方兆珩
,
陈家镛
金属学报
研究了合成镍硫化物的阳极过程。Ni_3S_2,Ni_7S_6和NiS的活性溶解伴随着生成表面产物层,其反应机理与电极电位有关。根据三种不同类型产物层生成规律的电化学研究,Ni溶出表观电子数的测定,以及产物层相组成分析和相的元素分析,认为存在三组平行反应:直接生成HSO_4~-或SO_(4-)~2的反应,生成中间硫化物的反应及生成元素硫的反应,每组反应具有不同的优势发展电位区。NiS_2阳极溶解时,基本上为生成HSO_(4-)或SO_(4-)~2的反应。
关键词:
镍硫化物
,
anodic dissolution
,
electrochemical behaviour
LIU Ping Institute of Aeronautical Material
,
Beijing
,
ChinaXU Changgan Beijing University of Aeronautics and Astronautics
,
Beijing
,
China XU Changgan
,
Associate Professor
,
Group 102
,
Beijing University of Aeronautics and Astronautics
,
37 Xueyuan Road
,
Beijing 100083
,
China
金属学报(英文版)
The electrochemical behaviour,which is presented by means of anodic polarization curves.of the component phases in Ti and Ti alloys in aqueous solutions of fluorhydrie acid,chhnhydric acid and amber acid has been investigated.The results indicate that the electrochemical behaviour of the allloys depends upon the composition and the lattice type.The corrosion of x and x′phase in actire region and that of β phase in passive region are the dominant corrosion behaviour.
关键词:
Ti alloy
,
null
,
null
