{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以改性聚丙烯酰胺、甲笨二异氰酸酯和聚醚多元醇为主要原料,采用一步发泡法,制备具有酰胺基(-NHCO-)的聚氨酯功能,并利用扫描电子显微镜(SEM)、傅里叶变换红外光谱仪(FT-IR)等对其性能进行表征.用该对溶菌酶/牛血清白蛋白混合液进行分离,通过SDS-PAGE电泳对其分离效果进行检测.结果表明,当制备的原料质童比为m(聚醚):m(甲笨二异氰酸酯):m(聚丙烯酰胺):m(丙酮):m(三乙烯二胺):m(二丁基二月桂酸锡):m(硅油):m(水)=100:150:25:20:0.6:0.4:1:0.1时,合成的孔陈率高,孔均匀,内外孔连通,溶胀度为18%,溶损率为0.036%,且具有功能基团酰胺基,对混合蛋白液具有良好的分离效果.","authors":[{"authorName":"和丽丽","id":"09a41d69-bf7a-44b7-94f2-79d107c205f6","originalAuthorName":"和丽丽"},{"authorName":"闫书一","id":"fdf5c317-d7ab-4995-a29b-541394b785ae","originalAuthorName":"闫书一"},{"authorName":"梁渠","id":"5e149d28-a67e-4e83-bf85-e1c4ac9c10e7","originalAuthorName":"梁渠"},{"authorName":"冯启明","id":"257d0755-e764-47bc-9a30-9710d28cadcc","originalAuthorName":"冯启明"},{"authorName":"王维清","id":"ebd3be26-ffe0-487f-ab72-62790924b9cb","originalAuthorName":"王维清"},{"authorName":"刘爱平","id":"df185bd2-d6a2-47e6-9679-d887d112b661","originalAuthorName":"刘爱平"}],"doi":"","fpage":"450","id":"e8f51837-3747-496c-8413-df3477377297","issue":"z3","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"b8255b2c-04ac-45a0-b929-69697befc5d0","keyword":"聚氨酯功能","originalKeyword":"聚氨酯功能泡塑"},{"id":"93fd08a2-d39f-4a45-a7ee-64e70484d1ae","keyword":"酰胺基","originalKeyword":"酰胺基"},{"id":"bc9aad35-6ebb-471f-b630-d78fc084606c","keyword":"蛋白","originalKeyword":"蛋白"}],"language":"zh","publisherId":"gncl2011z3019","title":"聚氨酯功能的制备及其分离蛋白性能的研究","volume":"42","year":"2011"},{"abstractinfo":"本文研究了SiO2和纤维增强剂对于聚氨酯塑料冲击性能的增强效应.试验结果表明,加入SiO2并不能增强聚氨酯塑料冲击性能.然而以2.5% KH550偶联剂四氢呋喃溶液处理的玻璃纤维作为增强剂,能使聚氨酯塑料的冲击性能有显著的提高.","authors":[{"authorName":"秦桑路","id":"534017a7-fca2-43f9-b2eb-5315fbcfe317","originalAuthorName":"秦桑路"},{"authorName":"杨振国","id":"392d86f8-14c2-4e79-a1fb-6ffdce51f5be","originalAuthorName":"杨振国"},{"authorName":"赵斌","id":"b35edd33-1137-4884-b575-3ccbfee236db","originalAuthorName":"赵斌"},{"authorName":"金忠(告羽)","id":"2ce24097-081d-42a2-8fa5-8ab4a2999ff1","originalAuthorName":"金忠(告羽)"},{"authorName":"王建华","id":"16943a5c-8e18-4c61-b25f-bc3e083ee8ef","originalAuthorName":"王建华"}],"doi":"10.3969/j.issn.1003-0999.2004.01.006","fpage":"18","id":"fee556b0-8222-4434-a17e-90c3b6bb5f7f","issue":"1","journal":{"abbrevTitle":"BLGFHCL","coverImgSrc":"journal/img/cover/BLGFHCL.jpg","id":"6","issnPpub":"1003-0999","publisherId":"BLGFHCL","title":"玻璃钢/复合材料"},"keywords":[{"id":"7e384c8d-8c79-443e-b8ac-50f3d85890bc","keyword":"聚氨酯塑料","originalKeyword":"聚氨酯硬泡塑料"},{"id":"487fa60a-ae57-4095-972f-3624df77aec3","keyword":"增强剂","originalKeyword":"增强剂"},{"id":"0f8b3121-988b-43a8-adc3-ac6d354729e1","keyword":"冲击性能","originalKeyword":"冲击性能"},{"id":"b1269b3e-fefa-4a8d-aa82-f4ffb1b1c23c","keyword":"偶联剂","originalKeyword":"偶联剂"}],"language":"zh","publisherId":"blgfhcl200401006","title":"增强聚氨酯塑料的冲击性能研究","volume":"","year":"2004"},{"abstractinfo":"以聚醚多元醇(PPO330)和甲苯二异氰酸酯(TDI)为原料,合成了一种孔结构较好的聚氨酯软质泡沫材料,研究了催化剂和匀剂质量分数对其孔结构的影响.结果表明,随着胺催化剂AN33质量分数的增大,泡沫孔径和开孔率都随之增大.而随着锡催化剂二丁基二月桂酸锡质量分数增大,泡沫的孔径和开孔率随之变小.匀剂L-580质量分数在1.0% ~1.5%之间时,泡沫孔径最大,随L-580质量分数增加,泡沫开孔率先增加后减小,在其质量分数为1.0%时,开孔率最大.","authors":[{"authorName":"魏徵","id":"bbeefb5e-971d-4965-821d-c284048e8c1f","originalAuthorName":"魏徵"},{"authorName":"王源升","id":"6c85cc02-7ae1-46df-ab73-9802a4cafac7","originalAuthorName":"王源升"},{"authorName":"王方超","id":"fb92887c-1af6-4381-a4d6-ca07e17bd1e3","originalAuthorName":"王方超"},{"authorName":"王轩","id":"5652807e-75a8-4ee2-b6f5-8fdc65c9425f","originalAuthorName":"王轩"}],"doi":"10.16865/j.cnki.1000-7555.2016.04.016","fpage":"86","id":"63d2711c-a971-4189-a9a0-3a929eb6b1d9","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"58ce7a7e-d0e6-4c6f-9ed1-bec873c5841c","keyword":"聚氨酯软质泡沫","originalKeyword":"聚氨酯软质泡沫"},{"id":"5e4c5c90-d22d-4e22-a649-5271caa5b337","keyword":"催化剂","originalKeyword":"催化剂"},{"id":"32f82f97-6ee7-45cb-b6b7-4a313534ac46","keyword":"匀剂","originalKeyword":"匀泡剂"},{"id":"eb8f6671-5e5f-471a-8a8d-a724605a4671","keyword":"孔结构","originalKeyword":"泡孔结构"}],"language":"zh","publisherId":"gfzclkxygc201604016","title":"催化剂和匀剂对聚氨酯软质泡沫孔结构的影响","volume":"32","year":"2016"},{"abstractinfo":"通过实验验证了在酸性介质存在条件下用ICP-MS法测定地电化学()样品中痕量金的可行性,在稀释因子存在条件下得到了方法的检出限为3 ng、精密度为1.40%.同时,通过制备模拟负载不同金含量的样品,计算加入标准物质回收率为88.80%~107.37%;与GAAS法测定结果进行显著性检验发现两组数据之间无显著性差异,其测定结果同样真实、可靠.","authors":[{"authorName":"聂凤莲","id":"ed0d73b1-4be0-45c4-9962-49ee25a1f980","originalAuthorName":"聂凤莲"},{"authorName":"张蜀冀","id":"f87112c3-76f6-46ca-9515-3eadbc0dd574","originalAuthorName":"张蜀冀"},{"authorName":"陈雪","id":"34fe4f96-d016-4e9f-8f50-a9aed240888b","originalAuthorName":"陈雪"},{"authorName":"艾晓军","id":"a3f83e1d-23a2-4b93-a48e-385acc74e944","originalAuthorName":"艾晓军"}],"doi":"10.3969/j.issn.1001-1277.2011.12.015","fpage":"58","id":"8c97b6af-5445-49a8-a1f7-e76204faa7fe","issue":"12","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"bbf3d2ea-dc71-491c-b786-d2aa2aef06d4","keyword":"地电化学()样品","originalKeyword":"地电化学(泡塑)样品"},{"id":"cdd09ee5-204e-48cd-a1f3-3b4e20abd2f7","keyword":"痕量金","originalKeyword":"痕量金"},{"id":"d2b58950-6fad-4103-bab3-86c272ff3630","keyword":"ICP-MS法","originalKeyword":"ICP-MS法"},{"id":"6a40b0f0-08ec-40d6-8563-fe4c4e4a5968","keyword":"测定","originalKeyword":"测定"}],"language":"zh","publisherId":"huangj201112015","title":"ICP-MS法测定地电化学()样品中痕量金","volume":"32","year":"2011"},{"abstractinfo":"针对消泡剂、润湿流平剂在聚氨酯(PU)亮光黑面漆中的效用和涂膜易产生的弊病,在相同条件下分别对其进行了平行对比实验,对PU亮光黑面漆消难的问题进行了深入的探究.实验结果显示,有机硅氧烷类流平剂OL31、丙烯酸酯类流平剂BYK358N、消泡剂BYK141搭配使用,效果优异,能获得良好的漆膜外观.","authors":[{"authorName":"何冬梅","id":"843c925b-e2ac-45c7-ade3-33ad3a56277f","originalAuthorName":"何冬梅"},{"authorName":"陈炳耀","id":"938a6f90-fe92-415f-a09a-365d836e2c79","originalAuthorName":"陈炳耀"},{"authorName":"谭学峰","id":"6706a69a-709e-42a3-8f3d-d1b2968c9a2a","originalAuthorName":"谭学峰"},{"authorName":"许耀魁","id":"c71a98fb-2442-4ca4-88d6-740a86f2ae59","originalAuthorName":"许耀魁"},{"authorName":"张熠","id":"7315ef12-ed2a-47b1-b2a8-e3640fe729a6","originalAuthorName":"张熠"},{"authorName":"陈炳强","id":"43716660-9152-4837-9295-2d4530b4b87d","originalAuthorName":"陈炳强"}],"doi":"","fpage":"13","id":"d24293cb-356a-477a-9a0c-e4a0c38212c7","issue":"4","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"5dc2112a-8211-44f6-aad1-6308f848f92a","keyword":"消泡剂","originalKeyword":"消泡剂"},{"id":"5f7d07fd-4b54-485e-9044-ca3a11fe411d","keyword":"流平剂","originalKeyword":"流平剂"},{"id":"48fab601-a53a-4a92-ae41-af4f2ce95ed0","keyword":"固化剂","originalKeyword":"固化剂"},{"id":"a149356c-8c38-4714-ab7d-6c096bb32992","keyword":"聚氨酯漆","originalKeyword":"聚氨酯漆"}],"language":"zh","publisherId":"tlgy201304004","title":"聚氨酯亮光黑面漆的消研究","volume":"43","year":"2013"},{"abstractinfo":"以不同系的多种阻燃剂添加于聚氨酯软质泡沫塑料(简称聚氨酯),进行部分物性和阻燃性能的对比试验,结果表明,大分子量的含磷类阻燃剂对软阻燃效果最好,且对其物理性能影响较小.","authors":[{"authorName":"张理平","id":"a9bfe7a1-439d-4a6a-b4b2-419f97978e52","originalAuthorName":"张理平"},{"authorName":"王俏","id":"b827e82e-21e5-4645-911e-d9ed56b1f166","originalAuthorName":"王俏"}],"doi":"10.3969/j.issn.1003-1545.2006.03.002","fpage":"4","id":"5805fe10-04d2-4c06-a8fe-bfaea0d876f7","issue":"3","journal":{"abbrevTitle":"CLKFYYY","coverImgSrc":"journal/img/cover/CLKFYYY.jpg","id":"10","issnPpub":"1003-1545","publisherId":"CLKFYYY","title":"材料开发与应用"},"keywords":[{"id":"376496e0-bea4-4f60-b330-f01d61bb05ae","keyword":"聚氨酯","originalKeyword":"聚氨酯"},{"id":"5c278878-7b39-4a1d-a516-85ecf9d79d11","keyword":"软质泡沫","originalKeyword":"软质泡沫"},{"id":"ec286af2-c22a-47b2-8667-b31e102b7311","keyword":"阻燃剂","originalKeyword":"阻燃剂"}],"language":"zh","publisherId":"clkfyyy200603002","title":"不同阻燃剂对聚氨酯阻燃性能影响的研究","volume":"21","year":"2006"},{"abstractinfo":"聚氨酯半硬质泡沫(SPUF)性能优异,应用广泛,但它属于易燃材料,且燃烧时极易产生烟毒,进而会对环境造成不利的影响.文中选用可膨胀石墨(EG)以及硅烷偶联剂KH791改性EG对全水发泡聚氨酯半硬进行阻燃,利用热重分析和残炭形貌对聚氨酯泡沫的热降解行为进行了研究,对比了EG改性前后对全水发泡聚氨酯半硬阻燃性能、热稳定性、力学性能和孔形貌的影响.结果表明,当EG的质量分数为20%时制得的可膨胀石墨阻燃聚氨酯泡沫氧指数可达29.4%,达到了UL94HB防火测试中HF-1级水平测试的要求;KH791改性EG后,阻燃效果略微降低,但是改性EG对于泡沫的孔形貌影响较小,能够提高全水发泡聚氨酯半硬的密度和压缩强度.","authors":[{"authorName":"窦艳丽","id":"92cc68d6-3c12-447c-8c05-d73b987ce78d","originalAuthorName":"窦艳丽"},{"authorName":"张天琪","id":"b9b07f07-0c8f-49e9-9aa5-b91078f2b80b","originalAuthorName":"张天琪"},{"authorName":"姚卫国","id":"62e17970-6037-45fb-be73-185fa0661db3","originalAuthorName":"姚卫国"},{"authorName":"付涛","id":"afeae1ab-89fa-49ab-93a3-376e44e3b03b","originalAuthorName":"付涛"},{"authorName":"管东波","id":"914dee7e-cf04-4699-b8fa-42b58d47486b","originalAuthorName":"管东波"}],"doi":"10.16865/j.cnki.1000-7555.2017.01.010","fpage":"50","id":"92928268-594f-4b5f-b07d-6ba7054b059b","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"eef66ebe-a663-4b07-936a-0ed1273e8e5c","keyword":"可膨胀石墨","originalKeyword":"可膨胀石墨"},{"id":"66ceb581-8821-4a5d-b9a5-41259c092b12","keyword":"半硬聚氨酯","originalKeyword":"半硬泡聚氨酯"},{"id":"79b8ce11-0998-4014-b2e6-0956ae9cc5c7","keyword":"表面改性","originalKeyword":"表面改性"},{"id":"f3ab8f96-4096-4332-a420-0d63785e6124","keyword":"阻燃性能","originalKeyword":"阻燃性能"},{"id":"48e9c90f-6cef-4fed-a51c-ed8d0ab420c6","keyword":"热稳定性","originalKeyword":"热稳定性"}],"language":"zh","publisherId":"gfzclkxygc201701010","title":"可膨胀石墨阻燃半硬聚氨酯材料的性能","volume":"33","year":"2017"},{"abstractinfo":"采用同步法合成了聚氨酯/环氧树脂互穿聚合物网络硬.为了研究聚氨酯/环氧树脂互穿网络聚合物(PU/ER IPN)硬对压缩载荷的响应及变形机理,对IPN硬进行了应变率在1.67×10(-4)S(-1)~1.67×10(-2)s(-1)范围内的静态压缩试验.研究表明,PU/ER IPN硬的压缩行为表现出明显的各向异性和应变率效应.平行发泡方向上的应力-应变曲线表现出三个变形阶段:即弹性阶段,\"平台\"阶段和\"硬化\"密实阶段,其平台阶段的显著特征是应变软化和局部变形.讨论了IPN硬的压缩力学本构关系.","authors":[{"authorName":"花兴艳","id":"1a30e25c-6889-4891-a48b-b925ad2671fd","originalAuthorName":"花兴艳"},{"authorName":"王源升","id":"bfdfaa2b-9756-4282-bab6-a2d21dd391b4","originalAuthorName":"王源升"},{"authorName":"赵培仲","id":"1fc6aed1-e25a-40ab-ba43-0eba7e502096","originalAuthorName":"赵培仲"},{"authorName":"朱金华","id":"e8777628-b48f-4d4d-af18-835f87915ded","originalAuthorName":"朱金华"}],"doi":"","fpage":"73","id":"de20b757-5826-4b36-a138-b62df5d9c6e2","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"f4fa910e-60e4-4fa6-bd87-5a7fd5091510","keyword":"聚氨酯/环氧树脂互穿聚合物网络","originalKeyword":"聚氨酯/环氧树脂互穿聚合物网络"},{"id":"dcaf9ab8-f89f-47f4-af0f-3b572baa024f","keyword":"硬","originalKeyword":"硬泡"},{"id":"c290366a-0e53-4287-ab2d-2334b7cbbd69","keyword":"静态压缩","originalKeyword":"静态压缩"},{"id":"fdf4daa5-448e-459d-a596-0a05a84d1815","keyword":"本构关系","originalKeyword":"本构关系"}],"language":"zh","publisherId":"gfzclkxygc201101020","title":"聚氨酯/环氧树脂互穿网络硬的静态压缩行为","volume":"27","year":"2011"},{"abstractinfo":"采用磷氮复合阻燃多元醇与通用聚醚配合制备阻燃聚氨酯,泡沫的尺寸稳定性均在1%左右,导热系数在0.03 W/(m·K)以下.压缩强度结果表明阻燃泡沫能满足一般建筑用聚氨酯保温材料的使用要求,动态力学测试表明泡沫的Tg随着阻燃聚醚用量的增加而升高,热失重测试表明硬的残炭量也随阻燃聚醚的增加而升高,阻燃多元醇制备的硬极限氧指数达到24.8%,较未做阻燃处理的泡沫有明显提高.","authors":[{"authorName":"张汪强","id":"615db8d4-8358-4959-b72a-bf3743818016","originalAuthorName":"张汪强"},{"authorName":"郭刚","id":"39345bc8-642f-4a0f-b3bf-59cc0b1f7ba0","originalAuthorName":"郭刚"},{"authorName":"邱进俊","id":"18b5a724-01db-476b-a013-fc285b6725e5","originalAuthorName":"邱进俊"},{"authorName":"刘承美","id":"45e1d36d-fc6c-437c-a1ed-2138f13ad90a","originalAuthorName":"刘承美"}],"doi":"","fpage":"141","id":"3948efa9-ab6a-488d-a912-587e8df69fa3","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"b4919231-14a2-4b65-bc1c-5dfcdbff319f","keyword":"聚氨酯硬质泡沫","originalKeyword":"聚氨酯硬质泡沫"},{"id":"f1e6aee2-e967-4251-91d0-7e3a3ddec384","keyword":"聚醚多元醇","originalKeyword":"聚醚多元醇"},{"id":"a7a1bb0a-71ca-4a3c-bdc9-f09226458afd","keyword":"四羟甲基硫酸鏻","originalKeyword":"四羟甲基硫酸鏻"},{"id":"25fc579b-e807-4940-a5a4-8e4540806f76","keyword":"反应型阻燃剂","originalKeyword":"反应型阻燃剂"}],"language":"zh","publisherId":"gfzclkxygc201509028","title":"反应型磷氮复合阻燃多元醇制备聚氨酯阻燃硬及性能","volume":"31","year":"2015"},{"abstractinfo":"采用尼龙66纤维及SiO2颗粒粉末作为增强剂制备了混杂增强聚氨酯塑料,这种混杂增强硬塑料的力学性能包括拉伸强度,压缩强度,冲击强度都有明显提高.研究表明,为达到增强效果增强剂必须以偶联剂预处理. 当尼龙66纤维的含量为7%, SiO2的含量为20%时所得聚氨酯泡沫塑料的力学性能增强最佳.SEM观察表明该硬塑料胞体平均大小为60 μm 左右.从拉伸断口形貌可看出纤维受力痕迹明显,表明纤维本身的拉伸强度对于硬塑料的力学性能增强起了重要作用.","authors":[{"authorName":"赵斌","id":"4808f60c-12ad-4e8a-82ed-c2cb843a988a","originalAuthorName":"赵斌"},{"authorName":"杨振国","id":"03791057-bcc0-448d-bdfc-11918627b6ad","originalAuthorName":"杨振国"},{"authorName":"王建华","id":"922d3b9f-73de-404d-b77c-39be238f666b","originalAuthorName":"王建华"},{"authorName":"胡正飞","id":"0ebf65aa-40c6-4c1b-801a-3105d68afb29","originalAuthorName":"胡正飞"},{"authorName":"秦桑路","id":"d5ee55d5-3b22-4fb0-bad9-81c1efe19d74","originalAuthorName":"秦桑路"},{"authorName":"金忠(告羽)","id":"905d42b1-3797-487e-bc7f-cb01b36ddbff","originalAuthorName":"金忠(告羽)"}],"doi":"","fpage":"188","id":"9a260ccb-70f4-4983-b1b2-dd4999fb24fc","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"7b0453a8-33a9-40fb-a162-d4fcff4fd159","keyword":"聚氨酯","originalKeyword":"聚氨酯硬泡"},{"id":"f1a75630-4e81-4581-a0d0-7918c61f073d","keyword":"混杂增强","originalKeyword":"混杂增强"},{"id":"30f733e2-3b24-4690-9d2d-b3b9d39d4217","keyword":"制备工艺","originalKeyword":"制备工艺"},{"id":"f62cafcb-fdf1-4b49-8076-9d8b40c1ef0a","keyword":"显微形貌","originalKeyword":"显微形貌"},{"id":"e63c3133-5b7d-46a8-baf2-cff5db45cd54","keyword":"尼龙66","originalKeyword":"尼龙66"},{"id":"f303b23c-ce32-4551-9121-2c7eeb084499","keyword":"二氧化硅","originalKeyword":"二氧化硅"}],"language":"zh","publisherId":"gfzclkxygc200501046","title":"纤维与颗粒混杂增强聚氨酯塑料的制备及显微形貌","volume":"21","year":"2005"}],"totalpage":897,"totalrecord":8964}