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AB5-type Hydrogen Storage Alloy Modified with Ti/Zr Used as Anodic Materials in Borohydride Fuel Cell

Lianbang WANG

材料科学技术(英文)

Fuel cell using borohydride as the fuel has received much attention. AB5-type hydrogen storage alloy used as the anodic material instead of noble metals has been investigated. In order to restrain the generation of hydrogen and enhance the utilization of borohydride, Ti/Zr metal powders has been add...

关键词: Fuel cell , null , null , null , null

Preparation and Characterization of Platinum Supported on Carbon Nanotubes with Different Tube Diameter for Cathode Catalysts of Proton Exchange Membrane Fuel Cells

Hong Su Bing Zhang Lijuan Chen

材料科学技术(英文)

Platinum supported on carbon nanotubes (CNTs) with different tube diameters <10, 10-20, 40-60 and 60-100 nm were prepared. The catalysts were characterized by  transmission electron microscopy (TEM), X-ray diffraction (XRD). The metal particle size for 40 wt pct Pt catalysts were 2-5 nm. Sel...

关键词: Fuel cell , 碳载铂催化剂 , 碳纳米管 , 催化活性

Electrochemical Characteristics of LaNi4.5Al0.5 Alloy Used as Anodic Catalyst in a Direct Borohydride Fuel Cell

Lianbang Wang Guobin Wu Zhenzhen Yang Yunfang Gao Xinbiao Mao Chun'an May

材料科学技术(英文)

Fuel cells using borohydride as the fuel have received much attention because of high energy density and theoretical working potential. In this work, LaNi4.5Al0.5 hydrogen storage alloy used as the anodic material has been investigated. It was found that the increasi...

关键词: Fuel cell , 硼氢化物 , 阳极催化剂 , 储氢合金

Electrochemical Characteristics of LaNi4.5Al0.5 Alloy Used as Anodic Catalyst in a Direct Borohydride Fuel Cell

Lianbang Wang Guobin Wu Zhenzhen Yang Yunfang Gao Xinbiao Mao Chun'an May

材料科学技术(英文)

Fuel cells using borohydride as the fuel have received much attention because of high energy density and theoretical working potential. In this work, LaNi4.5Al0.5 hydrogen storage alloy used as the anodic material has been investigated. It was found that the increasi...

关键词: Fuel cell , 硼氢化物 , 阳极催化剂 , 储氢合金

气体扩散层中聚四氟乙烯的分布对质子交换膜燃料电池水淹的影响

宋微 , 俞红梅 , 邵志刚 , 衣宝廉 , 林瑾 , 刘娜

催化学报 doi:10.1016/S1872-2067(14)60014-0

通过在不同真空度下进行碳纸的聚四氟乙烯(PTFE)浸渍处理,考察了PTFE在碳纸中的分布对燃料电池水淹情况的影响。碳纸PTFE浸渍过程中,抽真空作用可以将碳纸微孔中存留的空气移除,使PTFE更均匀地扩散到内部微孔中。碳纸的断面电镜照片显示真空浸渍可以改善PTFE的分布。在总浸渍量相同时,由于真空浸渍...

关键词: 燃料电池 , 气体扩散层 , 憎水性 , 水淹

石墨烯负载Pt-Co纳米粒子及其在氧化还原反应中的应用

马延文 , 刘忠儒 , 王博琳 , 朱磊 , 杨建平 , 李兴鳌

新型炭材料 doi:10.1016/S1872-5805(12)60016-X

采用微波-乙二醇方法还原氧化石墨烯和Pt(v)、Co(Ⅱ)粒子混合物,再经300℃H2还原,制备了石墨烯负载Pt-Co合金催化剂(Pt-Co/G).利用透射电镜、X-射线能谱、X-射线衍射和光电子能谱对所制催化剂进行表征.Pt-Co合金的粒径为3nm~8 nm,均匀地分散在石墨烯片上.与单金属的Pt...

关键词: 石墨烯 , Pt-Co合金纳米粒子 , 氧化还原反应 , 燃料电池 , 电催化剂

甲醇浓度对Pt/C催化剂氧还原活性的影响

唐水花 , 林文锋 ,

催化学报 doi:10.1016/S1872-2067(11)60480-4

采用半池考察了Pt/C催化剂在含不同浓度甲醇的0.5 mol/L硫酸中的氧还原活性(ORR).研究发现,当甲醇浓度为0.1 mol/L时,Pt/C催化剂的ORR活性最高,在催化层上热压商品Nafion NRE-212膜后也出现同样趋势.线性扫描伏安曲线显示,压膜前后的Pt/C催化剂的ORR活性在含0...

关键词: , , 甲醇渗透 , 氧还原 , 燃料电池

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