度碳化钒","volume":"27","year":"2003"},{"abstractinfo":"研究了一步法合成碳氮化钒的生产工艺及工艺参数对碳氮化钒氮含量的影响.研究结果表明:V2O3与C的配比对产物氮含量影响较大,当碳过量15%时,产物的氮含量最高;产物氮含量随反应温度的提高先增后降,在1 400℃时产物氮含量最高;当反应温度在1 280-1 480℃时,XRD分析显示产物组分均为VN和VC构成的碳氮化钒固溶体;产物中氮含量随反应时间的延长有增加的趋势,反应时间120 min时能得到较高氮含量的产物.同时反应时间对产物的粒度也有明显的影响,SEM图显示产物的粒度随保温时间的延长而增加;添加剂(NH4Cl、Fe)对产物氮含量有较大程度的影响.","authors":[{"authorName":"于三三","id":"66959067-391c-4d88-a04d-09635d183729","originalAuthorName":"于三三"},{"authorName":"付念新","id":"225edbb9-dd47-4c62-9c4b-e0847ef48830","originalAuthorName":"付念新"},{"authorName":"高峰","id":"e59e8dc0-8d64-4ddf-a898-b2554f407a20","originalAuthorName":"高峰"},{"authorName":"隋智通","id":"e2a25004-b4c3-4a6c-84a3-a994f2661081","originalAuthorName":"隋智通"}],"doi":"10.3969/j.issn.1004-7638.2007.04.001","fpage":"1","id":"4821165d-d80b-4985-aabb-4877240cdea2","issue":"4","journal":{"abbrevTitle":"GTFT","coverImgSrc":"journal/img/cover/gtft1.jpg","id":"28","issnPpub":"1004-7638","publisherId":"GTFT","title":"钢铁钒钛"},"keywords":[{"id":"e34f5f7f-ab53-4386-a50f-1d169b03a480","keyword":"碳氮化钒","originalKeyword":"碳氮化钒"},{"id":"502f9585-adb3-4479-a793-d27027cb8cef","keyword":"固溶体","originalKeyword":"固溶体"},{"id":"c6d6fa09-1600-43a1-a94f-1c9d766ed454","keyword":"三氧化二钒","originalKeyword":"三氧化二钒"},{"id":"3cc9f535-80a3-47ab-b20f-144ca9716c06","keyword":"碳热还原","originalKeyword":"碳热还原"},{"id":"331b5806-15ed-48fb-87d2-c0ee833262e6","keyword":"氮化","originalKeyword":"氮化"}],"language":"zh","publisherId":"gtft200704001","title":"一步法合成碳氮化钒的研究","volume":"28","year":"2007"},{"abstractinfo":"工业V2O3产品为粉状,堆密度仅为0.6 ~ 1.2 g/cm3,不利于提高其后续冶炼收率;由于V2 O3的熔点较高,只能选择物理方法提高其密度.采用干法造粒成型工艺,通过降低压辊转速、增加压辊压强等方法可以获得相对密度较高的造粒物,造粒过程中采用多次排气,并施加120 N/cm2的机械成型压力,使其密度提高到1.7~2.1g/cm3;使用高密度氧化钒制备钒铁,钒收率由89%~92%提高到94% ~97%,且钒铁产品的结晶品质有所改善.","authors":[{"authorName":"陈东辉","id":"7f5b3354-a4c0-40a7-bc38-5726e5d7a617","originalAuthorName":"陈东辉"},{"authorName":"李兰杰","id":"c078be06-eb68-41f3-b91d-c3d9815d9125","originalAuthorName":"李兰杰"},{"authorName":"石立新","id":"73e31f07-b040-48f9-a6f9-fe73355adc37","originalAuthorName":"石立新"}],"doi":"10.7513/j.issn.1004-7638.2014.02.004","fpage":"20","id":"4a066fc1-868a-481c-9b16-a05972118cf9","issue":"2","journal":{"abbrevTitle":"GTFT","coverImgSrc":"journal/img/cover/gtft1.jpg","id":"28","issnPpub":"1004-7638","publisherId":"GTFT","title":"钢铁钒钛"},"keywords":[{"id":"cbcebfb0-da93-4a08-83ee-b9abf3daf3c6","keyword":"三氧化二钒","originalKeyword":"三氧化二钒"},{"id":"1f37a6ee-7018-4807-8d2c-767c12263da4","keyword":"堆密度","originalKeyword":"堆密度"},{"id":"037aa188-2545-4e56-b832-9fa9e0acfc8d","keyword":"干法造粒","originalKeyword":"干法造粒"},{"id":"46b0f181-8930-4ad9-b383-79eadb3380fc","keyword":"成型压力","originalKeyword":"成型压力"},{"id":"01892691-c41b-4a4a-b10f-b88aa1d9149a","keyword":"钒收率","originalKeyword":"钒收率"}],"language":"zh","publisherId":"gtft201402004","title":"高密度粉粒状V2O3的制备及应用研究","volume":"35","year":"2014"}],"totalpage":6794,"totalrecord":67936}