齐芸馨
,
唐文泰
,
夏建国
,
李望
,
展振宗
金属学报
本文采用SAM和XPS对实用Au-Ni-Kovar合金系统热处理样品(250—350℃,0.5—1.5h)进行了基底元素穿透Au层的表面偏聚研究,给出了这一复杂系统中Ni,Co表面偏聚机理的直观证据,即Ni,Co主要是通过晶界扩散穿透Au层而后以表面扩散覆盖镀Au表面的;表面偏聚元素化学态的研究则不仅表明,氧的吸附和氧化反应是Ni,Co表面偏聚的驱动力,而且发现,上述偏聚会引起样品表面吸水的现象。
关键词:
Au-Ni-Kovar合金系统
,
surface segregation
,
substrate element
,
SAM
,
XPS
QI Yunxin TANG Wentai XIA Jianguo Nei Mongol Institute of Metallic Materials
,
Baotou
,
ChinaLI Wang ZHAN Zhenzong Institute of Physical and Chemical Engineering Research
,
Tianjin
,
China
金属学报(英文版)
The surface segregation of substrate elements through the Au layer in the Au-Ni-Kovar sys- tem specimens heated at 250—350℃ for 0.5—1.5 h has been studied by SAM and XPS. Visual evidence of the mechanism for Ni and Co surface segregation of the complicated sys- tem has been given,i.e.Ni and Co penetrated the gold layer mainly by grain boundary diffu- sion and then covered the Au layer by surface diffusion.The strdy results of the chemical states of surface segregation elements not only indicate that oxygen adsorption and oxidation reaction are the driving force for the surface segregation of Ni and Co,but also show that the above segregation can result in water absorption on surfaces.
关键词:
Au-Ni-Kovar alloy system
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