Applied Physics a-Materials Science & Processing
LiBH(4) possesses a high hydrogen content, and though it is highly stable, its restoration from LiH+B+H(2) can only be accomplished under unacceptable high temperature and pressure conditions (650 degrees C and 15 MPa). Recently, it has been reported that destabilizing LiBH(4) by, i.e., MgH(2), transition metal oxides and chlorides presents a promising approach to exert its potential for hydrogen storage. In the present study, we find that simple mechanical milling with Al in a mole ratio of 2:1, markedly improves the reversible dehydrogenation performance of LiBH(4). The system possesses a theoretical capacity of 8.5 wt.% and could be reversibly operated at 400-450 degrees C. The combined property and phase examinations suggest that the observed property improvement should be associated with the formation of AlB(2) in the dehydriding process. Further cyclic examination found that the system suffered from a serious capacity loss in the dehydriding/rehydriding cycles. A better understanding of the degradation mechanism may provide a means for further material property improvement.
关键词:
complex hydrides
