{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"在水相中合成了硫普罗宁(Tiopronin,TP)修饰的CdTe/CdS量子(TP-CdTe/CdS QDs).利用紫外-可见吸收光谱、荧光光谱研究了TP-CdTe/CdS QDs与丝裂霉素(mitomycin C,MMC)的相互作用机理.在pH=7.6的tris-HCl缓冲溶液介质中,TP-CdTe/CdS QDs与MMC相互作用,使TP-CdTe/CdS QDs的荧光发生猝灭,并且QDs的荧光强度与MMC的浓度有良好的线性关系(r=0.9991),线性范围4.7×10-9~1.2×10-8g/mL,检出限(3σ)为1.4×10-g/mL.此方法快速简便,用于尿样中丝裂霉素的测定,实验结果令人满意.","authors":[{"authorName":"李萍萍","id":"4720d3d4-881c-48be-9d02-29c4703a27e8","originalAuthorName":"李萍萍"},{"authorName":"殷鹏飞","id":"10f7bf42-df84-44d7-a785-01e68dbbe48a","originalAuthorName":"殷鹏飞"},{"authorName":"龚会乎","id":"0b98ffcb-6ebb-477e-a246-968069b81fc4","originalAuthorName":"龚会乎"},{"authorName":"刘正清","id":"cde4e118-154e-4fb5-9db9-15768465c6dd","originalAuthorName":"刘正清"},{"authorName":"王晓丹","id":"d5b92c8d-a0f2-4193-b2e0-4df4418fc648","originalAuthorName":"王晓丹"},{"authorName":"何佑秋","id":"f62a6ee1-fb48-4eb7-abac-9b4109e817e2","originalAuthorName":"何佑秋"}],"doi":"10.3724/SP.J.1095.2012.00326","fpage":"705","id":"fb8bd5e0-c2ba-48ea-aaf8-3dd7af3ebe06","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"7c3a959b-f8d7-4fa3-ba79-a36e085d24d1","keyword":"CdTe/CdS量子","originalKeyword":"CdTe/CdS量子点"},{"id":"6a5cf990-d54b-4abc-a421-ac42a51ecabd","keyword":"紫外-可见吸收光谱","originalKeyword":"紫外-可见吸收光谱"},{"id":"189bc12c-9d6c-4085-9565-8c86899ad54e","keyword":"荧光猝灭法","originalKeyword":"荧光猝灭法"},{"id":"1f8fb142-fd88-4abe-b673-e30dd1ac466f","keyword":"丝裂霉素","originalKeyword":"丝裂霉素"}],"language":"zh","publisherId":"yyhx201206016","title":"CdTe/CdS量子与丝裂霉素的相互作用及其应用","volume":"29","year":"2012"},{"abstractinfo":"采用水相法合成了Cu掺杂CdTe量子,并用CdS壳层进行包覆,得到了Cu∶CdTe/CdS核壳结构量子。采用荧光发射光谱(FL)、紫外可见吸收光谱(UV-Vis)、透射电镜(TEM)以及能谱仪(EDS)等手段对 CdTe量子和Cu∶CdTe/CdS核壳量子进行了表征。研究了不同 Cu 掺杂浓度、CdS壳层生长时间以及 Cd/硫脲物质的量比对Cu∶CdTe掺杂量子光学性能的影响,并采用人成骨肉瘤细胞(MG-63细胞)对样品做了细胞毒性分析。研究结果表明:通过掺杂和包壳的步骤,合成的 Cu∶CdTe/CdS 核壳量子点在 CdTe 量子的基础上实现了荧光发射红移,荧光强度提高,以及细胞毒性降低。","authors":[{"authorName":"肖立","id":"86856935-0eaf-4afe-8367-9b35bf0d31fd","originalAuthorName":"肖立"},{"authorName":"赵欢","id":"e3bf0352-8ddd-47d1-8b9f-871099a5fcaf","originalAuthorName":"赵欢"},{"authorName":"范红松","id":"4571c438-8209-43fd-8998-4c158085a14a","originalAuthorName":"范红松"}],"doi":"10.11896/j.issn.1005-023X.2016.22.012","fpage":"55","id":"5769a63a-dd92-4a2d-b33e-1e0c03d5286b","issue":"22","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"f90a0f40-81b7-487c-8e5d-325c616fda29","keyword":"量子","originalKeyword":"量子点"},{"id":"6c5005f6-3aca-4031-9268-ff640932bd8a","keyword":"Cu∶CdTe/CdS","originalKeyword":"Cu∶CdTe/CdS"},{"id":"6d324be9-6a53-4a8a-8263-d523a4b5f86f","keyword":"核壳结构","originalKeyword":"核壳结构"},{"id":"b3a2324c-c2f6-4ac6-a827-92249af4ba40","keyword":"光学性能","originalKeyword":"光学性能"},{"id":"97310069-e610-49c2-a980-c60d72016841","keyword":"细胞毒性","originalKeyword":"细胞毒性"}],"language":"zh","publisherId":"cldb201622012","title":"水溶性Cu∶CdTe/CdS核壳量子的合成、表征及细胞毒性检测","volume":"30","year":"2016"},{"abstractinfo":"本文在水热法合成水溶性CdTe及核壳结构CdTe/CdS量子的基础上,分别研究了细胞色素c对CdTe量子CdTe/CdS核壳量子荧光的猝灭效应和CdTe量子对牛血清白蛋白荧光的猝灭效应,并阐述了猝灭机理.结果显示,细胞色素c对CdTe量子的荧光猝灭效应具有一定的粒径依赖性,粒径越小,猝灭效应越强;细胞色素c对CdTe/CdS核壳量子的猝灭效应比对CdTe量子的更强,揭示了受激电子的表面传递机理.CdTe量子通过松散牛血清白蛋白的螺旋结构而猝灭其荧光.","authors":[{"authorName":"焦勇","id":"426e8379-9a9a-47bb-a34e-ca182296d004","originalAuthorName":"焦勇"},{"authorName":"李荣霞","id":"86c990b2-d6cc-4e74-9c05-34aae491000f","originalAuthorName":"李荣霞"},{"authorName":"安文汀","id":"8dac0400-f81b-4b48-a424-0e884489dc67","originalAuthorName":"安文汀"},{"authorName":"李世琴","id":"e07aa7bf-7b11-4cd7-a4de-053733b9bad9","originalAuthorName":"李世琴"},{"authorName":"赵俊红","id":"719a8411-5c57-47a0-b9f3-f8087abe8fd9","originalAuthorName":"赵俊红"}],"doi":"10.7517/j.issn.1674-0475.2014.02.181","fpage":"181","id":"e8563236-d0fa-48e3-b32b-1952bd8ee9d4","issue":"2","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学 "},"keywords":[{"id":"26bfc593-ad9c-456d-b641-acb61462034c","keyword":"CdTe量子","originalKeyword":"CdTe量子点"},{"id":"52d6220f-a62f-4aea-9d12-0b66f203e540","keyword":"CdTe/CdS核壳量子","originalKeyword":"CdTe/CdS核壳量子点"},{"id":"850a08e9-1e22-40bb-9c11-baa29352ed43","keyword":"细胞色素c","originalKeyword":"细胞色素c"},{"id":"31e414a6-761b-4ff7-badd-18a9ef638e65","keyword":"牛血清白蛋白","originalKeyword":"牛血清白蛋白"},{"id":"5870f2c5-09b8-4163-af89-e282265f1f13","keyword":"荧光猝灭效应","originalKeyword":"荧光猝灭效应"},{"id":"66d838ab-1883-41dd-8208-f5a9d193c096","keyword":"荧光猝灭机理","originalKeyword":"荧光猝灭机理"}],"language":"zh","publisherId":"ggkxyghx201402007","title":"CdTe量子与蛋白质相互作用的荧光猝灭效应","volume":"32","year":"2014"},{"abstractinfo":"合成了巯基乙酸(TGA)修饰的壳核型CdTe/CdS量子(TGA-CdTe/CdSQDs).利用紫外-可见光谱吸收、荧光光谱研究TGA-CdTe/CdS QDs与盐酸药根碱(JH)的相互作用机理.在pH值为7.4的tris-HCl缓冲溶液介质中,QDs与JH相互作用后使QDs的荧光呈线性猝灭,并有良好的线性关系(r=0.999 1),线性范围0.011 ~ 10 mg/L,检出限(3σ为3.3×10-3 mg/L,因此可以作为一种快速、简便、定量测定盐酸药根碱的新方法.","authors":[{"authorName":"殷鹏飞","id":"4b98ee62-1502-4fcd-bbcf-9e12653fe7cc","originalAuthorName":"殷鹏飞"},{"authorName":"龚会平","id":"e25ce8e2-2e64-41e1-890b-97080ba2f6f5","originalAuthorName":"龚会平"},{"authorName":"刘正清","id":"2b344975-406f-489a-89bc-df0e64bb39de","originalAuthorName":"刘正清"},{"authorName":"王晓丹","id":"9b7db396-f6d8-4991-a5e8-6f598f1b42d8","originalAuthorName":"王晓丹"},{"authorName":"李萍萍","id":"bd0746af-352b-41a4-9bf1-b8e717704b89","originalAuthorName":"李萍萍"},{"authorName":"何佑秋","id":"ac8bc3e1-2516-4629-9f9e-03a7118cb925","originalAuthorName":"何佑秋"}],"doi":"10.3724/SP.J.1095.2012.00163","fpage":"320","id":"1f55aea5-efeb-4522-b885-aa944551f942","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"51906784-b683-4c54-bfc1-a572cc23ac10","keyword":"盐酸药根碱","originalKeyword":"盐酸药根碱"},{"id":"850ed585-0eb7-4286-bc1c-5a6ef3dfc475","keyword":"壳核型CdTe/CdS量子","originalKeyword":"壳核型CdTe/CdS量子点"},{"id":"7f757560-5a68-436a-8946-4be011e6c8b1","keyword":"紫外-可见吸收","originalKeyword":"紫外-可见吸收"},{"id":"578de4c2-0c7f-4755-9440-f54b66bb7707","keyword":"荧光猝灭法","originalKeyword":"荧光猝灭法"}],"language":"zh","publisherId":"yyhx201203015","title":"紫外-可见吸收、荧光光谱研究壳核型CdTe/CdS量子与盐酸药根碱的相互作用及其应用","volume":"29","year":"2012"},{"abstractinfo":"以巯基丙酸为稳定剂, 在水相中合成了表面带负电荷、具有良好的分散性、平均粒径为5nm的CdTe量子. 通过CdTe量子与阳离子聚电解质聚二烯丙基二甲基氯化铵(PDDA)和阴离子聚电解质聚苯乙烯磺酸钠(PSS)之间的静电相互作用, 在石英基片表面通过层层静电自组装方法制备了多层CdTe量子纳米薄膜. 以荧光分光光度计、UV-Vis、XPS、AFM等测试手段对所得的CdTe量子纳米薄膜进行了表征. 研究结果表明, CdTe量子自组装多层薄膜的UV-Vis吸光度与组装层数基本呈线性关系, 薄膜成膜质量良好. 自组装薄膜基本上规整并均匀地覆盖在石英基底表面, 但薄膜中存在部分CdTe量子聚集现象. 通过在相邻的两层CdTe量子之间引入基本结构单元为PDDA/PSS/PDDA的聚电解质复合层, 可有效提高CdTe量子纳米薄膜的成膜质量. 所得的CdTe量子纳米薄膜具有良好的荧光光致发光性.
","authors":[{"authorName":"刘明贤","id":"586691a2-1dad-497c-bd87-1ec422df6a4d","originalAuthorName":"刘明贤"},{"authorName":"孙颖","id":"d5647d72-93d4-4a23-bff1-15d3328ea2b7","originalAuthorName":"孙颖"},{"authorName":"甘礼华","id":"e690ea72-817f-478e-b706-062762c82578","originalAuthorName":"甘礼华"},{"authorName":"王京红","id":"fa7d3560-9292-4b00-8527-b46c198cf5a3","originalAuthorName":"王京红"},{"authorName":"徐子颉","id":"d66846e2-ba21-4181-9fde-2485111d7ae9","originalAuthorName":"徐子颉"},{"authorName":"陈龙武","id":"528337d4-e8ea-4765-851c-b3a3d37fe169","originalAuthorName":"陈龙武"}],"categoryName":"|","doi":"10.3724/SP.J.1077.2008.00557","fpage":"557","id":"f69a2ecf-ccd7-4702-ba34-925995a91a5a","issue":"3","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"13fc5b19-1fc1-4805-92fb-c8493949903c","keyword":"纳米薄膜","originalKeyword":"纳米薄膜"},{"id":"28b29770-cc3a-45e7-9cf0-3ab01a720280","keyword":"null","originalKeyword":"null"},{"id":"d725c918-ae38-4749-b649-0ad0cb88a505","keyword":"null","originalKeyword":"null"},{"id":"dab756d2-3c06-4b2a-bf02-1d45129febc3","keyword":"null","originalKeyword":"null"}],"language":"zh","publisherId":"1000-324X_2008_3_26","title":"静电自组装制备CdTe量子纳米薄膜","volume":"23","year":"2008"},{"abstractinfo":"以巯基丙酸为稳定剂,在水相中合成了表面带负电荷、具有良好的分散性、平均粒径为5nm的CdTe量子.通过CdTe量子与阳离子聚电解质聚二烯丙基二甲基氯化铵(PDDA)和阴离子聚电解质聚苯乙烯磺酸钠(PSS)之间的静电相互作用,在石英基片表面通过层层静电自组装方法制备了多层CdTe量子纳米薄膜.以荧光分光光度计、UV-Vis、XPS、AFM等测试手段对所得的CdTe量子纳米薄膜进行了表征.研究结果表明,CdTe量子自组装多层薄膜的UV-Vis吸光度与组装层数基本呈线性关系,薄膜成膜质量良好.自组装薄膜基本上规整并均匀地覆盖在石英基底表面,但薄膜中存在部分CdTe量子聚集现象.通过在相邻的两层CdTe量子之间引入基本结构单元为PDDA/PsS/PDDA的聚电解质复合层,可有效提高CdTe量子纳米薄膜的成膜质量.所得的CdTe量子纳米薄膜具有良好的荧光光致发光性.","authors":[{"authorName":"刘明贤","id":"909bd0ad-acd6-4991-b009-d58ff146e0b5","originalAuthorName":"刘明贤"},{"authorName":"孙颖","id":"a0c5d76c-3d43-41d4-83a2-2a50391bbcfd","originalAuthorName":"孙颖"},{"authorName":"甘礼华","id":"0d03bf42-c7a3-416b-85aa-5a3345057889","originalAuthorName":"甘礼华"},{"authorName":"王京红","id":"d89a14e0-b891-4522-b986-2cdfdce6f351","originalAuthorName":"王京红"},{"authorName":"徐子颉","id":"535f2666-d579-4e57-9bbf-60b3425258df","originalAuthorName":"徐子颉"},{"authorName":"陈龙武","id":"ae72083a-5ee1-47ae-be5f-8ef3edcfd385","originalAuthorName":"陈龙武"}],"doi":"10.3321/j.issn:1000-324X.2008.03.028","fpage":"557","id":"4e223317-5919-4828-ad6a-b6c977c4d5b4","issue":"3","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"304aa57c-4792-4b1a-9397-b821fb22bb62","keyword":"纳米薄膜","originalKeyword":"纳米薄膜"},{"id":"4a7ff0e8-5760-45fd-8a67-346a7b3cb36b","keyword":"CdTe量子","originalKeyword":"CdTe量子点"},{"id":"82484b69-4c9c-4ee5-b838-57f85fda9afe","keyword":"静电自组装","originalKeyword":"静电自组装"},{"id":"5a88114e-b280-48bc-938b-b0c761d7ccf4","keyword":"荧光","originalKeyword":"荧光"}],"language":"zh","publisherId":"wjclxb200803028","title":"静电自组装制备CdTe量子纳米薄膜","volume":"23","year":"2008"},{"abstractinfo":"以NaTeO3为碲源,还原型谷胱甘肽(GSH)为稳定剂,一步合成CdTe量子.研究了参与反应回流的镉与碲摩尔比和Cd2+浓度对CdTe量子生长速率的影响,并用荧光光谱、X射线衍射光谱及透射电子显微镜对其性能进行表征.结果表明:GSH稳定的CdTe量子具有闪锌矿结构、球形形貌;在pH =8.5,n(Cd2+)∶ n(GSH)=1∶1.2,C(Cd2)=0.67 mmol/L,n(Cd)∶ n(Te)=6∶1时,CdTe量子荧光量子效率最高可达51.53%,并且量子生长的速率在初期的1h内达到最高点,并随着时间的延长呈下降趋势.","authors":[{"authorName":"姜青松","id":"aed2fec6-2200-4b9a-b1a8-37a8425cc627","originalAuthorName":"姜青松"},{"authorName":"朱月华","id":"00df5b5a-3a00-447d-b5a9-586a17c5ced3","originalAuthorName":"朱月华"},{"authorName":"邢海东","id":"d5f87ced-d522-452f-993c-8dc667cd3492","originalAuthorName":"邢海东"},{"authorName":"施丰华","id":"a6ef7287-a335-4a50-b428-05db5229a543","originalAuthorName":"施丰华"},{"authorName":"卓宁泽","id":"b7a4c8d6-e82f-4984-ab5f-66070512754a","originalAuthorName":"卓宁泽"},{"authorName":"王海波","id":"e4c553e3-e17c-4b8b-94ec-fcc7f33510e5","originalAuthorName":"王海波"}],"doi":"","fpage":"1981","id":"3a1b3394-dcd5-4d2b-ab56-0afcde9bc550","issue":"8","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"e09f2e4c-de1d-4fd1-b989-dcf62fc489c1","keyword":"碲化镉量子","originalKeyword":"碲化镉量子点"},{"id":"7935bc1e-9da3-48ad-ae86-5cabf272b6c8","keyword":"生长速率","originalKeyword":"生长速率"},{"id":"972dffdb-6f54-49fa-8651-b7456048546f","keyword":"量子效率","originalKeyword":"量子效率"}],"language":"zh","publisherId":"rgjtxb98201408018","title":"CdTe量子生长速率的参数研究","volume":"43","year":"2014"},{"abstractinfo":"在水相中合成高发光性能的CdTe量子,研究以巯基乙酸(TGA)为稳定剂对CdTe表面进行修饰,制备在水中分散性良好的纳米晶,通过对CdTe量子合成反应条件的摸索,掌握了其合成的反应规律.同时用紫外分光光度计、荧光分光光度计和透射电子显微镜对其进行了表征.结果表明,回流时间、n(Cd2+):n(HTe-)、反应物浓度、TGA用量、反应体系pH值,对纳米晶的光学性质具有显著影响.回流2 h制得的CdTe纳米粒子直径约为5 nm,其发射峰窄且对称,表现出良好稳定的光学性质.","authors":[{"authorName":"许世超","id":"c8c20ff7-0fe5-404e-aeb3-99a67fed67a8","originalAuthorName":"许世超"},{"authorName":"姚翠翠","id":"053fef38-7db4-4f5c-9c76-e67f9403c215","originalAuthorName":"姚翠翠"},{"authorName":"张纪梅","id":"1fa913fb-ff80-453f-9e85-04c42d9f59db","originalAuthorName":"张纪梅"},{"authorName":"代昭","id":"0ae854e2-8c30-489c-8134-0ede6b0bd4dc","originalAuthorName":"代昭"},{"authorName":"孙波","id":"9c45fffa-6aaf-4251-8e5f-1505cb3cdb37","originalAuthorName":"孙波"},{"authorName":"郑帼","id":"bc3972c8-f6f9-4b92-8b9c-ed0e9f568d1f","originalAuthorName":"郑帼"},{"authorName":"韩青","id":"e36c5956-60a9-400e-96c0-5cbe723ad92f","originalAuthorName":"韩青"},{"authorName":"胡斐","id":"9de8e5ac-7e74-4fa1-8729-ed24d1b230bd","originalAuthorName":"胡斐"},{"authorName":"周鸿明","id":"caf14131-5fd8-4a1c-9904-7b3c061fe774","originalAuthorName":"周鸿明"}],"doi":"","fpage":"161","id":"4362620e-5e19-4444-902b-b2e6334db7a2","issue":"3","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学 "},"keywords":[{"id":"a35ca1a0-988c-45ae-ab71-890906ea2b18","keyword":"CdTe量子","originalKeyword":"CdTe量子点"},{"id":"23a58046-333e-493d-aa83-8496b55a06b9","keyword":"纳米晶","originalKeyword":"纳米晶"},{"id":"0ad8d231-cf9b-4f87-9ff7-32892dc9c90f","keyword":"表面修饰","originalKeyword":"表面修饰"},{"id":"6e8882c9-4460-487f-873a-aff52b802889","keyword":"合成与表征","originalKeyword":"合成与表征"}],"language":"zh","publisherId":"ggkxyghx200903001","title":"表面修饰CdTe量子的合成及其光学特性","volume":"27","year":"2009"},{"abstractinfo":"以巯基乙酸(TGA)作为稳定剂,用微波辅助法快速合成了水溶性CdTe/CdSe核壳量子.比较了传统水热法和微波辅助法制备的量子性能,研究了加热温度、反应物配比及CdTe量子浓度对CdTe/CdSe核壳量子的性能影响.研究结果表明,核壳结构的CdTe/CdSe量子比单一的CdTe量子具有更优异的光致发光强度和光稳定性.","authors":[{"authorName":"徐昕","id":"6fcfeae5-7525-43b4-b871-6044470c8814","originalAuthorName":"徐昕"},{"authorName":"贺蓉","id":"7993b47b-3485-4475-aea2-742ab52decbb","originalAuthorName":"贺蓉"},{"authorName":"崔大祥","id":"3896f9d0-9d1d-4d1d-8c71-6e0472f95fac","originalAuthorName":"崔大祥"}],"doi":"","fpage":"659","id":"8af006ec-d849-49e2-b65c-643ab71a3728","issue":"4","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"c8a2ba86-eea7-4c9d-97b0-a1d9f997cc6d","keyword":"水溶性","originalKeyword":"水溶性"},{"id":"a6fe2734-5882-4f45-a842-b8ce68171fc0","keyword":"量子","originalKeyword":"量子点"},{"id":"c4d63896-205f-4d05-9dce-6a021db9c65a","keyword":"微波","originalKeyword":"微波"},{"id":"c2d5bed2-bc27-4713-912c-abdbfddeaeb3","keyword":"核壳","originalKeyword":"核壳"}],"language":"zh","publisherId":"gncl201104021","title":"微波辅助快速合成水溶性CdTe/CdSe核壳量子","volume":"42","year":"2011"},{"abstractinfo":"以醋酸镉、硫粉为原料制备CdS量子, 研究了硫的加入量对其光学性质的影响. 结果表明: 合成的CdS量子粒径均匀, 分散性较好, 随着硫加入量的增加CdS量子的粒径增大; 反应中过量的硫能有效地填补硫空位, 从而抑制表面态发光. 同时, ODA的修饰也能有效地钝化表面态, 减小表面态的发光强度.","authors":[{"authorName":"宋冰程轲武超杜祖亮","id":"9b1cc64a-76f8-40f9-9bf7-c1b3bc49cc58","originalAuthorName":"宋冰程轲武超杜祖亮"}],"categoryName":"|","doi":"","fpage":"89","id":"50eab229-aa1d-45f0-8f0f-33cc047a7c02","issue":"1","journal":{"abbrevTitle":"CLYJXB","coverImgSrc":"journal/img/cover/CLYJXB.jpg","id":"16","issnPpub":"1005-3093","publisherId":"CLYJXB","title":"材料研究学报"},"keywords":[{"id":"3ed2b736-fb96-47f6-b036-9fce7124a4bb","keyword":"无机非金属材料","originalKeyword":"无机非金属材料"},{"id":"b2f7f246-ccc9-4192-b1cf-7310ff4273ee","keyword":"CdS","originalKeyword":"CdS"},{"id":"e2c467fa-177f-4b96-a249-7234685c0a52","keyword":"quantum dot","originalKeyword":"quantum dot"},{"id":"c574699b-3737-4afe-98db-ee2b9099c80c","keyword":"quantum size effects","originalKeyword":"quantum size effects"},{"id":"d7e9c945-aa2b-4c08-a4cd-de6730acbd68","keyword":"surface states","originalKeyword":"surface states"}],"language":"zh","publisherId":"1005-3093_2009_1_13","title":"CdS量子的制备和光学性质","volume":"23","year":"2009"}],"totalpage":871,"totalrecord":8707}