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TRANSMISSION ELRCTRON MICROSCOPY INVESTIGATIONS OF LOW-PRESSURE CVD GROWTH AND STRAIN RELAXATION OF Ge ISLANDS ON Si(110)

E.Spiecker

金属学报(英文版)

Shapes, dimensions, arrangements and the microstructure of self-assembled islands fabricated by low-pressure chemical vapour deposition (LPCVD) of Ge at 700℃ onto Si(110) substrates have been investigated for different nominal Ge coverage by transmission electron microscopy (TEM) of plan-view and cross-section specimens and have been compared with photoluminescence (PL) measurements of Si-capped layer samples. The transition from the 2-dimensional layer to the 3-dimensional island growth mode takes place for a Ge deposition of nominally less than 2 monolayers. Upon this transition, many coherent islands and few larger islands with extended defects are observed. The coherent islands possess a dome-like shape and lateral sizes up to 130nm. Photoluminescence spectra show island-related peaks whose energy positions are shifted towards lower energy with higher Ge coverage.

关键词: Si-Ge heteroepitaxy , null , null

THE INFLUENCE OF ISLAND-INDUCED STRAIN ON THE Si SURFACE MORPHOLOGY IN Ge-Si MULTILAYERS: A TRANSMISSION ELECTRON MICROSCOPY STUDY

H.M.Lu

金属学报(英文版)

Growth and ordering of coherently strained Ge-rich islands in Ge/Si single layer and multilayer systems and the influence of island arrangements on the evolution of the surface morphology of Si cap layers during deposition by low-pressure chemical vapour deposition(LPCVD) on Si(001) substrates at 700℃ have been investigated by TEM of cross-section and plan-view specimens. At distances between the Ge layers of 35-50nm, vertical order of GeSi islands is observed for Ge-Si bilayer systems and for Ge-Si multilayer systems consisting of 5 layer pairs whereas lateral ordering parallel to <100> substrate directions is observed for the latter case only. In agreement with earlier results the vertical ordering in the multilayer system can be understood as result of the elastic interaction between island nuclei forming in the layers with close islands in a buried layer below. The lateral ordering along <100> may be attributed to the anisotropy of the elastic interaction. Characteristic for all Si surfaces are the spatial correlation between the presence of island-induced lattice strain and the appearance of arrays of larger square-shaped pyramids with distinct faceting and facet edges along <110>. The results reflect the importance of the control of growth parameters and of the island-induced strain state for the evolution of the Si top layer surface morphology during LPCVD growth.

关键词: Si-Ge heteroepitaxy , null , null

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