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Morphological Changes During Annealing of Electrodeposited Ni-Cr Coating on Steel and Their Effect on Corrosion in 3% of NaCl Solution

Manpreet Singh Marwah , Vajjala Srinivas , Ajoy Kumar Pandey , Shyam Ranjan Kumar4 , Koushik Biswas , Joydeep Maity5

钢铁研究学报(英文版)

Steel containing carbon of 02% was coated with Ni and Cr through electrodeposition, and subsequently annealed at 400 and 600 ℃ for 5 min, 30 min, 1 h and 2 h. During annealing at 400 ℃, the formation and growth of oxides occurred in the form of petals along with voids, cracks and porosities. However, at 600 ℃, the nucleation and growth of chromium oxide whiskers produced a surface almost free from crack, porosity and void for 1 h and 2 h of holding. In accordance with the surface morphology, the bare steel, as-deposited steel, all specimens deposited and annealed at 400 ℃, and specimens deposited and annealed at 600 ℃ for 5 and 30 min exhibited continuous corrosion in 3% of NaCl solution. However, the specimens deposited and annealed at 600 ℃ for 1 and 2 h exhibited an improved corrosion resistance in 3% of NaCl solution with high pitting potential due to presence of a dense passive oxide film almost free from voids at the surface.

关键词: steel , electrodeposition , annealing , corrosion resistance

稀土对电沉积镍基合金镀层组织和耐蚀性的影响

张乐

物理测试

针对提高镍基合金镀层性能问题,采用单脉冲电沉积法制备镍基合金镀层,并用扫描电镜、电化学和失重法研究了镀液中添加稀土元素对镍基合金镀层的组织和耐蚀性的影响。结果表明:镀液中添加适量的稀土能细化镍基合金镀层组织,使镀层表面平整致密,有效地提高镀层的耐蚀性能。

关键词: 镍基合金镀层 , electrodeposition , corrosion resistance , rare earth

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