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含硼的Cu-Zn-Al合金中母相晶粒度和有序度对M_s的影响

吴建新 , 江伯鸿 , 徐祖耀

金属学报

研究了母相平均晶粒尺寸和有序度对Cu-25.62Zn-3.97Al-0.0018B(wt-%)形状记忆合金热弹性马氏体相变点的影响。从相变热力学出发,得到马氏体相变点和晶粒尺寸的平方根的倒数成线性关系,并且随晶粒尺寸增大,马氏体相变点升高,与电阻法测得的结果符合很好。运用Landau理论,得到马氏体相变点和母相有序度的定量关系式,与X光衍射和电阻法试验的结果符合较好。求得试验用合金母相DO_3有序化的激活能约为46kJ/mol。

关键词: Cu-Zn-Al合金 , shape memory alloy , thermoelastic martensite , grain size , ordering degree

INFLUENCE OF GRAIN SIZE AND ORDERING DEGREE OF PARENT PHASE ON SME IN A CuZnAl ALLOY CONTAINING BORON

WU Jianxin JIANG Bohong XU Zuyao(Hsu T.Y.) Shanghai Jiaotong University , Shanghai , China [Originally published in ACTA METALL SIN(CHINESE EDN)25(3)1989 pp A173—A178. Professor , Dept.of Materials Science , Shanghai Jiaotong University , Shanghai , China

金属学报(英文版)

The influence of grain size and ordering degree of the parent phase on the shape memory re- covery in a Cu-25.62Zn-3.97Al-0.0018B(wt-%)memory alloy is investigated.A mathematical relationship is set up between the recovery ratio and ordering degree,probabili- ty of atoms at their ordered sites,grain size,the thickness of the grain boundary affected re- gions,the stress during deformation,as well as the critical shear stress.Shape memory effect reaches a maximum with varying grain size and increases linearly with increasing ordering parameter,which agrees well with experimental results.

关键词: CuZnAl alloy , null , null , null

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