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Microstructure and Mechanical Properties of Hot Rolled Low Silicon TRIP Steel Containing Phosphorus and Vanadium

HOU Xiao-ying , XU Yun-bo , ZHAO Yan-feng , WU Di

钢铁研究学报(英文版)

The microstructure characteristics and mechanical properties of a low-silicon TRIP steel containing phosphorus and vanadium at different finish rolling temperatures were studied by laboratory hot rolling experiments. Different ratios of multiphase microstructure (ferrite, granular bainite and retained austenite) are obtained. With a decrease in finish rolling temperature, the volume fractions of ferrite and retained austenite increase. EBSD analysis reveals that most of the ferrite grains are fine, and decreasing of finish rolling temperature leads to an increase in low angle boundaries. Under the joint effects of fine grain strengthening, dislocation strengthening and precipitation strengthening, higher strength is obtained. When the finish rolling temperature is decreased to 800 ℃, the steel has excellent mechanical properties: Rp02=470 MPa; Rm=960 MPa; Rp02/Rm=049; A50=197%; n=025.

关键词: hot rolling , low silicon , TRIP steel , phosphorus , vanadium , EBSD , precipitation

Phosphorous Enrichment in Molten Adjusted Converter Slag: Part II Enrichment Behavior of Phosphorus in CaO-SiO2-FeOx-P2O5 Molten Slag

WANG Nan , LIANG Zhi-gang , CHEN Min , ZOU Zong-shu

钢铁研究学报(英文版)

The enrichment behavior of phosphorus in CaO-SiO2-FeOx-P2O5 slag was studied by making an investigation on the distribution of phosphorous content in the CaO-SiO2-FeOx-P2O5 molten slag. The research results showed that the 2CaO·SiO2 solid particles existing in molten slag were the condensation sites for the phosphorus enrichment. The enrichment process of phosphorus in the molten slag can be recognized as three substeps: mass transfer of phosphorus from bulk slag to the surface of 2CaO·SiO2 particle, superficial solid solution reaction of phosphorus around the 2CaO·SiO2 particle, and diffusion of phosphorus through the product layer of 2CaO·SiO2-3CaO·P2O5 solid solution to the inner of 2CaO·SiO2 particle. Moreover, higher temperature is favorable to the phosphorous enrichment from molten bulk slag to the 2CaO·SiO2 particles.

关键词: enrichment behavior , phosphorus , 2CaO·SiO2 particle , mass transfer

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