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恒氧位下渣-熔Cu间Ti和Si的传输

薛向欣 , 杜鹤桂

金属学报

本文研究了1500℃恒氧位下与不同含有TiO_2和SiO_2渣系共存的熔态Cu-Ti Si合金中Ti和Si的表观传输现象。

关键词: Cu-Ti-Si合金 , apparent mass transfer

含H_2O气氛下Cu液中Ti的氧化

薛向欣 , 杜鹤桂

金属学报

本文研究了1500℃H_2O气氛下液态Cu合金中Ti的氧化。

关键词: Cu-Ti合金 , apparent mass transfer , oxidation

TRANSFER OF Ti AND Si BETWEEN SLAGS AND MOLTEN Cu UNDER CONSTANT OXYGEN POTENTIAL

XUE Xiangxin D U Hegui Northeast University of Technology , Shenyang China XUE Xiangxin , Dept.of Ferrous Metallurgy , Northeast University of Technology , Shenyang 110006 , China

金属学报(英文版)

An experimental study has been made of the mass transfer of Ti and Si between slags and mol- ten Cu under constant oxygen potential at 1500℃.Apparent mass transfer coefficients of Ti and Si in molten Cu have been obtained.

关键词: Cu-Ti alloy , null

OXIDATION OF Ti IN MOLTEN Cu UNDER WATERY ATMOSPHERE

XUE Xiangxin DU Hegui Northeast University of Technology , Shenyang , China XUE Xiangxin Lecturer , Dept.of Ferrous Metallurgy , Northeast University of Technology , Shenyang , 110006 , China

金属学报(英文版)

An experimental study has been made of oxidation kinetics of Ti in molten Cu-Ti alloy under watery atmosphere at 1500℃.The results may be expressed as follows: [Ti]_(Cu)=0.92-0.69t O≤t≤1.0(h) [Ti]_(Cu)=0.02t~2-0.14t+0.35 1.0≤t≤6.0(h) where t is time in hour.The apparent rate and order of reaction are: (-d[Ti]_(Cu))/dt=0.69,pseudo-zeroth order,k=0.69 (-d[Ti]_(Cu))/dt=0.14-0.04t,pseudo-0.85 order,k=0.39 The apparent mass tranfer coefficient is k'=0.16 cm/h,and the relation of W~2 vs time is: W~2=1.04·10~(-4)t

关键词: Cu-Ti alloy , null , null

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