朱云洲
,
黄政仁
,
董绍明
,
袁明
,
江东亮
无机材料学报
doi:10.3724/SP.J.1077.2007.00959
采用微米级Al粉作为活性填料, SiC微粉作为惰性填料, 聚碳硅烷作为陶瓷前驱体制备SiC基复相陶瓷. 研究了热解温度和保温时间对陶瓷产率、线收缩率、力学性能以及微观结构的影响. 研究表明, 由于活性Al粉颗粒在热解过程中与含碳的有机小分子以及反应性气氛发生...
关键词:
陶瓷前驱体
,
active filler
,
linear shrinkage
,
ceramic yield
H.F.Hu
,
Z.H.Chen and C.J.Zhou Department of Material Engineering & Applied Chemistry
,
National University of Defense Technology
,
Changsha 410073
,
China
金属学报(英文版)
The pyrolytic process of polycarbosilane (PCS) with active fillers (Ti, TiH 2, TiB 2, Cr, CrSi 2) is investigated. The ceramic yields with active fillers reach over 100% in N 2 atmosphere, and no shrinkage occurs when 12vol% Ti, or 4vol% Cr, or 3vol% CrSi 2 is added into PCS. XRD patterns indic...
关键词:
polycarbosilane
,
null
,
null
,
null
,
null
