H.W. Yang
,
D.P. Tao
,
Z.H. Zhou
金属学报(英文版)
The mixing enthalpies of 23 binary liquid alloys are calculated by molecular interaction volume model (MIVM), which is a two-parameter model with the partial molar infinite dilute mixing enthalpies. The predicted values are in agreement with the experimental data and then indicate that the model is reliable and convenient.
关键词:
Molecular interaction volume model
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Dongping TAO
,
Zhuo CHEN
,
Dunfang LI
,
Yifeng GAO
,
Qianghua SHEN
材料科学技术(英文)
The coordination numbers in the molecular interaction volume model (MIVM) can be calculated from the common physical quantities of pure liquid metals. A notable feature of the model lie in its capability to predict the thermodynamic properties of solutes in the Zn-Pb-In and Zn-Sn-Cd-Pb dilute solutions using only the binary infinite dilute activity coefficients, and the predicted values are in good agreement with the experimental data of the dilute solutions.
关键词:
Activity
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