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中间相沥青纤维制备高导热炭材料的研究

马兆昆 , 史景利 , 刘朗 , 郭全贵 , 翟更太

无机材料学报 doi:10.3724/SP.J.1077.2006.01167

利用中间相沥青纤维中沥青分子的高度择优取向和适度的热塑性热压制备高导热块体炭材料. 对比研究了经不同氧化处理的带形及圆形中间相沥青纤维热压所得炭材料的传导性及力学性能.
结果表明: 相对圆形纤维来说, 由于带形中间相纤维具有更高的纤维轴向取向度和纤维之间更高的接触面积, 故其热压所得材料具有更高的密度和传导性. 经260℃氧化的带形纤维热压所得炭材料的密度、抗弯强度、电阻率及热导率分别达到了2.18g·cm-3、118.4MPa、1.13μΩm和717W/m·K.

关键词: 中间相沥青纤维 , stabilization , hot-pressing , high thermal conductivity

INFLUENCE OF PRECIPITATES ON THE TWO WAY SHAPE MEMORY EFFECT

M Liu , XM Zhang , M.Z. Liu , X.M. Mengand Y Y Li(Institute of Metal Research , Chinese Academy of Sciences , Shenyang 110015 , China)(Metal Material Department , Sichuan Union University , Chengdu 610065 , China)

金属学报(英文版)

In this paper by means of TEM and HREM, we found that the presence of r-phase plays the most important role in enabling two way shape memory effect (TWME) to be obtained by the stabilization of stress induced martensite variants (SSIM). This idea is different from the traditional suggestion that strain fields developed by dislocation produced TWME. With prolonged isothermal ageing time, the bainitic tronsforma-tion product α1 precipitated, the amount of γ-phase increased, while the martensite was retained and became less ondered. These factors all reduced TWME. During age-ing, the stacking faults in bainitic product α1 disappeared, which indicated that the bainitic product α1 is a sub-equilibrium phase. The interfaces of α-plates also lost straightness step by step, some plates twisted, bronched and overlapped. Its formation is irreversible in tnorphology and reduces the quantities of martensite. Although the precipitation of r may stabilize some martensite or oppose its growth,α may hinder nucleation of martensite. Thus, it was considered that α-plates were the worst de- stroyed element. These suggestions agreed well with our performance test results in that the transformation temperntures and the amount of TWME changed in the same way with prolonged ageing, firstly increasing and then decreasing after reaching an optimal maximum value.

关键词: precipitate , null , null , null

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