{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"聚(甲基)<span style=\"color:red\">丙烯酸酯</span>或<span style=\"color:red\">丙烯酸</span>高级<span style=\"color:red\">酯</span>与其它一些单体的共聚物是一类优良的油品增粘-降凝双效剂。<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>与第二单体A的共聚物对润滑油有较好的降凝效果。<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>与第二单体A的共聚物对润滑油也应有较好的增粘作用(即稠化能力)。用四种溶剂分别采用溶液聚合方法，用正交试验法对<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>与第二单体A进行共聚试验，共聚物以1%的添加量加入到润滑油基础油中，做调合油的粘度测定，以增比粘度、粘温指数Q和粘度指数VI为考察目标，探讨<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>与第二单体A共聚物对润滑油基础油的稠化能力，并找出较好的共聚条件。试验结果表明：<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>与第二单体A共聚物对润滑油确有较好的增粘和改变油品粘温性能的作用，是一种增粘-降凝双效添加剂。","authors":[{"authorName":"李学东","id":"c312805d-98b5-4935-bac2-328db19372b7","originalAuthorName":"李学东"}],"doi":"","fpage":"27","id":"ed0541a8-ce2e-45bf-bad5-88a78e3cf70d","issue":"2","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"40ecdddd-391c-419f-996a-92ad033a4bc0","keyword":"<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>","originalKeyword":"丙烯酸十二酯"},{"id":"5263143b-6216-43d4-aaf8-04aeedc5c886","keyword":"共聚物","originalKeyword":"共聚物"},{"id":"f4a602e0-a3be-4a74-b379-885ddcde22fa","keyword":"润滑油","originalKeyword":"润滑油"},{"id":"36a62b32-a21c-4fe5-aa4e-752a835622fe","keyword":"稠化能力","originalKeyword":"稠化能力"},{"id":"3896a82a-d9ba-4f7f-9c87-7a118589d66c","keyword":"正交试验法","originalKeyword":"正交试验法"}],"language":"zh","publisherId":"hccllhyyy201402008","title":"<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>共聚物稠化能力的试验研究","volume":"","year":"2014"},{"abstractinfo":"以<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span>(BA)为核单体,甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>(LMA)为壳单体,二甲基<span style=\"color:red\">丙烯酸</span>乙二醇<span style=\"color:red\">酯</span>(EGDMA)为交联剂,采用分阶段饥饿态加料方式和半连续乳液聚合方法合成了具有软核软壳结构的聚(<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span>/甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>). 采用复配比为2∶ 1的OP-10和<span style=\"color:red\">十二</span>烷基硫酸钠(SDS)复合乳化剂,采用乳化剂的质量分数为4%左右时的乳液稳定;壳单体的滴加速度在8 mL/h时,体系稳定,且转化率高. 用FTIR分析了聚合物的结构. 透射电子显微镜观察表明,交联剂交联场所不同形成的粒子的形态也不同即核层不加交联剂、核层加交联剂与核、壳层均加交联剂分别形成了球形、核壳结构和梅花形状的粒子;DSC分析表明,聚合物具有2个玻璃化转变温度Tg1=-64 ℃,Tg2=-51 ℃.","authors":[{"authorName":"郑玉艳","id":"11d12f33-477f-4e05-a3af-9a0f27239556","originalAuthorName":"郑玉艳"},{"authorName":"史铁钧","id":"d4019823-8879-410c-b68f-a158abe111b8","originalAuthorName":"史铁钧"},{"authorName":"杭国培","id":"0f6c6c6c-f90b-4414-b2d9-9d844e4cbb31","originalAuthorName":"杭国培"},{"authorName":"刘兵","id":"7a005f0b-005b-4de8-9b89-6bc3c5905cc7","originalAuthorName":"刘兵"}],"doi":"10.3969/j.issn.1000-0518.2008.10.006","fpage":"1146","id":"cbcf92d7-f447-4e88-9f5e-819543573a4d","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"5f20d221-73ef-4175-b18b-f1a0a8773d4a","keyword":"<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span>","originalKeyword":"丙烯酸丁酯"},{"id":"955b60c7-abfd-4e40-8de5-6c3e7b2126e6","keyword":"甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>","originalKeyword":"甲基丙烯酸十二酯"},{"id":"79863730-930f-45ca-9c81-05cb46196633","keyword":"核壳结构","originalKeyword":"核壳结构"},{"id":"f5e1a1cd-b94a-44b4-975f-3876df40fc8d","keyword":"制备","originalKeyword":"制备"}],"language":"zh","publisherId":"yyhx200810006","title":"核壳型聚(<span style=\"color:red\">丙烯酸</span>丁<span style=\"color:red\">酯</span>/甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>)乳液的制备及表征","volume":"25","year":"2008"},{"abstractinfo":"以甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>(LMA)为单体,采用悬浮聚合法合成了聚甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>(PLMA),研究了该树脂对柴油、汽油、甲苯和四氯化碳的吸油性能.结果表明,树脂的吸油率随着时间的延长不断增大,最后达到最大吸油率Qmax,CCl4 的Qmax最大,为14.596 g/g,达到Qmax的时间约为110 min;柴油的的Qmax最小,为4.174 g/g,而吸油速率则随着时间的延长呈现出不断降低的趋势.树脂对CCl4、甲苯和汽油的保油率不到90％,对柴油的保油率达到90％以上.树脂的缓释保油率与油品的种类关系较大,树脂对甲苯和四氯化碳的缓释能力较大.","authors":[{"authorName":"魏徵","id":"7009aa08-1bac-490c-b009-1cc833579d55","originalAuthorName":"魏徵"},{"authorName":"刘鹏宇","id":"af30145b-b091-4485-907d-16255ec948e4","originalAuthorName":"刘鹏宇"},{"authorName":"王源升","id":"24b7ba05-d5e3-40c9-bafc-1e5ed857972c","originalAuthorName":"王源升"},{"authorName":"李瑜","id":"a0390f04-84e3-4eeb-9193-e1135e6a9895","originalAuthorName":"李瑜"},{"authorName":"余红伟","id":"3e3ee076-fed2-4f54-a53a-13dda071af4b","originalAuthorName":"余红伟"}],"doi":"","fpage":"5","id":"2eaeb8a3-994b-402c-b8d2-df1813cf11c1","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"407944f1-390a-4855-b351-82cca0defe71","keyword":"聚甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>","originalKeyword":"聚甲基丙烯酸十二酯"},{"id":"26a1fd7d-4434-4297-a63e-b88fd1a69519","keyword":"吸油率","originalKeyword":"吸油率"},{"id":"920f9306-c298-4a3b-93e6-566485f81d8f","keyword":"保油率","originalKeyword":"保油率"}],"language":"zh","publisherId":"gfzclkxygc201302002","title":"聚甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>的合成及吸油性能","volume":"29","year":"2013"},{"abstractinfo":"采用聚已二<span style=\"color:red\">酸</span>丁二醇<span style=\"color:red\">酯</span>(PBA)、异氟尔酮二异氰酸<span style=\"color:red\">酯</span>(IPDI)、二羟甲基丙酸(DMPA)、甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span>氟庚<span style=\"color:red\">酯</span>(MBFA-12)等原料合成了含氟水性聚氨酯乳液(WPU-F),考察了MBFA-12的用量对WPU-F乳液的粒径与黏度,WPU-F胶膜的吸水率、接触角、附着力、硬度、拉伸强度、热力学性能等的影响.结果表明:用MBFA-12改性水性聚氨酯,在提高水性聚氨酯胶膜的拉伸强度、附着力、热力学性能的同时,由于侧链上密集的-CF3作用,接触角从70.7(°)增加到107.6(°),胶膜吸水率从61.3%降到15%以下,大大提高了聚氨酯的耐水性.","authors":[{"authorName":"郑飞龙","id":"853a05a1-e6a1-43db-a90d-9f653eaea4b3","originalAuthorName":"郑飞龙"},{"authorName":"项尚林","id":"3c77f95d-3319-4f0a-91bf-ea12f17fc6c1","originalAuthorName":"项尚林"},{"authorName":"陆春华","id":"734e0337-f8d9-4846-8e20-b921c5b15857","originalAuthorName":"陆春华"},{"authorName":"赵石林","id":"8ab3dff9-7a21-4934-a499-c96a229c1787","originalAuthorName":"赵石林"},{"authorName":"许仲梓","id":"666f0ceb-4758-4b18-8193-0ef354d31e01","originalAuthorName":"许仲梓"}],"doi":"10.3969/j.issn.0253-4312.2009.07.012","fpage":"45","id":"6ef880e4-2bea-475e-913b-c241e9c4406b","issue":"7","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"2027783e-57f1-47a6-ba2e-95b6c3c3f9fc","keyword":"水性聚氨酯","originalKeyword":"水性聚氨酯"},{"id":"1d64d71e-0499-4a85-b0c1-fd8ee1598458","keyword":"甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span>氟庚<span style=\"color:red\">酯</span>","originalKeyword":"甲基丙烯酸十二氟庚酯"},{"id":"40d22c80-7c2e-472c-8e60-07a7599dbff2","keyword":"改性","originalKeyword":"改性"},{"id":"37adf478-72df-4636-8053-69b57c8a404b","keyword":"耐水性能","originalKeyword":"耐水性能"}],"language":"zh","publisherId":"tlgy200907012","title":"甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span>氟庚<span style=\"color:red\">酯</span>改性水性聚氨酯","volume":"39","year":"2009"},{"abstractinfo":"以相变物质正<span style=\"color:red\">十二</span>醇(DA)为芯材,聚甲基<span style=\"color:red\">丙烯酸甲酯</span>(PMMA)为壁材,采用悬浮聚合法制备了正<span style=\"color:red\">十二</span>醇-聚甲基<span style=\"color:red\">丙烯酸甲酯</span>(DA@PMMA)微胶囊。通过差示扫描量热仪(DSC),扫描电镜(SEM),透射电镜(TEM),傅里叶变换红外光谱仪(FIIR)和热重分析仪(TGA)等仪器对微胶囊进行检测表征。结果表明：当工艺为苯乙烯-马来<span style=\"color:red\">酸</span>甘钠盐(SMA)加入量占 DA质量的7.5%,偶氮二异丁腈(AIBN)加入量占单体甲基<span style=\"color:red\">丙烯酸</span>甲<span style=\"color:red\">酯</span>(MMA)质量的7.5%,芯材壁材质量比为2∶1,搅拌速度为1000 r/min 时,所制备的微胶囊整体性能最好。DA@PMMA微胶囊为球形,平均粒径26μm,DA@PMMA微胶囊中 DA的质量分数为66%。DA@PMMA微胶囊的熔化焓和结晶焓分别是137.6 J/g和132.8 J/g。TGA和 FIIR的分析表明,DA@PMMA微胶囊具有良好的性能。","authors":[{"authorName":"宋晓秋","id":"e2189d7c-a5d1-4f96-a763-72af0538cadc","originalAuthorName":"宋晓秋"},{"authorName":"曹龙迪","id":"23cd6dce-bc60-4314-9fe5-b687882d76a0","originalAuthorName":"曹龙迪"},{"authorName":"叶琳","id":"94a51b4c-1437-44c0-b2bc-59dc93f12e54","originalAuthorName":"叶琳"}],"doi":"10.13801/j.cnki.fhclxb.20160315.002","fpage":"191","id":"939575c0-d979-40af-8a91-ae5224834b1c","issue":"1","journal":{"abbrevTitle":"FHCLXB","coverImgSrc":"journal/img/cover/FHCLXB.jpg","id":"26","issnPpub":"1000-3851","publisherId":"FHCLXB","title":"复合材料学报"},"keywords":[{"id":"fdc4dc8f-c3c4-449d-ba6b-f6fa5de4942b","keyword":"正<span style=\"color:red\">十二</span>醇","originalKeyword":"正十二醇"},{"id":"08073ab9-65eb-4b4c-b6cf-523779ffa679","keyword":"相变材料","originalKeyword":"相变材料"},{"id":"83fd60ba-e033-438a-b98a-93d4574ced63","keyword":"聚甲基<span style=\"color:red\">丙烯酸甲酯</span>","originalKeyword":"聚甲基丙烯酸甲酯"},{"id":"d5d4a167-3129-426f-94a4-a32a405013dd","keyword":"微胶囊","originalKeyword":"微胶囊"},{"id":"c165c558-0ff3-457b-8514-b7656ece451f","keyword":"悬浮聚合法","originalKeyword":"悬浮聚合法"}],"language":"zh","publisherId":"fhclxb201701025","title":"聚甲基<span style=\"color:red\">丙烯酸甲酯</span>包覆<span style=\"color:red\">十二</span>醇微胶囊的制备及表征","volume":"34","year":"2017"},{"abstractinfo":"将两亲高分子聚(甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>-<span style=\"color:red\">丙烯酸</span>)作为膜稳定剂加到由Span-80作表面活性剂、二-(2-乙基己基)磷酸作流动载体、煤油和液体石蜡作膜溶剂以及硫酸稀溶液作内相而组成的W/O型乳液膜中,研究了此体系对Zn2+的迁移作用. 结果表明,由于两亲高分子的空间稳定作用而导致乳液膜对Zn2+具有较高的迁移效率. 最优条件是在膜相中膜稳定剂的质量分数为3.0%、表面活性剂为4.0%、流动载体为3.0%、膜添加剂为6.0%,内相中H+浓度为1.0 mol/L,乳液相与料相体积比为1∶ 10,接触时间为6 min,混合液搅拌速率为200～300 r/min.","authors":[{"authorName":"田大听","id":"0ab1aac8-c132-45f6-bb6a-1fd829273296","originalAuthorName":"田大听"}],"doi":"10.3969/j.issn.1000-0518.2003.12.013","fpage":"1180","id":"e152b382-4399-43b5-b830-b179758751f7","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"d3da9313-1f26-47fc-bc1e-a6d6febcaa45","keyword":"两亲高分子,乳状液膜,迁移,稳定剂,锌(Ⅱ)离子","originalKeyword":"两亲高分子,乳状液膜,迁移,稳定剂,锌(Ⅱ)离子"}],"language":"zh","publisherId":"yyhx200312013","title":"用甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span><span style=\"color:red\">酯</span>/<span style=\"color:red\">丙烯酸</span>共聚物作乳状液膜稳定剂迁移锌(Ⅱ)","volume":"20","year":"2003"},{"abstractinfo":"采用连续再生催化剂原子转移自由基聚合(ICAR ATRP)合成了甲基<span style=\"color:red\">丙烯酸</span>环氧丙<span style=\"color:red\">酯</span>-b-甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span>氟庚<span style=\"color:red\">酯</span>嵌段共聚物(PGMA-b-PDFHMA).然后将嵌段共聚物与纳米二氧化钛(TiO2)复合制备疏水涂层.通过凝胶渗透色谱、核磁共振仪、接触角、扫描电子显微镜等对嵌段共聚物及涂层进行了研究与表征.研究结果表明,采用ICAR ATRP法成功制备了甲基<span style=\"color:red\">丙烯酸</span>环氧丙<span style=\"color:red\">酯</span>-b-甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span>氟庚<span style=\"color:red\">酯</span>嵌段共聚物.嵌段共聚物结构及嵌段共聚物与纳米粒子的比例对涂层疏水性有显著影响.当含氟嵌段共聚物的链段摩尔比为1∶0.10,含氟嵌段共聚物与TiO2质量比为0.5/1～10/1时,含氟嵌段共聚物接枝纳米TiO混合物制备的涂层表面的接触角可达150°.嵌段共聚物的含氟链段长度和涂层表面粗糙结构的差异是影响涂层疏水性的主要原因.","authors":[{"authorName":"朱冠南","id":"ee01ca33-358d-4003-bd8b-96e3835df9a7","originalAuthorName":"朱冠南"},{"authorName":"孙建平","id":"bb2c75eb-45de-4e8b-806d-80f2925f658a","originalAuthorName":"孙建平"},{"authorName":"任强","id":"ac8bd42c-1911-463f-8c1e-2e097180ae02","originalAuthorName":"任强"},{"authorName":"汪称意","id":"a0079ac4-d41f-4fbb-9640-922c9e716f36","originalAuthorName":"汪称意"},{"authorName":"李坚","id":"a932997a-7b24-43fa-98ed-8e44079c64ae","originalAuthorName":"李坚"},{"authorName":"盛刚","id":"b82eba73-4d32-46be-94a5-81e9462b2e9f","originalAuthorName":"盛刚"}],"doi":"10.16865/j.cnki.1000-7555.2016.04.003","fpage":"11","id":"a641241c-ee5c-42d5-b986-720a2e40b0b8","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"a1bf714b-1b35-4fa1-9a16-245af5b2214a","keyword":"嵌段共聚物","originalKeyword":"嵌段共聚物"},{"id":"9e119977-fe46-41ca-85af-c175200a4a4c","keyword":"纳米二氧化钛","originalKeyword":"纳米二氧化钛"},{"id":"54dc0278-9b51-42e2-a96c-e698ed93143a","keyword":"疏水","originalKeyword":"疏水"},{"id":"9f99895c-7435-46b3-b3a3-9471578d7df6","keyword":"接触角","originalKeyword":"接触角"}],"language":"zh","publisherId":"gfzclkxygc201604003","title":"甲基<span style=\"color:red\">丙烯酸</span>环氧丙<span style=\"color:red\">酯</span>-b-甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span>氟庚<span style=\"color:red\">酯</span>嵌段共聚物的合成及在疏水涂层中的应用","volume":"32","year":"2016"},{"abstractinfo":"在采用分子动力学模拟方法讨论了相关的分子设计基础上,通过乳液聚合方法合成了甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span>烷基<span style=\"color:red\">酯</span>高聚物,经后处理形成具有离子-偶极作用的离聚体系减阻剂.给出了构成离聚体系减阻剂单体的选择和合成方法,并对反应体积倍增与产物收率的工艺进行了实验分析；采用DAWN HELEOS 18角度激光光散射仪测试了离聚体系的流体力学半径；并通过减阻剂减阻效果环道测试评价系统装置和评价系统中的管泵传输子系统,进行减阻性能和抗剪切性能的研究.结果表明,离聚体系减阻剂有明显的减阻性能,随着合成分子量的增大减阻率逐渐增大,分子量的提高有利于减阻性能的提高；反应体积的倍增对乳液聚合反应收率基本没有影响；随着剪切次数增加,离聚体系减阻率呈现下降趋势,但仍具有良好的抗剪切性能.","authors":[{"authorName":"李长雨","id":"159bc534-538a-4ed0-8f2d-6b7e4166cf5b","originalAuthorName":"李长雨"},{"authorName":"募春玲","id":"b1e5d673-780f-4405-b9c0-1c219de3512f","originalAuthorName":"募春玲"},{"authorName":"陈世伟","id":"53b07d31-a9e0-4a71-b458-2fa112dd2488","originalAuthorName":"陈世伟"},{"authorName":"方舒","id":"e64a372a-8d2b-4c52-b24c-5b812c94cdde","originalAuthorName":"方舒"},{"authorName":"陈祥俊","id":"aae51e7e-93a9-4d69-91e9-6bb5277f0eda","originalAuthorName":"陈祥俊"},{"authorName":"张长桥","id":"31da8dee-278b-490a-9730-5e358f3acce1","originalAuthorName":"张长桥"}],"doi":"10.3969/j.issn.1001-4381.2011.11.016","fpage":"74","id":"edffa89f-999d-4716-b74c-630fbe4a637b","issue":"11","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"7115cb26-3cc0-47c2-9435-98bc857983af","keyword":"离子-偶极作用","originalKeyword":"离子-偶极作用"},{"id":"4a084580-c828-40c0-bf31-5c264de4d31d","keyword":"离聚体系","originalKeyword":"离聚体系"},{"id":"c2dd23d7-9c9b-4895-8695-d0ff97669104","keyword":"减阻率","originalKeyword":"减阻率"},{"id":"1011470b-9de7-499c-8d98-c8e858502ff1","keyword":"抗剪切","originalKeyword":"抗剪切"}],"language":"zh","publisherId":"clgc201111016","title":"甲基<span style=\"color:red\">丙烯酸</span><span style=\"color:red\">十二</span>烷基<span style=\"color:red\">酯</span>离聚体系减阻性能与抗剪切稳定性研究","volume":"","year":"2011"},{"abstractinfo":"以<span style=\"color:red\">十二</span>烷基甲基<span style=\"color:red\">丙烯酸酯</span>(LMA)为功能单体,乙叉二甲基<span style=\"color:red\">丙烯酸酯</span>(EDMA)为交联剂,正丙醇、1,4-丁二醇和水为三元致孔剂,以及2-<span style=\"color:red\">丙烯</span>酰胺-2-甲基丙磺酸(AMPS)为电渗流产生剂,制备了聚<span style=\"color:red\">十二</span>烷基甲基<span style=\"color:red\">丙烯酸酯</span>整体柱.系统考察了AMPS含量和单体-致孔剂比例对柱性能的影响.结果表明,单体溶液和致孔剂的最佳聚合溶液质量比为35:65,其中单体溶液组成为59.5%(质量分数,下同)LMA、40%EDMA和0.5%AMPS,致孔剂溶液组成为60%正丙醇、30%1,4-丁二醇和10%水.在优化的流动相条件下应用制备的整体柱采用毛细管电色谱法成功地分离了肌红蛋白酶解产物.","authors":[{"authorName":"王婷婷","id":"f5a77dcb-115b-4ec8-88ad-743061913d2f","originalAuthorName":"王婷婷"},{"authorName":"梁振","id":"1a57701a-5dc7-416c-95d5-a9199fcfc868","originalAuthorName":"梁振"},{"authorName":"张丽华","id":"49e1c3f5-0e7a-4875-ae0a-da86d9651e0f","originalAuthorName":"张丽华"},{"authorName":"张玉奎","id":"a22371a3-56e9-4d80-ac17-3ac3087d9b96","originalAuthorName":"张玉奎"}],"doi":"10.3724/SP.J.1123.2010.00236","fpage":"236","id":"55812421-953d-4007-be16-0b6cc72c2e12","issue":"3","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"77ece531-d81b-4707-94f9-f45e2673fa10","keyword":"毛细管电色谱法","originalKeyword":"毛细管电色谱法"},{"id":"89918875-ca72-465b-871f-85fb6890b34e","keyword":"肌红蛋白酶解产物","originalKeyword":"肌红蛋白酶解产物"},{"id":"35040aff-e679-4656-ad26-380f244268ba","keyword":"<span style=\"color:red\">十二</span>烷基甲基<span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"十二烷基甲基丙烯酸酯"},{"id":"648f234d-ab55-4fad-a9f9-c5436433b8b6","keyword":"整体柱","originalKeyword":"整体柱"}],"language":"zh","publisherId":"sp201003004","title":"聚<span style=\"color:red\">十二</span>烷基甲基<span style=\"color:red\">丙烯酸酯</span>整体柱的制备及其在毛细管电色谱法分离肌红蛋白酶解产物中的应用","volume":"28","year":"2010"},{"abstractinfo":"制备了一种紫外光固化预聚物--带有羧基的低分子量聚<span style=\"color:red\">丙烯酸酯</span><span style=\"color:red\">丙烯酸</span>树脂(Polyacrylate acrylic resin, PAAR).其主链由<span style=\"color:red\">丙烯酸</span>烷基<span style=\"color:red\">酯</span>和<span style=\"color:red\">丙烯酸</span>进行共聚而得,当采用<span style=\"color:red\">丙烯酸</span>甲<span style=\"color:red\">酯</span>、<span style=\"color:red\">丙烯酸</span>乙<span style=\"color:red\">酯</span>和<span style=\"color:red\">丙烯酸</span>(摩尔比1∶1∶1)作为共聚单体,引发剂AIBN为1 5%,链转移剂<span style=\"color:red\">十二</span>硫醇为2 5%时,聚合得到的聚<span style=\"color:red\">丙烯酸酯</span>(Polyacrylate, PA)分子量在1100-1400之间,多分散性小于2,反应速率快,转化率高;由这种PA和甲基<span style=\"color:red\">丙烯酸</span>缩水甘油<span style=\"color:red\">酯</span>(GMA)进行酯化反应,制备得到最终产物聚<span style=\"color:red\">丙烯酸酯</span><span style=\"color:red\">丙烯酸</span>树脂,酯化率可以达到80%以上,其光固化膜具有较好的涂膜硬度和柔韧性,光泽度饱满.","authors":[{"authorName":"欧霄巍","id":"6f455cdc-9a12-4bd8-8334-c4c77a620e9a","originalAuthorName":"欧霄巍"},{"authorName":"聂俊","id":"b37dc74c-78cd-4b90-b58d-70259575c679","originalAuthorName":"聂俊"},{"authorName":"何勇","id":"1544121d-ce19-41b7-acd4-a7e392d8b83b","originalAuthorName":"何勇"}],"doi":"","fpage":"182","id":"09d5c548-dee7-443a-84da-220543bd3099","issue":"3","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学   "},"keywords":[{"id":"e68b820d-43e7-47d0-af67-3f23a023fa1e","keyword":"紫外光固化","originalKeyword":"紫外光固化"},{"id":"9e865e79-dc20-4c7f-ae6b-8e92b8058ded","keyword":"齐聚物","originalKeyword":"齐聚物"},{"id":"8ebe4484-df85-4bf8-9d3a-aab2b88c0ff9","keyword":"聚<span style=\"color:red\">丙烯酸酯</span>","originalKeyword":"聚丙烯酸酯"}],"language":"zh","publisherId":"ggkxyghx201003003","title":"一种低分子量带有羧基的聚<span style=\"color:red\">丙烯酸酯</span><span style=\"color:red\">丙烯酸</span>树脂的制备和性质","volume":"28","year":"2010"}],"totalpage":2116,"totalrecord":21158}