Zhang Lan
,
Gao Qin
,
Han Yong
材料科学技术（英文）
doi:10.1016/j.jmst.2016.01.008
Micro-porous TiO2 coatings co-doped with Zn2+ and Ag nanoparticles were fabricated on Ti by micro-arc oxidation (MAO) for 0.5, 1.5, 2 and 4?min, respectively. The evolutions of morphology and phase component of the coating as a function of processing time were investigated. The microstructure of the 2?min treated coating was further observed by transmission electron microscopy to explore the coating formation mechanism. The amounts of Ag and Zn released from the 2?min treated coating were measured and the antibacterial properties of the coatings against Staphylococcus aureus (S.?aureus) were also investigated. The obtained results showed that with prolonged MAO time, the contents of Ag and Zn on the coating surfaces increased. All the coatings were micro-porous with pore diameters of 1-4?μm; however, some pores were blocked by deposits on the 4?min treated coating. The 2?min treated coating was composed of amorphous TiO2, anatase, rutile, ZnO, Zn2TiO4 and homogenously distributed Ag nanoparticles. After immersion, Zn2+, Ag+, Ti2+ and Ca2+ were released from the coating and with the immersion time prolonged, the accumulated concentrations of these ions increased. After immersion for 36 weeks, the accumulated Zn2+ and Ag+ concentrations were 6.88 and 0.684?ppm, respectively, which are higher than the minimal inhibitory concentration but much lower than the cytotoxic concentration. Compared with polished Ti control, the coatings co-doped with Zn2+ and Ag nanoparticles significantly inhibited the adhesions of S.?aureus and reduced the amounts of planktonic bacteria in culture medium, indicating that the Zn and Ag co-doped TiO2 could be a bio-adaptable coating for long-lasting anti-microbial performance.
关键词:
Zn
,
Ag nanoparticle
,
Co-doped TiO2
,
Micro-arc oxidation
,
Bio-adaptable
孙晓君
,
霍伟光
,
魏金枝
,
刘婧婧
,
牛海涛
功能材料
doi:10.3969/j.issn.1001-9731.2013.22.025
采用溶胶-凝胶法制备了Co掺杂TiO2光催化剂,并用浸渍法对其表面进行 SO2-4修饰,借助于 X射线衍射(XRD)、红外吸收光谱(FT-IR)及紫外-可见吸收光谱(UV-Vis)等分析手段对所制备的催化剂进行表征,并对其光催化分解水制氢性能进行了研究。结果表明,Co掺杂TiO2显示出明显的可见光响应,对其表面进行 SO2-4修饰能进一步提升其光催化活性。当Co掺杂量为2.0%(原子分数),SO2-4的修饰量为8.0%(质量分数),焙烧温度为500℃时,所制催化剂催化活性最高,其产氢速率为171.3μmol/h。
关键词:
光催化剂
,
Co掺杂TiO2
,
SO2-4 修饰
,
制氢
