{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"用新戊<span style=\"color:red\">二</span>醇(NPG)和<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>(TPA)反应生成\"低聚物\"中间体,当n(NPG)/n(TPA)由2.4增加至3.0时,中间体的聚合度(m)在3.5～1.45之间,收率75.5%.再将中间体与油酸、菜籽油酸进行酯化得到复合酯,收率88.5%.结果表明,复合酯的粘度随着分子量的增大而增大,粘度指数大于125,凝点低于-27 ℃,氧化稳定性随分子量的增大而提高,生物降解率＞70%,最大无卡咬负荷(P_B)为784 N,磨斑直径0.41 mm,热分解温度＞250 ℃,因此目标产物是性能良好的绿色润滑剂.","authors":[{"authorName":"廖德仲","id":"6adc76bb-3734-44f1-aa65-50b5d24c42f5","originalAuthorName":"廖德仲"},{"authorName":"张泰铭","id":"5637b914-11f3-4946-b1c6-9455122e2a50","originalAuthorName":"张泰铭"},{"authorName":"王素琴","id":"d5cd624a-4c33-451e-aa1d-8efd728c2b48","originalAuthorName":"王素琴"},{"authorName":"毛立新","id":"752b5395-6eac-4e7d-90ab-2b116d8e0ba3","originalAuthorName":"毛立新"},{"authorName":"许怡学","id":"82afdf09-1792-49ad-9b5b-fd3054cb56eb","originalAuthorName":"许怡学"}],"doi":"10.3724/SP.J.1095.2010.90140","fpage":"159","id":"d0010346-b341-4884-bf61-8f16a234d231","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"b7cfcfd9-c479-43c1-bac2-3279e3944440","keyword":"新戊<span style=\"color:red\">二</span>醇","originalKeyword":"新戊二醇"},{"id":"19b54921-03a1-4db9-a4f5-26b9f43b456f","keyword":"<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>","originalKeyword":"对苯二甲酰氯"},{"id":"cbbe7268-277d-41c3-9338-a7524f3ca22a","keyword":"油酸","originalKeyword":"油酸"},{"id":"411e2637-fc1c-480e-b031-4e0bd0a4fccd","keyword":"菜籽油酸","originalKeyword":"菜籽油酸"},{"id":"135e6a98-bcb4-4130-89cf-4fc368004118","keyword":"复合酯","originalKeyword":"复合酯"},{"id":"f5f28d42-ba84-4151-aebc-4f0ff4a5014b","keyword":"润滑性能","originalKeyword":"润滑性能"}],"language":"zh","publisherId":"yyhx201002008","title":"植物油酸新戊<span style=\"color:red\">二</span>醇<span style=\"color:red\">对苯二甲</span>酸复合酯的合成及其润滑性能","volume":"27","year":"2010"},{"abstractinfo":"研究了以1,2-<span style=\"color:red\">二氯</span>乙烷为溶剂,以无水三氯化铝/DMF为复合催化剂体系,在温和条件下,以<span style=\"color:red\">二</span>苯醚和<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>为原料合成高分子量聚醚酮酮(PEKK)的方法.该方法制备的PEKK其主要理化性能达到或超过了文献值,经济简便,污染小,是一个切实可行的制备方法.","authors":[{"authorName":"王长松","id":"72e60414-653f-452a-b066-5900744599c9","originalAuthorName":"王长松"},{"authorName":"黎前跃","id":"447605d5-be1e-4fdf-9cf6-d66f15ded07a","originalAuthorName":"黎前跃"},{"authorName":"崔连复","id":"83c44f22-1ec5-41da-a810-b4a0b5667d70","originalAuthorName":"崔连复"},{"authorName":"孔凡","id":"56927058-56a6-4eef-bf63-6db0c9ee5228","originalAuthorName":"孔凡"},{"authorName":"门志超","id":"187d30bc-cc52-48cf-8bd5-1d761384f7a2","originalAuthorName":"门志超"},{"authorName":"李三喜","id":"7c685599-58c9-4685-8bda-97421c9e6e1c","originalAuthorName":"李三喜"}],"doi":"","fpage":"44","id":"fbc221b6-50c5-4876-9336-ad6c46ed62ff","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"c17f6223-3dce-4396-9049-7b2412c34066","keyword":"聚醚酮酮","originalKeyword":"聚醚酮酮"},{"id":"40af0bd3-85d4-4c2a-98b8-8667b467e098","keyword":"缩聚反应","originalKeyword":"缩聚反应"},{"id":"ad4ba829-6277-4554-afde-57e89c845ceb","keyword":"<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>","originalKeyword":"对苯二甲酰氯"},{"id":"ce80bd0d-5445-472c-84ed-05258a9caa8c","keyword":"<span style=\"color:red\">二</span>苯醚","originalKeyword":"二苯醚"},{"id":"8b34e191-8e1c-45fe-b8bf-d3ef1a35c453","keyword":"Lewis酸碱络合物","originalKeyword":"Lewis酸碱络合物"}],"language":"zh","publisherId":"gfzclkxygc199902013","title":"聚醚酮酮的合成与表征","volume":"","year":"1999"},{"abstractinfo":"以饲料级维生素A醋酸酯为原料,通过提纯、相转移催化水解和选择性氧化得到视黄醛;对苯<span style=\"color:red\">二</span>胺与<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>反应,合成了端基为伯胺基团的聚酰胺,当反应起始温度为-10℃,单体对苯<span style=\"color:red\">二</span>胺与<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>的投料比为1.1∶1,起始单体浓度为0.4 mol/L,反应时间为45～60 min,聚酰胺的粘均分子量为800左右.通过视黄醛与聚酰胺反应,合成了聚合物视黄基席夫碱.通过FT-IR、元素分析、XRD、TG等分析和研究,对产物结构及其基本物理性能进行了表征.结果表明,所得产物为视黄基聚酰胺席夫碱.","authors":[{"authorName":"席敏","id":"6fd12a41-cc5b-4119-b82b-ffb5ef556bb1","originalAuthorName":"席敏"},{"authorName":"周祚万","id":"d9c3ddb5-1dea-46de-b316-a4030e226006","originalAuthorName":"周祚万"},{"authorName":"黄婷","id":"55ed36b7-44c6-4677-b68c-4cc36b8d9d8c","originalAuthorName":"黄婷"}],"doi":"","fpage":"258","id":"4dd88bf7-c64c-4533-8ca1-b285eda48dd2","issue":"z2","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"3ee17a90-e9d7-4be5-934c-7f721efd59ee","keyword":"视黄基席夫碱","originalKeyword":"视黄基席夫碱"},{"id":"7b6fdf47-4e75-49c1-bed5-4fda5935a174","keyword":"聚酰胺","originalKeyword":"聚酰胺"},{"id":"c812b145-c80e-4aaf-a809-cd5596692eab","keyword":"视黄醛","originalKeyword":"视黄醛"},{"id":"c435269a-e5a2-43ce-a6cf-ae91260bd39d","keyword":"<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>","originalKeyword":"对苯二甲酰氯"}],"language":"zh","publisherId":"cldb2007z2091","title":"聚合物型视黄基席夫碱的合成及其表征","volume":"21","year":"2007"},{"abstractinfo":"在KOH和K2CO3存在下,通过2,6-<span style=\"color:red\">二</span>氯苯<span style=\"color:red\">甲</span>腈(DCBN)与苯酚在N-甲基吡咯烷酮(NMP)中的缩合反应,合成了一种新单体2,6-<span style=\"color:red\">二</span>苯氧基苯<span style=\"color:red\">甲</span>腈(DPOBN). 在无水AlCl3及NMP存在下,将其与<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>(TPC)在1,2-<span style=\"color:red\">二氯</span>乙烷(DCE)中进行低温溶液缩聚,合成了含氰基聚芳醚醚酮酮(PEEKK). 当n(DPOBN)∶n(TPC)控制在1∶ 1,n(AlCl3)/n(TPC)控制在6～6.5,n(NMP)/n(TPC)控制在2.38～2.59时,聚合物的对数比浓粘度ηinh可达0.55. 用IR、DSC、TG、WAXD等测试技术对其结构和性能进行了表征. 结果表明,聚合物的Tg为180 ℃,比PEKK(Tg=156 ℃)要高,聚合物的Td为495 ℃. DSC和WAXD分析表明,含氰基PEEKK为非晶态聚合物.","authors":[{"authorName":"徐曲","id":"63edc1ac-ff6c-4592-924e-13eb046fc5d7","originalAuthorName":"徐曲"},{"authorName":"蔡明中","id":"023d8c5a-7bac-49fa-aaf0-535a2536cb2b","originalAuthorName":"蔡明中"},{"authorName":"宋才生","id":"ac55ec36-028e-4970-9ab1-9516dc94697e","originalAuthorName":"宋才生"}],"doi":"10.3969/j.issn.1000-0518.2003.03.008","fpage":"238","id":"93be3d8d-dd5b-4b28-80de-8a94dffb2c57","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"5ed92dd7-fba6-4686-99e1-98744f48b208","keyword":"聚芳醚醚酮酮","originalKeyword":"聚芳醚醚酮酮"},{"id":"3805d6d8-5766-4b8c-8ad8-2b083725ed1e","keyword":"<span style=\"color:red\">二</span>苯氧基苯<span style=\"color:red\">甲</span>腈","originalKeyword":"二苯氧基苯甲腈"},{"id":"56f8c3fd-f777-4e2a-9fb4-ac2f47bd9da3","keyword":"<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>","originalKeyword":"对苯二甲酰氯"},{"id":"32068859-35de-4733-92a3-b6fe0daa20ca","keyword":"低温溶液缩聚","originalKeyword":"低温溶液缩聚"}],"language":"zh","publisherId":"yyhx200303008","title":"含氰基聚芳醚醚酮酮(PEEKK)的合成","volume":"20","year":"2003"},{"abstractinfo":"在无水三氯化铝(AlCl3)和N,N-<span style=\"color:red\">二甲</span>基甲酰胺(DMF)存在下,以1,4-<span style=\"color:red\">二</span>苯氧基苯(DPB)、4,4′-<span style=\"color:red\">二</span>(2,6-<span style=\"color:red\">二甲</span>基苯氧基)<span style=\"color:red\">二</span>苯砜(o-M2DPODPS)和<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>(TPC)为单体,于1,2-<span style=\"color:red\">二氯</span>乙烷(DCE)中进行低温溶液缩聚反应,合成了一系列共聚物.用IR,DSC,WAXD,TGA等方法对共聚物进行表征和性能测试.研究结果表明,随着o-M2DPODPS含量的增加,共聚物的玻璃化转变温度(Tg)大幅提高,熔融温度(Tm)和结晶度则逐渐减小,溶解性能得到了一定的改善.","authors":[{"authorName":"刘勇军","id":"088a35ed-df19-4942-859a-96e44a1a04af","originalAuthorName":"刘勇军"},{"authorName":"温红丽","id":"e7daf5ff-76a3-4628-b25c-a10a0d189706","originalAuthorName":"温红丽"},{"authorName":"宋才生","id":"a08c7b04-fce5-4976-a709-b497ac7819f9","originalAuthorName":"宋才生"},{"authorName":"叶尚辉","id":"7ff8939a-eec4-41d5-8308-1c910c6795f5","originalAuthorName":"叶尚辉"},{"authorName":"钟鸣","id":"3e1d3fe7-bece-4620-b345-81387306e934","originalAuthorName":"钟鸣"},{"authorName":"刘晓玲","id":"8cd3c4a7-38ee-4264-8661-239140353b12","originalAuthorName":"刘晓玲"}],"doi":"","fpage":"64","id":"6f0e9dcc-5cb7-4108-8432-dce1ca4af436","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"b2b04264-44c1-4835-bada-7dff210b3876","keyword":"1,4-<span style=\"color:red\">二</span>苯氧基苯","originalKeyword":"1,4-二苯氧基苯"},{"id":"330c9259-fc65-428d-bfbb-230c6561a400","keyword":"4,4′-<span style=\"color:red\">二</span>(2,6-<span style=\"color:red\">二甲</span>基苯氧基)<span style=\"color:red\">二</span>苯砜","originalKeyword":"4,4′-二(2,6-二甲基苯氧基)二苯砜"},{"id":"e117313a-b7dc-41e8-9413-c1668cae6a54","keyword":"聚芳醚醚酮酮","originalKeyword":"聚芳醚醚酮酮"},{"id":"859c7b44-3a25-4658-af8d-e52af155527d","keyword":"缩聚","originalKeyword":"缩聚"}],"language":"zh","publisherId":"gfzclkxygc200604016","title":"4,4′-<span style=\"color:red\">二</span>(2,6-<span style=\"color:red\">二甲</span>基苯氧基)<span style=\"color:red\">二</span>苯砜、三苯<span style=\"color:red\">二</span>醚和<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>三元无规共聚物的合成与表征","volume":"22","year":"2006"},{"abstractinfo":"以4,4-<span style=\"color:red\">二</span>苯氧基<span style=\"color:red\">二</span>苯砜(DPODPS)作为第3单体,将其与<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>(TPC)和4,4-<span style=\"color:red\">二</span>苯氧基<span style=\"color:red\">二</span>苯酮(DPOBP)在无水AlCl3和N-甲基吡咯烷酮(NMP)存在下,于1,2-<span style=\"color:red\">二氯</span>乙烷(DCE)中进行低温溶液共缩聚反应,合成了一系列DPODPS/DPOBP/TPC三元共聚物. 用IR、WAXD、DSC和TG等对共聚物进行了表征和性能测试. 研究结果表明,随着DPODPS与DPOBP摩尔比的增加,共聚物的玻璃化转变温度(Tg)和热分解温度(Td)逐渐增加,而其熔融温度(Tm)及结晶温度(Tc)则逐渐降低.","authors":[{"authorName":"黎苇","id":"bebbda59-a495-4de9-944d-2eda33e0958c","originalAuthorName":"黎苇"},{"authorName":"蔡明中","id":"6df67048-bad4-44e5-a948-a5a6cb39e845","originalAuthorName":"蔡明中"},{"authorName":"宋才生","id":"4d282c8e-f131-4163-8750-b94a55c43303","originalAuthorName":"宋才生"}],"doi":"10.3969/j.issn.1000-0518.2002.07.011","fpage":"653","id":"6cb853a7-dc26-4ff7-bd2e-98a3a7c0c382","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"3d5d1ee9-695e-422b-8ab6-e303767a1dbd","keyword":"聚醚酮醚酮酮","originalKeyword":"聚醚酮醚酮酮"},{"id":"cc1ca9a7-f9ba-43c9-82fd-f8750448618c","keyword":"聚醚砜醚酮酮","originalKeyword":"聚醚砜醚酮酮"},{"id":"76b115e7-3ac3-4ebd-b4ca-492cec2b7448","keyword":"三元共聚物","originalKeyword":"三元共聚物"},{"id":"2b181018-e079-409f-a9bf-f893440bc836","keyword":"低温溶液缩聚","originalKeyword":"低温溶液缩聚"}],"language":"zh","publisherId":"yyhx200207011","title":"4,4'-<span style=\"color:red\">二</span>苯氧基<span style=\"color:red\">二</span>苯砜、4,4'-<span style=\"color:red\">二</span>苯氧基<span style=\"color:red\">二</span>苯酮、<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span><span style=\"color:red\">氯</span>三元共聚物的合成","volume":"19","year":"2002"},{"abstractinfo":"以浓硫酸为溶剂,聚乙<span style=\"color:red\">二</span>醇(PEG)为致孔剂,采用溶液相转化法制备了聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>对苯<span style=\"color:red\">二</span>胺(PPTA)多孔平板膜,考察了膜的纯水通量、力学强度、截留率等性能,并用场发射扫描电子显微镜观察膜形貌.结果表明,所得PPTA多孔膜为具有不对称结构的非均质膜,上表面(自由面)为致密层,下表面(玻璃板面)为多孔层,可观察到原纤化微孔结构,膜横截面存在典型的溶出指状孔.随PPTA含量降低、致孔剂相对分子质量和凝固浴温度提高,膜通透性均随之相应有所提高.PPTA多孔膜对卵清蛋白溶液截留率达90％以上,对油水乳化液截留率可迭70％以上.","authors":[{"authorName":"王纯","id":"c3061a26-1a9b-431a-af20-f40a9126315f","originalAuthorName":"王纯"},{"authorName":"肖长发","id":"8812be0a-ffbd-46ed-9663-a1dea4a728eb","originalAuthorName":"肖长发"},{"authorName":"黄庆林","id":"c8a683b1-1030-4b19-b099-8530d1285b78","originalAuthorName":"黄庆林"}],"doi":"","fpage":"149","id":"d085ad20-1171-40bc-94e5-78ffb831d43e","issue":"12","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"e7716303-3f8b-462d-9c54-42f84be9c145","keyword":"聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>对苯<span style=\"color:red\">二</span>胺","originalKeyword":"聚对苯二甲酰对苯二胺"},{"id":"2792b24c-01df-4abf-9455-d1576440d780","keyword":"多孔膜","originalKeyword":"多孔膜"},{"id":"e02c5333-de1a-4035-b056-9d91e767d86a","keyword":"溶液相转化法","originalKeyword":"溶液相转化法"},{"id":"df18bde2-530d-42a0-8fc0-652a8ea85f5c","keyword":"原纤化","originalKeyword":"原纤化"}],"language":"zh","publisherId":"gfzclkxygc201412030","title":"聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>对苯<span style=\"color:red\">二</span>胺多孔膜的制备及表征","volume":"30","year":"2014"},{"abstractinfo":"利用热重法研究了聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>十二碳<span style=\"color:red\">二</span>胺(PA12T)在N2气流中以不同升温速率β升温时的热降解过程及热降解动力学.结果表明,PA12T的热降解为一步反应;随着β的增大,降解温度线性升高,其起始平衡降解温度447.34 ℃,降解终止时的平衡热降解温度为474.54 ℃,最大降解速率时的平衡降解温度为466.17 ℃.为了确定PA12T的热降解机理,采用Kissinger动力学处理方法求得的表观活化能与用Coats-Redfern求得的活化能进行比较,分析鉴别出动力学表达式,从而确定了PA12T的热降解机理为Deceleration类型中的D1、D2、D3、D4机理,即扩散控制机理.","authors":[{"authorName":"高丽君","id":"68ab2925-70f4-4f98-8410-605a05cdb9ed","originalAuthorName":"高丽君"},{"authorName":"刘民英","id":"c67789b6-69a7-4bd2-b04e-448257214b87","originalAuthorName":"刘民英"},{"authorName":"赵清香","id":"7912dccb-9439-46e3-839f-bde85a3508d5","originalAuthorName":"赵清香"},{"authorName":"王玉东","id":"28ecf799-07b7-4c7d-87a8-c37d82676a13","originalAuthorName":"王玉东"},{"authorName":"杨小娟","id":"4eb41792-9573-46f1-bb09-99ded527c9ef","originalAuthorName":"杨小娟"},{"authorName":"曹少魁","id":"b51ccadb-a615-4925-8e93-34541c26a4af","originalAuthorName":"曹少魁"}],"doi":"","fpage":"129","id":"0ba8a1f8-1e41-445a-afa3-b3c3d56b3d25","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"e4b49e61-dbdd-40a3-86f9-0a4274995b9e","keyword":"聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>十二碳<span style=\"color:red\">二</span>胺","originalKeyword":"聚对苯二甲酰十二碳二胺"},{"id":"5470f2a6-3cb7-4e8c-93d7-fee07eef1763","keyword":"热降解","originalKeyword":"热降解"},{"id":"f594e941-d6d1-4e29-8bf4-c198d44a74d2","keyword":"机理","originalKeyword":"机理"},{"id":"6ee9f309-9540-4ed5-b097-ef2cb22d5444","keyword":"热重法","originalKeyword":"热重法"}],"language":"zh","publisherId":"gfzclkxygc200206033","title":"聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>十二碳<span style=\"color:red\">二</span>胺的热降解过程与机理","volume":"18","year":"2002"},{"abstractinfo":"介绍了在聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>对苯<span style=\"color:red\">二</span>胺(PPTA)树脂主链骨架改变、侧基上引入取代基和超支化结构等改性方法的研究现状,评价了几种方法的改性效果.分析结果表明,主链骨架改变和侧基上引入取代基改行方法仍是目前研究的主要方向;改善PPTA树脂性能的有效方法是改变聚合物的化学结构.","authors":[{"authorName":"宋涛","id":"bed10924-dafc-44b2-a5f2-8af90765b70e","originalAuthorName":"宋涛"},{"authorName":"王丹","id":"f0011268-a57e-44c0-bd6a-7dce499d713d","originalAuthorName":"王丹"},{"authorName":"廖学明","id":"e58fd912-7b38-4442-a050-665d00b59e4f","originalAuthorName":"廖学明"},{"authorName":"宋志祥","id":"4925ebd4-3f7d-4aa5-b537-3fcf856f13fe","originalAuthorName":"宋志祥"}],"doi":"10.3969/j.issn.1009-9239.2009.01.010","fpage":"33","id":"2d04ce8a-ca3d-4fcc-a06d-0cf63e5d086c","issue":"1","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"5b16f206-02d6-41e5-b74a-0683fab6aa0e","keyword":"PPTA","originalKeyword":"PPTA"},{"id":"cf46f033-0782-4e91-996e-fcdcdbc5a357","keyword":"共缩聚","originalKeyword":"共缩聚"},{"id":"3972bc35-894b-4c3e-9afd-f0a9a1a24625","keyword":"溶解性","originalKeyword":"溶解性"},{"id":"c119a02b-af36-4221-b435-db40d8ad5b32","keyword":"改性","originalKeyword":"改性"}],"language":"zh","publisherId":"jycltx200901010","title":"聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>对苯<span style=\"color:red\">二</span>胺树脂共缩聚改性研究进展","volume":"42","year":"2009"},{"abstractinfo":"以<span style=\"color:red\">对苯二甲</span>酸和癸<span style=\"color:red\">二</span>胺为原料,经成盐、预聚合和固相聚合三个步骤合成了新型长碳链和较高分子量的半芳香尼龙聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>十碳<span style=\"color:red\">二</span>胺(PA10T).用TG-DTG方法研究了PA10T的热降解和热降解动力学,结果表明,PA10T的热分解为一步降解,其起始平衡降解温度为435.3 ℃,终止平衡降解温度为470.7 ℃,最大降解速率时平衡降解温度为459.5 ℃.通过微分法和积分法计算出PA10T的热分解活化能分别为274.4 kJ mol-1和263.96～290.37 kJ mol-1之间,其耐热性能优于脂肪族尼龙.","authors":[{"authorName":"王文志","id":"75373023-be6e-4995-bba0-27319411edf6","originalAuthorName":"王文志"},{"authorName":"章永化","id":"05b7645a-7980-4688-9f5c-841f04b509b1","originalAuthorName":"章永化"},{"authorName":"尹国杰","id":"79be5952-4097-4a59-9bc8-5c4d8200fa0e","originalAuthorName":"尹国杰"}],"doi":"10.3969/j.issn.1671-5381.2009.02.004","fpage":"14","id":"6b8c4448-04a0-4e22-81dc-fe8d95202b0b","issue":"2","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"62a37a8b-27f3-4ea0-824a-a35aa47e064b","keyword":"<span style=\"color:red\">对苯二甲</span>酸","originalKeyword":"对苯二甲酸"},{"id":"2869e122-be3f-4161-8e5f-e6e333e03c39","keyword":"癸<span style=\"color:red\">二</span>胺","originalKeyword":"癸二胺"},{"id":"ad805d85-f776-446b-877c-39a5002b266f","keyword":"聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>十碳<span style=\"color:red\">二</span>胺","originalKeyword":"聚对苯二甲酰十碳二胺"},{"id":"e6f6db04-8816-456c-ab7a-afd19c748c5a","keyword":"热稳定性","originalKeyword":"热稳定性"},{"id":"f29b0347-d7c3-4bcb-8f5b-7469b862b7ed","keyword":"活化能","originalKeyword":"活化能"}],"language":"zh","publisherId":"hccllhyyy200902004","title":"聚<span style=\"color:red\">对苯二甲</span><span style=\"color:red\">酰</span>十碳<span style=\"color:red\">二</span>胺的制备和热稳定性研究","volume":"38","year":"2009"}],"totalpage":3288,"totalrecord":32879}