CHE Guangcan Institute of Physics
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Academia Sinica
,
Beijing
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ChinaM.ELLNER Max-Planck Institut for Metallforschung
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Stuttgart
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Germany Associate Professor
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Institute of Physics
,
Academia Sinica
,
Beijing 100080
,
China
金属学报(英文版)
Isothermal section at 25℃ of phase diagram and phase structure of Bi-Pb-Tl ternary system have been studied by means of room and high temperature X-ray diffraction and quenching.
关键词:
ternary system
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ZHENG Chaogui JIN Jun YE Yupu Department of Chemistry
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Peking University
,
Beijing
,
China Dept.of Chemistry
,
Peking University
,
Beijing
,
China
金属学报(英文版)
The liquidus of ternary system NdCl_3-MgCl_2-LiCl has been determined by means of DTA.It was found that there are two surfaces corresponding to the primary crystallization of NdCl_3 and α-(MgCl_2,LiCl)respectively,and a univariant line related to the secondary crystallization with a minimum M(68.5 wt-% NdCl_3,2.7 wt-% MgCl_2,28.8 wt-% LiCl_2 441℃)in the system.
关键词:
NdCl_3
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Zhiyu QIAO Xianran XING Shuzhen DUAN University of Science and Technology Beijing
,
Beijing
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100083
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ChinaChaogui ZHENG Beijing University
,
Beijing
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100871
,
China
材料科学技术(英文)
A new geometric asymmetric model for predicting the thermodynamic properties of ternary system from three sub-binaries is presented in this paper.Its analytical expression with good calculating ac- curacy is most simple in all asymmetric models.The new model was applied to predict the enthalpies of mixing of the Bi-Ga-Sn.Au-Ag-Sn and NaCl-KCl-CaCl_2 ternary systems which were in good agreements with experimental data.Based on thermodynamic principles,the importance of the choice of asymmetric component is also discussed.The error analysis indicates that in the case of judging the asymmetric component in ternary system according to the thermodynamic criterion the deviation is minimum.It is of great significance to improve the calculating accuracy for predicting thermodynamic properties of ternary solution phase from the sub-binary ones.
关键词:
thermodynamic properties
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