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EFFECT OF W ON MECHANICAL PROPERTIES OF 12%Cr HEAT-RESISTANT STEEL

LIU Xingyang Northeast University of Technology , Shenyang , China FUJITA Toshio The University of Tokyo , Tokyo , Japan

金属学报(英文版)

The effect of W on mechanical properties of 12% Cr-W-V-Nb heat resistant steel at high temperatures and room temperature is reported.The experimental results indicated that if the W content was about 2.2—3.0 wt-%,there was no obviously change of R.T.tensile strength, but impact toughness decreased with the rise of W content.On the other hand,the increase of W content enhanced the short time stress rupture strength,but did not for the long time one. The increase of W have two effects on the precipitation behavior,promoting Laves formation of type Fe_2W,increasing the precipitated phase amount and speeding up the coarsening pro- cess of precipitated phase at high temperatures.The effect of W on the mechanical properties is closely associated with precipitation behaviors.When the rupture life is short,there has no enough time to coarsen the precipitated phases,so the increase of precipitated phases results in strengthening effect,i.e.the W increases the high temperature strength.After prolonged expo- sure,the evident coarsening took plaee,that decreased the effect of precipitation.

关键词: 12%Cr-W-V-Nb steel , null , null , null

中国超超临界电站锅炉关键材料用钢及合金的研究现状

王敬忠 , 刘正东 , 包汉生 , 王快社

钢铁 doi:10.13228/j.boyuan.issn0449-749x.20140685

综述了近几年国内用于超超临界火电机组锅炉的马氏体耐热钢、奥氏体耐热钢、镍基耐热合金的研究情况.国内学者们对马氏体和奥氏体耐热钢高温强化机理和生产工艺进行了系统研究,并实现了马氏体/铁素体耐热钢T/P91、T/P92与奥氏体耐热钢S31042、S30432、TP347HFG的国产化,对新型9% Cr马氏体耐热钢展开了研究.对镍基合金的投入和研究还不够,研究内容不够系统,但表现出较好的势头,学者们正对Inconel 740、Alloy 617及其改型合金和Alloy 263合金进行较广泛的研究.对用于超超临界火电机组关键材料的研究提出了建议,展望了国内耐热钢及合金的研究趋势.

关键词: 马氏体耐热钢 , 奥氏体耐热钢 , 镍基合金 , 发展趋势

服役条件下马氏体耐热钢中碳化物演变与寿命相关性

王岗 , 胡正飞 , 何大海 , 吴细毛

材料热处理学报

12Cr马氏体耐热钢是发电及其它行业高温高压部件的关键用材.在高温高压环境下长期服役会导致材料的性能下降和组织结构退化.评价服役材料的可靠性一直是高度关注的实际问题.本文通过对发电锅炉X20再热器炉管在不同服役时期的性能和组织结构比较研究,材料硬度随寿命减损而下降,尤其是晶界硬度低于基体硬度.相应的微观结构出现碳化物粗化和蠕变损伤现象.定量分析显示,主要碳化物M23C6成分显示出明显的合金元素富集,粗化的M23C6碳化物中Cr/Fe原子比随服役时间的变化规律存在明确的动力学规律.

关键词: 马氏体耐热钢 , 碳化物 , 微观结构 , 蠕变损伤 , 化学成分富集

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