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A COMBINATORIAL APPROACH TO THE OXIDATION RESISTANCE OF(Ti,Al)N AND Ti-Al-Si-N HARD COATINGS

R.Cremer , D.Neuschütz

金属学报(英文版)

The increasing complexity of modern functional materials leads to the demand of acost efficient tool for the development of new products. One possible approach to thisquestion is the adaptation of combinatorial methods to the specific requirements of ma-terials industry. These methods, originally developed for the pharmaceutical industry,have recently been applied to the screening of superconductive, magnetoresistant andphotoluminescent materials. The principle of these combinatorial approaches is thedeposition of large materials libraries in one process combined with fast methods forthe determination of the resulting properties. In this paper, the deposition and charac-terization of laterally graded materials libraries (composition spread) is presented. Thefilms have been deposited by reactive magnetron sputtering, using two or three metallictargets at a low angle to the substrate surface as well as a system of apertures. Toillustrate the advantages of combinatorial approaches for the development of advancedmaterials, the multicomponent metastable hardcoatings (Ti, Al)N and Ti-Al-Si-N arediscussed with special emphasis on the relations between structure and composition onthe one hand and the oxidation resistance of these coatings on the other. The resultsillustrate that the composition spread approach is a powerful and cost efficient tool forthe development and optimization of new multicomponent functional materials.

关键词: combinatorial chemistry , null , null , null

利用化学指示剂在多相催化反应中进行高通量筛选

孙波 , 孟祥举 , 王世超 , 孙淑清 , 肖丰收

催化学报

介绍了一种简单的组合化学技术,该技术利用催化反应中产物或反应物导致的化学指示剂的颜色变化快速地指示反应进程.选用甲基橙为指示剂,分子筛为催化剂,考察了不同反应条件下羧酸的酯化反应,并用气相色谱和高效液相色谱分析方法对实验结果进行验证.结果表明,利用化学指示剂进行的高通量颜色筛选结果与色谱检测结果很好地吻合,该方法具有简单和高效的特点,可应用于对化学指示剂敏感的反应.

关键词: 组合化学 , 高通量筛选 , 化学指示剂 , 沸石

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