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Effect of Calcium Treatment on Non-Metallic Inclusions in Ultra-Low Oxygen Steel Refined by High Basicity High Al2O3 Slag

YANG Jun , WANG Xin-hua , JIANG Min , WANG Wan-jun

钢铁研究学报(英文版)

The influence of calcium treatment on non-metallic inclusions had been studied when control technology of refining top slag in ladle furnace was used in ultra-low oxygen steelmaking. A sufficient amount aluminium was added to experimental heats for final deoxidizing during BOF tapping, and the refining top slag with strong reducibility, high basicity and high Al2O3 in ladle furnace was used to produce ultra-low oxygen steel and the transformation of non-metallic inclusions in molten steel was compared by calcium treatment and no calcium treatment. The results show that the transformation of Al2O3→MgO·Al2O3 spinel→CaO-MgO-Al2O3 complex inclusions has been completed for aluminum deoxidation products and calcium treatment to molten steel is unnecessary when using the control technology of ladle furnace refining top slag to produce ultra-low oxygen steel, and the complex inclusions are liquid at the temperature of steelmaking and easily removable to obtain very high cleanliness steel by flotation. Furthermore, the problems of nozzle clogging in casting operations do not happen and the remaining oxide inclusions in steel are the relatively lower melting point complex inclusions.

关键词: ultra-low oxygen , top slag , deoxidization , aluminium , oxide inclusion , calcium treatment

低碳铝脱氧钢连铸开浇阶段钢中非金属夹杂物的变化

曹晶,杨文,王新华,王万军,薛勇强

钢铁

较系统地研究了开浇阶段钢中非金属夹杂物的变化。对板坯连铸生产SPHC钢开浇阶段钢水连续取样,并对试样全氧和氮以及非金属夹杂物进行分析。结果表明:开浇初期中间包钢水二次氧化较严重;开浇大约21min后中间包内达到较为稳定状态;钙处理可使夹杂物变性,防止水口粘结、堆积。

关键词: 开浇 , reoxidation , nonmetallic inclusion , calcium treatment

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