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MECHANISM OF SECONDARY M_(23)C_6 PRECIPITATION AROUND MC IN A COBALT-BASE SUPERALLOY

W.H. Jiang , X.D. Yao , H.R. Guan and Z.Q. Hu(1) Department of Superalloys , Institute of Metal Research , The Chinese Academy of Sciences , Shenyang 110015 , China2) Department of Metal Materials Engineering , Shenyang Polytechnic University) Shenyang 110023 , China )Manuscript received in revised form 11 September 1998

金属学报(英文版)

Secondary M23C6 precipitation around primary MC carbide in a directionally solidified cobalt-base saperalloy was investigated duriny aging at 850℃. The results show that it was closely related to the decomposition of the MC. Two mechanisms were suggested,i.e. the in situ reaction, MC+γ→M23C6+C, and the direct reaction, M+C→M23C6,in which MC acted as a carbon source.

关键词: cobalt-base superalloy , null , null , null

钴基高温合金的循环氧化行为研究

袁福河 , 孙晓峰 , 管恒荣

中国腐蚀与防护学报

研究了钴基高温合金K40S在950℃和1000℃的循环氧化行 为.发现合金在950℃ 400 h以内的抗循环氧化性能较好.合金在1000℃氧化50 h以后因为 表面氧化膜剥落开始出现失重现象.在1000℃循环氧化初期的产物主要为Cr2O3,其次 为CoCr2O4和少量的CoO,400 h以后,Cr2O3基本剥落,合金表面由于Cr的损耗又生 成Cr2WO6、NiCr2O4以及挥发性的WO3氧化产物.添加Si和Mn元素使K40S合金抗循 环氧化性能明显地比不含Si和Mn元素的DZ40M钴基高温合金优越.

关键词: 钴基高温合金 , cyclic oxidation

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