Chengtao LI
金属学报(英文版)
The corrosion behaviors of alloy 690 in 1 wt pct sodium hydroxide aqueous solutions with and without PbO were characterized by electrochemical measurements, including potentiodynamic polarization, electrochemical impedance spectroscopy and Mott-Schottky measurement. The results reveal that there is a great difference between the corrosion behaviors of alloy 690 in the two tested solutions. The corrosion current density in PbO-containing solution is higher than that in the solution without PbO, which may be attributed to the anodic dissolution of metallic lead deposited at the early stage of polarization. The electrochemical impedance of the specimen in PbO-free solution is higher than that in the solution containing PbO. The slope of the Mott-Schottky curve in Pb-containing solution decreases notably compared with that in the Pb-free solution, which can be interpreted by the chromium depletion in the duplex structure of passive films.
关键词:
Alloy 690
,
电化学阻抗谱
,
氧化铅
,
Mott-Schottky曲线
,
钝化膜
王光耀
,
王浩
中国腐蚀与防护学报
应用XPS和电化学测量技术研究了Ti-15Mo合金在70℃的1mol/L和4mol/LHCl溶液中不同阳极极化条件下生成的钝化膜。结果表明,钝化膜是双层结构,由表层和过渡层组成。在低极化电位(0.000和-0.100V)下膜表层较厚(4nm),富集Mo。在高极化电位(+0.900V)下膜表层较薄(2nm),贫Mo。在钝化膜内含有较多Cl~-,而且Cl~-分布很深。推测Cl参加了膜的生成反应,生成了Ti和Mo的含氯和氧的化合物。
关键词:
钝化腹
,
XPS
,
Ti-Mo alloy
